Integrated process for treating heavy metal wastewater

A heavy metal and wastewater technology, applied in water/sewage treatment, adsorbed water/sewage treatment, reduced water/sewage treatment, etc. It can solve the problem of reducing the concentration of nano-zero valent iron, large area of ​​the reactor, and inability to guarantee the treatment effect, etc. problem, to achieve the effect of excellent treatment effect, low production cost, simple and easy process

Active Publication Date: 2013-05-22
TONGJI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

In addition, the traditional nano-zero-valent iron treatment heavy metal sewage reactor needs to set up a reaction zone and a precipitation zone separately, which not only leads to a large area of ​​the reactor, but also requires a large number of reflux equipment
During the reflux process, due to the mutual support between the nanoparticles increases the required energy consumption, and the bonding of the nanoparticles in the reflux pipeline will block the pipeline, so the unsatisfactory reflux effect will make the nanoparticle in the reaction zone The concentration of zero-valent iron gradually decreases, and the subsequent treatment effect cannot be guaranteed

Method used

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  • Integrated process for treating heavy metal wastewater
  • Integrated process for treating heavy metal wastewater
  • Integrated process for treating heavy metal wastewater

Examples

Experimental program
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Effect test

Embodiment 1

[0039] At 25°C, add a certain amount of lead, copper, nickel, zinc, and zinc compounds to distilled water to prepare simulated wastewater for later use. The concentrations of heavy metal ions in the simulated wastewater are shown in Table 1.

[0040] The reactor used in this example is a new type of integrated reactor. The main body of the reaction device is a similar cylindrical reactor 2, made of plexiglass, mainly including the main reaction zone 1, the reflux zone 2, the precipitation zone 3, and the water outlet zone. 4 and the agitator 5, the upper edge of the water outlet area is provided with a water guide 6, and the two ends of the bottom of the main reaction area 1 are respectively provided with a heavy metal waste water inlet 7 and a nanometer zero-valent iron inlet 8.

[0041] The simulated wastewater is fed from the water inlet of the reactor, and the nano-zero-valent iron ethanol solution to be used enters the device from the bottom inlet, so that the concent...

Embodiment 2

[0046] Take the electroplating wastewater stock solution at the exit of the electroplating workshop of an electroplating factory, first pretreat the electroplating wastewater stock solution: add a certain amount of PAM flocculant, first stir quickly for 1-2 minutes to mix the added flocculant in the solution evenly, and then reduce the stirring speed , slowly stir the electroplating wastewater for 30-60 min, so that the suspended impurities in the electroplating wastewater stock solution coagulate into flocs, stop stirring after the flocculation is completed, and let the electroplating wastewater stand for 1-3 h to settle, and filter it with filter paper after the precipitation is completed. Obtain clarified electroplating wastewater. The electroplating wastewater after pretreatment contains Zn 2+ 400~500mg / L, Cu 2+ , Pb 2+ 、Ni 2+ 600~800mg / L, pH between 5~7.

[0047] The reactor used in this example is a new type of integrated reactor. The main body of the reaction devic...

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Abstract

The invention relates to an integrated process for treating heavy metal wastewater. A reactor adopted in the integrated process is simple to construct, compact in structure, high in heavy metal wastewater treatment efficiency, and easy to operate, manage and maintain. The integrated process is free of a nanometer zero-valent iron mixed solution refluxing device, capable of increasing the nanometer zero-valent iron by sufficiently utilizing flow fields, which are formed by a stirring device on the inner part of the reactor, and capable of realizing solid-liquid separation and zero-valent iron refluxing by utilizing the gravity of the nanometer zero-valent iron, so that the nanometer zero-valent iron is sufficiently mixed and circulated in the reactor, and the high-adsorption performance and strong reduction characteristic to the heavy metals are greatly utilized. An integrated device is used to treat simulated wastewater and the pre-treated electroplating wastewater containing heavy metals, so that the concentration of various heavy metals in the treated outlet water are better than the emission standards of the national pollutant I. Moreover, the reactor has short hydraulic retention time and high treatment efficiency, and is free of additionally added chemical coagulant, capable of separating and recycling the nanometer zero-valent iron containing heavy metals and capable of avoiding the secondary pollution of the heavy metals.

Description

technical field [0001] The invention belongs to the technical field of heavy metal wastewater treatment, and in particular relates to an integrated process for treating heavy metal wastewater. Background technique [0002] Heavy metal pollution has the characteristics of refractory, easy to enrich, and difficult to remove. It is not only highly toxic, but also has concealment, irreversibility, and long-term nature. It can accumulate in organisms and amplify the toxicity through the bioaccumulation of the food chain. Therefore, Heavy metal pollution has become one of the most harmful water pollution problems. Heavy metals generally exist in nature in natural concentrations, but due to the increasing mining, smelting, processing and commercial manufacturing activities of heavy metals, heavy metals enter the atmosphere, water and soil. Industrial wastewater containing heavy metals mainly comes from mechanical processing wastewater, mining wastewater, steel and non-ferrous meta...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F1/28C02F1/70C02F1/62
Inventor 张亚雷代朝猛苏益明周雪飞
Owner TONGJI UNIV
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