Preparation method for solar cell spectrum conversion polymeric membrane
A solar cell and spectrum conversion technology, applied in circuits, photovoltaic power generation, electrical components, etc., can solve the problems of reducing the light transmittance of the encapsulation film, the photoelectric conversion efficiency of solar cells, limitations, uneven distribution of spectrum conversion materials, etc. The effect of light transmittance and utilization of sunlight, long life and high photoelectric conversion efficiency
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[0033] Example 1:
[0034] (1) Preparation of spectrum conversion material: Add 15 g of silsesquioxane to 30 mL of methylene chloride to prepare a silsesquioxane solution, and then add 360 mg of rare earth chloride to the above silsesquioxane solution In the nitrogen environment, under the condition of 130℃, stirring for 20 minutes and then naturally cooling to room temperature, solution A is obtained; 120 mg of ammonium fluoride and 80 mg of sodium hydroxide are mixed and dissolved in 10 mL of anhydrous methanol and added to the above solution In A, after stirring for 20 minutes at 40°C, methanol volatilizes to obtain solution B; in a nitrogen environment, the solution B is heated to 280°C, kept for 40 minutes and then cooled to room temperature naturally, and the spectrum conversion material is washed with ethanol The particles are separated out, and the spectrum conversion material I is obtained after repeated centrifugation, separation and ethanol washing for 2 to 3 times.
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Example Embodiment
[0039] Example 2:
[0040] (1) Preparation of spectrum conversion material: The spectrum conversion material I was prepared by the same steps and conditions as in Example 1.
[0041] (2) Treatment of polymer film: Plasma treatment of polyethylene composite film or polyvinyl fluoride composite film under the same conditions as in Example 1.
[0042] (3) Chemical grafting of spectrum conversion material and treated polymer film: According to raw material components and parts by weight, take 115 parts of plasma-treated polyethylene composite film or polyvinyl fluoride composite film, 10 parts of spectrum conversion material I, light Stabilizer poly[1-(2-hydroxyethyl)-2,2,6,6-tetramethyl-4-hydroxypiperidine succinate] or sebacic acid bis 2,2,6,6-tetra 0.20 parts of methyl piperidinol ester, 0.20 parts of initiator azobisisobutyronitrile, ultraviolet light absorber 2-hydroxy-4-n-octyloxybenzophenone or 2-(2H-benzotriazole-2 -Base)-6-(dodecyl)-4-methylphenol 0.3 parts, using the same ste...
Example Embodiment
[0044] Example 3:
[0045] (1) Preparation of spectrum conversion material: The spectrum conversion material I was prepared by the same steps and conditions as in Example 1.
[0046] (2) Treatment of polymer film: Plasma treatment of polyethylene composite film or polyvinyl fluoride composite film under the same conditions as in Example 1.
[0047] (3) Chemical grafting of spectrum conversion material and treated polymer film: 130 parts of plasma-treated polyethylene composite film or polyvinyl fluoride composite film, 15 parts of spectrum conversion material I, light Stabilizer poly[1-(2-hydroxyethyl)-2,2,6,6-tetramethyl-4-hydroxypiperidine succinate] or sebacic acid bis 2,2,6,6-tetra 0.50 parts of methyl piperidinol ester, 0.40 parts of initiator azobisisobutyronitrile, ultraviolet light absorber 2-hydroxy-4-n-octyloxybenzophenone or 2-(2H-benzotriazole-2 -0.5 parts of 6-(dodecyl)-4-methylphenol, using the same steps and reaction conditions as the step (3) in Example 1 to prepare...
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