A mildew-proof water-based coating
A water-based paint and anti-mildew technology, applied in the field of coatings, can solve the problems of poor persistence of inorganic anti-fungal agents, aging and decomposition of organic anti-fungal agents, and affecting the film-forming properties of coatings, achieving excellent application value, fast curing, and strengthening The effect of film-forming effect
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Synthetic example 2
[0026] Synthetic Example 2 Synthesis of bromine-containing compounds
[0027] Add 80g of potassium bromide and 0.4g of sodium silanolate to 100g of diethylene glycol, stir and react in an ice-water bath for 3 hours, raise the temperature to room temperature, and stir for 2 hours to react; wash the reaction product twice with water, separate the organic layer, anhydrous magnesium sulfate Drying, filtering, and distilling out the product under reduced pressure are bromine-containing compounds; the reaction formula is as follows:
[0028]
Synthetic example 3
[0029] Preparation of Synthetic Example 3 Composite Filler
[0030] Mix 500g of raw shell powder and 100g of aluminum phosphate evenly and sinter at 600°C for 25min, then crush the sintered body and select powder with a particle size of 0.8-1.2μm; then carry out surface treatment on the powder, specifically put 200g of powder into Add 2000g of ethanol and 2.2g of hydroxyl-terminated polysiloxane into the container, stir for 45min, and finally dry to obtain the composite filler.
[0031] Preparation of synthetic example 4 antifungal agent
[0032] The main reactions are as follows:
[0033]
[0034] Add 100 g of bromine-containing compound, 40 g of methyl p-hydroxybenzoate, and 12 g of potassium carbonate to 80 g of butanone, reflux for 2 hours, cool to room temperature, filter with suction, and dry the filter residue at 80° C. for 1 hour to obtain a solid powder; Solid powder, lanthanum trifluoromethanesulfonate (La(OTf) 3 ) 1g and imidazole 260g are mixed uniformly, pla...
Synthetic example 5
[0036] Preparation of Synthetic Example 5 Silicone Acrylic Emulsion
[0037] (1) 25g of butyl acrylate and 10g of deionized water are mixed uniformly to obtain mixture A; then another 2g of potassium carbonate aqueous solution whose mass concentration is 10% is prepared;
[0038] (2) In a nitrogen atmosphere, add 20g of deionized water, 1.3g of nonylphenol polyoxyethylene ether and 0.4g of NaHCO to the reactor in sequence 3 , stirring at 50°C for 30 minutes to obtain mixture B;
[0039] (3) mixing and stirring mixture A, mixture B and the potassium carbonate aqueous solution prepared in step (1) for 55 min to obtain mixture C;
[0040] (4) Add 3.5g of tetraethoxysilane to the mixture C; then keep the reaction at 60°C for 0.5h; stop heating, and cool to room temperature to obtain the silicon-acrylic emulsion.
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