Preparation and application of oxidation catalyst taking cerium-zirconium-silicon composite oxide as carrier
A technology of composite oxides and oxidation catalysts, applied in the direction of metal/metal oxide/metal hydroxide catalysts, physical/chemical process catalysts, catalyst carriers, etc., can solve high light-off temperature, low oxidation catalytic activity, and conversion Low-level problems, to achieve the effect of low ignition temperature, large specific surface area and high conversion rate
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Embodiment 1
[0035] A method for preparing a diesel vehicle oxidation catalyst with cerium-zirconium-silicon composite oxide as a carrier, the specific preparation steps are as follows:
[0036] The cerium-zirconium-silicon composite oxide support material is prepared by hydrothermal synthesis: under the condition of stirring at room temperature, weigh 5g of cerous nitrate, 2.5g of zirconyl nitrate and 14g of silica sol with a content of 20% (wt) and mix evenly to form Mix the metal salt solution. Under the condition of vigorous stirring, add 2 mol / L ammonia solution dropwise into the metal salt solution until the pH value is 9.5 to stop the dropwise addition. ℃ hydrothermal reaction for 3h. Take it out and cool it down, vacuum filter the resulting precipitate, wash it with deionized water until it is neutral, dry it at 100°C in air atmosphere for 12h, put it in a muffle furnace and bake it at 500-1000°C in air atmosphere for 5h to get cerium Zirconium-silicon composite oxide, the result...
Embodiment 2
[0054] Concrete preparation method step is basically the same with activity evaluation experiment and implementation case 1, and difference is:
[0055] When preparing the cerium-zirconium-silicon composite oxide support material, under the condition of stirring at room temperature, weigh 13g of cerous nitrate, 7.5g of zirconyl nitrate and 35g of silica sol with a content of 20% (wt) and mix evenly to form a mixed metal salt solution . The cerium-zirconium-silicon composite oxide support material is obtained by calcination at 1000°C for 5 hours, and its specific surface area is 196.1m 2 / g, the pore volume is 0.39cm 3 / g, the average pore diameter is 6.4nm, and the catalyst obtained is denoted as Pt-CZS-A. Carry out the activity evaluation experiment such as embodiment 1 under the simulated atmosphere of diesel vehicle exhaust in the laboratory, the catalyst Pt-CZS-A prepared is to the CO catalytic oxidation activity in diesel vehicle exhaust see figure 1 , for C in diesel ...
Embodiment 3
[0057] The specific steps of the preparation method and the activity evaluation experiment are basically the same as those in Example 1, the difference is: when preparing the cerium-zirconium-silicon composite oxide carrier material, weigh 9g of cerous nitrate, 5g of zirconyl nitrate and stir at room temperature. Mix evenly with 24.5g content of 20% (wt) silica sol to form a mixed metal salt solution, the amount of noble metal added is 0.5% (wt) of the slurry, and the resulting catalyst is designated as Pt-CZS-1-F. Carry out the activity evaluation experiment as embodiment 1 under the simulated atmosphere of diesel vehicle exhaust in the laboratory, the catalyst Pt-CZS-1-F prepared is to the CO catalytic oxidation activity in diesel vehicle exhaust see figure 1 , for C in diesel vehicle exhaust 3 h 8 Catalytic oxidation activity see figure 2 , Table 2 lists the Pt-CZS-1-F catalyst for CO and C 3 h 8 Catalytic oxidation results, it was found from Table 2 that the Pt-CZS-1-...
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