Preparation method for solar cell spectrum conversion polymeric membrane

A solar cell and spectrum conversion technology, applied in circuits, photovoltaic power generation, electrical components, etc., can solve the problems of reducing the light transmittance of the encapsulation film, the photoelectric conversion efficiency of solar cells, limitations, uneven distribution of spectrum conversion materials, etc. The effect of light transmittance and utilization of sunlight, long life and high photoelectric conversion efficiency

Inactive Publication Date: 2013-08-21
NINGBO UNIV
View PDF3 Cites 3 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Prog. Photovolt: Res. Appl. 2011; 19:345~351 mentioned that encapsulating the film with conversion properties on the surface of solar cells improves the photoelectric conversion efficiency to a certain extent, but this film only has up-conversion Performance or only down-conversion performance, unable to simultaneously and fully convert high-energy ultraviolet light and low-energy infrared light into visible light or near-infrared light in sunlight
In addition, in Chinese patents with publication numbers CN200710302510.4 and CN201110021649.8, it is also

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Preparation method for solar cell spectrum conversion polymeric membrane
  • Preparation method for solar cell spectrum conversion polymeric membrane

Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0033] Example 1:

[0034] (1) Preparation of spectrum conversion material: Add 15 g of silsesquioxane to 30 mL of methylene chloride to prepare a silsesquioxane solution, and then add 360 mg of rare earth chloride to the above silsesquioxane solution In the nitrogen environment, under the condition of 130℃, stirring for 20 minutes and then naturally cooling to room temperature, solution A is obtained; 120 mg of ammonium fluoride and 80 mg of sodium hydroxide are mixed and dissolved in 10 mL of anhydrous methanol and added to the above solution In A, after stirring for 20 minutes at 40°C, methanol volatilizes to obtain solution B; in a nitrogen environment, the solution B is heated to 280°C, kept for 40 minutes and then cooled to room temperature naturally, and the spectrum conversion material is washed with ethanol The particles are separated out, and the spectrum conversion material I is obtained after repeated centrifugation, separation and ethanol washing for 2 to 3 times.

[...

Example Embodiment

[0039] Example 2:

[0040] (1) Preparation of spectrum conversion material: The spectrum conversion material I was prepared by the same steps and conditions as in Example 1.

[0041] (2) Treatment of polymer film: Plasma treatment of polyethylene composite film or polyvinyl fluoride composite film under the same conditions as in Example 1.

[0042] (3) Chemical grafting of spectrum conversion material and treated polymer film: According to raw material components and parts by weight, take 115 parts of plasma-treated polyethylene composite film or polyvinyl fluoride composite film, 10 parts of spectrum conversion material I, light Stabilizer poly[1-(2-hydroxyethyl)-2,2,6,6-tetramethyl-4-hydroxypiperidine succinate] or sebacic acid bis 2,2,6,6-tetra 0.20 parts of methyl piperidinol ester, 0.20 parts of initiator azobisisobutyronitrile, ultraviolet light absorber 2-hydroxy-4-n-octyloxybenzophenone or 2-(2H-benzotriazole-2 -Base)-6-(dodecyl)-4-methylphenol 0.3 parts, using the same ste...

Example Embodiment

[0044] Example 3:

[0045] (1) Preparation of spectrum conversion material: The spectrum conversion material I was prepared by the same steps and conditions as in Example 1.

[0046] (2) Treatment of polymer film: Plasma treatment of polyethylene composite film or polyvinyl fluoride composite film under the same conditions as in Example 1.

[0047] (3) Chemical grafting of spectrum conversion material and treated polymer film: 130 parts of plasma-treated polyethylene composite film or polyvinyl fluoride composite film, 15 parts of spectrum conversion material I, light Stabilizer poly[1-(2-hydroxyethyl)-2,2,6,6-tetramethyl-4-hydroxypiperidine succinate] or sebacic acid bis 2,2,6,6-tetra 0.50 parts of methyl piperidinol ester, 0.40 parts of initiator azobisisobutyronitrile, ultraviolet light absorber 2-hydroxy-4-n-octyloxybenzophenone or 2-(2H-benzotriazole-2 -0.5 parts of 6-(dodecyl)-4-methylphenol, using the same steps and reaction conditions as the step (3) in Example 1 to prepare...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The invention discloses a preparation method for a solar cell spectrum conversion polymeric membrane. The invention is characterized in that raw materials used in the method comprise, by weight, 100 to 150 parts of a polymer membrane, 0.01 to 1 part of a light stabilizing agent, 0.01 to 1 part of an ultraviolet absorber, 1 to 20 parts of a spectrum conversion material and 0.01 to 1 part of an initiator and the preparation method comprises the following steps: (1) reacting a rare earth chloride with silsesquioxane to prepare the spectrum conversion material; (2) processing the polymer membrane with a plasma processor; and (3) grafting the spectrum conversion material prepared in step (1) with the polymer membrane processed in step (2) so as to obtain the solar cell spectrum conversion polymeric membrane. The invention has the following advantages: the preparation process of the preparation method for the solar cell spectrum conversion polymeric membrane is simple; the prepared polymeric membrane has high light transmittance and good weatherability; and a solar cell prepared with the polymeric membrane as an assembly has high photoelectric conversion efficiency and a long service life.

Description

technical field [0001] The invention relates to a preparation method of a solar cell spectrum conversion encapsulation adhesive film, in particular to a preparation method of a solar cell spectrum conversion polymer film. Background technique [0002] A solar cell is a device that converts light energy into electrical energy, and its main components are tempered glass, packaging film, and solar cells. The spectral composition of sunlight covers the band from ultraviolet to far infrared, and as the wavelength increases, the photon energy of sunlight decreases. When sunlight hits the surface of the solar cell, it is separated into three parts: one part is reflected by the solar cell, one part is absorbed by the solar cell, and the other part directly passes through the solar cell. Due to the nature of the solar cell material, both the high-energy photon part (ultraviolet band) and the low-energy photon part (far-infrared band) of sunlight cannot be absorbed by the solar cell ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
IPC IPC(8): C08J7/12C08J7/00H01L31/048H01L31/055
CPCY02E10/50Y02E10/52
Inventor 李鹏侯琳熙张祥洲张小梅
Owner NINGBO UNIV
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products