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Weaving machine and preparation method for conductive fabric

A loom and fiber weaving technology, which is applied in the field of loom and conductive fabric preparation, can solve the problems of long reaction time, complicated preparation process, and large consumption of reagents, etc.

Active Publication Date: 2015-01-07
苏州高飞纺织有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Taking polyaniline as an example of a conductive fiber with a conductive coating, the preparation method is as follows: immerse the ordinary fiber in an aniline acidic medium containing a swelling agent and a catalyst containing copper ions, and then polymerize after dipping in an oxidizing agent solution to obtain a conductive fiber. Not only the preparation process is complicated, but also consumes a lot of reagents and produces a lot of waste water
Especially for chemical fibers that are difficult to modify such as polyester and acrylic fibers, this method not only consumes a large amount of reagents and produces a large amount of waste water, but also has uneven deposition of aniline, resulting in uneven polyaniline coating in the conductive fibers, poor bonding fastness and conductivity. Poor ability
[0005] In order to improve the bonding fastness between polyaniline and processed chemical fibers, such as polyester (PET), acrylic fiber (PAN), etc., and to improve the electrical conductivity of composite fibers, some people use low-temperature plasma pretreatment on polyester or acrylic fibers first, and then use Aniline is oxidatively polymerized by a wet chemical method to form a polyaniline conductive coating. The conductive polyaniline polyester composite fiber prepared by this method has the characteristics of good electrical conductivity and excellent antistatic performance. However, in the wet preparation process, the solution Aniline monomer, acidic medium and oxidant are indispensable. Not only the pretreatment is complicated, the reaction time is long, the reagent consumption is large, but also a large amount of waste water is generated.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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  • Weaving machine and preparation method for conductive fabric
  • Weaving machine and preparation method for conductive fabric
  • Weaving machine and preparation method for conductive fabric

Examples

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preparation example Construction

[0085] The present invention also provides a preparation method of conductive fabric, comprising:

[0086] After the fibers to be woven are adsorbed by aniline gas, they are polymerized under plasma conditions, and the obtained conductive fibers are woven as weft yarns and warp yarns to obtain conductive fabrics.

[0087] In the present invention, the fibers to be woven first absorb aniline through an aniline gas generator, and then polymerize aniline in situ in a plasma polymerization reactor to form a polyaniline conductive coating on the surface of the fibers to be woven to obtain conductive fibers; The fibers are used as weft yarns, which are woven with warp yarns to obtain conductive fabrics.

[0088] In the present invention, the fiber to be woven is used as the raw material, after being adsorbed by aniline gas in sequence, the aniline is subjected to in-situ polymerization reaction under plasma conditions, and a conductive coating is formed on the surface of the fiber t...

Embodiment 1

[0098] see Figure 5 , Figure 5 The partial structure diagram of the loom provided for the embodiment 1 of the present invention, the loom comprises: weft feeder 4, aniline gas generator 1, hydrogen chloride gas generator 2, plasma polymerization reactor 3 and weft insertion device (not shown in the figure Shown in), wherein, the aniline gas generator comprises: aniline solution storage bottle, the sealing cover that is arranged on the aniline solution storage bottle, the inlet pipe that is positioned at the aniline solution liquid level, the inlet pipe is connected with the inlet pump through flow meter, is positioned at The air outlet pipe above the liquid level of the aniline solution, and the aniline gas storage pipe connected to the other end of the air outlet pipe;

[0099] The hydrogen chloride gas generator includes: a hydrochloric acid solution storage bottle, a sealing cover arranged on the hydrochloric acid solution storage bottle, an air inlet pipe located below ...

Embodiment 2~4

[0102] Using polyester yarns with a specification of 150D / 299F, an average value of specific resistance of 2500MΩ·cm, and a length of 2m as raw materials, polyaniline modification was carried out in the preparation device provided in Example 1. During the modification process, in the aniline gas generator, Nitrogen is used as the intake air, and the blowing volume of nitrogen gas is 30L / h, 60L / h and 90L / h respectively; in the hydrogen chloride gas generator, air is used as the intake air, and the blowing volume of air is 30L / h, 60L / h respectively. h and 90L / h; in the plasma polymerization reactor, the output voltage of the plasma generator power supply is 32v, and the polymerization time is 3s, that is, the residence time of the yarn in the plasma polymerization reactor is 3s, and the conductive fiber is obtained.

[0103] Carry out scanning electron microscope observation to the conductive fiber prepared by embodiment 4 and the original polyester fiber, the results can be foun...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Abstract

The invention discloses a weaving machine and a preparation method for conductive fabric. An aniline gas generator and a plasma polymerization reactor are arranged between a weft accumulator and a weft guide device of the weaving machine in sequence, and fiber to be weaved passes through the aniline gas generator and the plasma polymerization reactor in sequence from the weft accumulator and is led out from the weft guide device. The preparation method for the conductive fabric includes that the fiber to be weaved is performed with polymerization reaction under a plasma condition after absorbing aniline gas, and the conductive fiber is weaved with warps to obtain the conductive fabric. According to the weaving machine, the aniline gas generator and the plasma polymerization reactor are arranged between the weft accumulator and weft guide device, the fiber to be weaved firstly adsorbs aniline through the aniline gas generator, and then the aniline is performed with in situ polymerization in the plasma polymerization reactor to form a poly-aniline conductive coat on the surface of the fiber to be weaved to obtain the conductive fiber; the conductive fiber serves as weft yarns, and the weft yarns are weaved with warps to obtain the conductive fiber. The weaving machine and the preparation method for the conductive fabric are capable of integrating the fiber modification and fabric production.

Description

technical field [0001] The invention belongs to the technical field of conductive fibers, and in particular relates to a loom and a method for preparing conductive fabrics. Background technique [0002] Conductive fiber is a functional fiber that eliminates static electricity through electron conduction and corona discharge. It has good conductivity and durability, and has a wide range of applications in industrial and civil fields. The conductive fabric made of conductive fiber has excellent functions such as electric conduction, heat conduction, shielding, and electromagnetic wave absorption. It is widely used in conductive mesh and conductive work clothes in the electronics and electric power industries; , aerospace, and electromagnetic frequency shields in the precision electronics industry, etc. [0003] Conductive fibers are divided into metal-based conductive fibers, carbon black-based conductive fibers, conductive polymer fibers and metal compound-type conductive fi...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D03J1/04D03D15/00D06M15/61D06M101/32D06M101/28D06M101/20D03D15/283D03D15/533
CPCD03D15/00D03J1/04D06M15/61D06M2101/32D06M2101/28D06M2101/20
Inventor 冯志华刘帅刘德启
Owner 苏州高飞纺织有限公司
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