The invention relates to an ion exchange resin composite cooperate recover agent, formed by following materials (mass percentage) as alkyl phenol at 0-8.0, high-effect penetrant at 0.5-4.5, sodium chloride at 3-10, alcaine at 0-7, acid of wine at 0-2.5, oxidant at 0.4-0.6, non-ionic surface activator at 5.5-10, sodium dithionite at 0-0.1, recover disperser T-225 at 2.5-8.0, and the left is water, or formed by following materials as recover reducer as 0.3-1.0, sodium chloride at 0-1, alcaine at 0-10, combiner at 0-1.2, sludge remover rosin amine at 3-11, caustic soda at 0-2, amphiprotic surface activator at 4-10, symclosene at 7.5-12, recover agent SW-218 at 1.0-2.5 and the left is water. The invention has short recover time, while it can remove high-level metal ion, and high organic removing efficiency, without corrosion on device and harm on people.