Preparation method of plating solution for electroplating tungsten-molybdenum-nickel alloy coating on surface of petroleum-pumping component

A nickel alloy and component technology, applied in the field of plating solution preparation, can solve the problems of poor compression and wear resistance, unresolved problems, expensive corrosion-resistant alloys, etc., achieve good corrosion resistance and friction resistance, and small environmental hazards , combined with good results

Inactive Publication Date: 2014-12-24
无锡市锡山区鹅湖镇荡口青荡金属制品厂
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

For more than 100 years, researchers of oil production machinery have carried out a lot of research work on corrosion and wear problems. On the sucker rod, such as using corrosion-resistant alloys: for example, K-grade sucker rods use 20Ni2Mo, which contains Ni, Cr, Mo Corrosion-resistant alloys are more expensive; use anti-corrosion coatings: including metal coatings (such as hot-dipped aluminum, chrome plating, spraying nickel-based alloys) and non-metallic coatings (such as epoxy resin coatings), existing problems: coating peeling off , this kind of sucker rod cannot be used in inclined wells; use non-metal: glass fiber reinforced plastic sucker rod, carbon fiber composite material continuous sucker rod, these two kinds of sucker rods are relatively expensive, and have poor compression and wear resistance; use corrosion inhibition Agent: relatively expensive, and the anti-corrosion effect is not ideal; on the oil suction pipe, nickel-phosphorus composite inner coating technology is used; bimetallic oil pipe; nitriding; FRP-lined oil pipe
Although some results have been achieved, the problem has not been solved

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0010] A preparation method of a plating solution for electroplating a tungsten-molybdenum-nickel alloy coating on the surface of an oil pumping part, the composition of the plating solution is: sodium tungstate 80g / L, sodium molybdate 10g / L, nickel sulfate 14g / L, boric acid 38g / L , sodium sulfate 30g / L, ammonium sulfate 24g / L, tartaric acid 30g / L, potassium pyrophosphate 15g / L, ascorbic acid 10g / L, formaldehyde 3ml / L, dimethylhexynol 2ml / L, the balance is water, The preparation method is: take half of the water, heat up to 55°C, add boric acid, sodium sulfate and ammonium sulfate, stir until dissolved, then add tartaric acid, potassium pyrophosphate, ascorbic acid, stir for 5 minutes, then add sodium tungstate, sodium molybdate and Nickel sulfate, stirred for 10 minutes, and finally added formaldehyde, dimethylhexynol and the remaining water, stirred evenly, and adjusted the pH value to 8.0-9.0 with ammonia water.

Embodiment 2

[0012] A preparation method of a plating solution for electroplating a tungsten-molybdenum-nickel alloy coating on the surface of an oil pumping part, the composition of the plating solution is: sodium tungstate 84g / L, sodium molybdate 6g / L, nickel sulfate 18g / L, boric acid 34g / L , sodium sulfate 36g / L, ammonium sulfate 20g / L, tartaric acid 34g / L, potassium pyrophosphate 11g / L, ascorbic acid 14g / L, formaldehyde 1ml / L, dimethylhexynol 4ml / L, the balance is water, The preparation method is: take half of the water, heat up to 65°C, add boric acid, sodium sulfate and ammonium sulfate, stir until dissolved, then add tartaric acid, potassium pyrophosphate, ascorbic acid, stir for 3 minutes, then add sodium tungstate, sodium molybdate and Nickel sulfate, stirred for 20 minutes, and finally added formaldehyde, dimethylhexynol and the remaining water, stirred evenly, and adjusted the pH value to 8.0-9.0 with ammonia water.

Embodiment 3

[0014] A preparation method of a plating solution for electroplating a tungsten-molybdenum-nickel alloy coating on the surface of an oil pumping part, the composition of the plating solution is: sodium tungstate 82g / L, sodium molybdate 8g / L, nickel sulfate 16g / L, boric acid 36g / L , sodium sulfate 33g / L, ammonium sulfate 22g / L, tartaric acid 32g / L, potassium pyrophosphate 13g / L, ascorbic acid 12g / L, formaldehyde 2ml / L, dimethylhexynol 3ml / L, the balance is water, The preparation method is: take half of the water, heat up to 60°C, add boric acid, sodium sulfate and ammonium sulfate, stir until dissolved, then add tartaric acid, potassium pyrophosphate, ascorbic acid, stir for 4 minutes, then add sodium tungstate, sodium molybdate and Nickel sulfate, stirred for 15 minutes, and finally added formaldehyde, dimethylhexynol and the remaining water, stirred evenly, and adjusted the pH value to 8.0-9.0 with ammonia water.

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PUM

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Abstract

The invention discloses a preparation method of a plating solution for electroplating a tungsten-molybdenum-nickel alloy coating on a surface of a petroleum-pumping component. The preparation method comprises the steps of measuring half of water; heating the water to a temperature of 55-65 DEG C; adding 34-38 g / L of boric acid, 30-36 g / L of sodium sulfate and 20-24 g / L of ammonium sulfate; stirring to dissolve the above materials; adding 30-34 g / L of tartaric acid, 11-15 g / L of potassium pyrophosphate and 10-14 g / L of ascorbic acid; stirring for 3-5 minutes; adding 80-84 g / L of sodium tungstate, 6-10 g / L of sodium molybdate and 14-18 g / L of nickel sulfate; stirring for 10-20 minutes; and finally adding 1-3 ml / L of formaldehyde, 2-4 ml / L of dimethyl hexynol and the residual water; stirring uniformly; and regulating a pH value to 8.0-9.0 with ammonia water.

Description

technical field [0001] The invention relates to the technical field of electroplating, in particular to a method for preparing a plating solution for electroplating a tungsten-molybdenum-nickel alloy coating on the surface of an oil pumping part. Background technique [0002] Sucker rods and tubing are used for oil recovery in oil fields. There are two world-class problems encountered in mines: corrosion and wear. Well fluids often contain CO 2 , H 2 Corrosive media such as S and brine can cause corrosion fatigue fracture of sucker rods, corrosion damage of oil well pumps and screw pumps, corrosion and perforation of oil pipes, and seriously affect crude oil production. Some pumping wells of Dongxin Oil Production Plant in Shengli Oilfield broke due to corrosion of couplings (45 steel, quenched and tempered) after three months of operation. In some pumping wells in Zhongyuan Oilfield, the sucker rods suffered from corrosion fatigue fracture after three months of operatio...

Claims

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Application Information

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IPC IPC(8): C25D3/56
Inventor 钱永清
Owner 无锡市锡山区鹅湖镇荡口青荡金属制品厂
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