Comprehensive utilization process of glutamic acid crystal mother liquid
A technology of crystallization mother liquor and glutamic acid, which is applied in the fields of application, preparation of organic compounds, animal feed, etc., can solve the problems of environmental protection pressure reduction, low extraction yield, high production cost, etc., achieve efficiency improvement, increase adsorption capacity, reduce The effect of water usage
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Embodiment 1
[0030] Example 1: Concentrate 200L of isoelectric glutamic acid crystallization mother liquor, pour it into a circulation tank, and transport it into the membrane group through a pump, with a feed pressure of 7kg / m 2 , Membrane pressure 3kg / m 2 , keep the membrane surface velocity at 4 m / s. Glutamic acid and small molecular substances pass through the membrane and enter the filtrate side for collection. Macromolecular substances, bacteria and other solid particles are intercepted. The filtrate directly enters the separation system for glutamic acid extraction and purification. The intercepted concentrated solution is dried to obtain bacterial protein, which is used as a feed additive.
Embodiment 2
[0032] Concentrate glutamic acid isoelectric crystallization mother liquor, and obtain filtrate 4L after filtering through 100nm membrane, wherein glutamic acid content is about 2.0%. Adjust the pH to 1.7 and enter the resin column. The volume of the resin column is 1.3L, and the gel-type strong acid resin is used. When the pH in the effluent no longer changes and the concentration of glutamic acid remains unchanged, the elution begins.
[0033] The eluent is prepared with ammonia water and ammonium sulfate to pH9.1, and the elution starts. The front flow, high flow and back flow were collected according to the difference of pH and glutamic acid content. Among them, the front part has a lower pH and a lower content of glutamic acid, which is merged into the crystallization mother liquor and adsorbed again. The high flow part is directly concentrated, and the low temperature is directly crystallized. The latter part is used as the preparation of the next batch of eluent. A...
Embodiment 3
[0035] After membrane separation, the glutamic acid crystallization mother liquor is adjusted to pH 1.7, and then enters resin columns A, B, and C connected in series for adsorption. Among them, the feed liquid enters the A column first, enters the B column after flowing out, and enters the C column after flowing out from the B column.
[0036] When the adsorption of column A is saturated, that is, when the concentration of glutamic acid entering and exiting column A remains unchanged, the feed starts from column B and continues to adsorb, and then enters column C and column D in sequence. Column A begins to elute. After the elution of the A column is completed and B is saturated, the B column starts to elute. Column A is connected after column D, and column C operates as the first adsorption column at this time. The analysis process is the same as in Example 2.
[0037] The invention combines membrane separation technology and ion exchange technology to realize the recover...
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