Peelable mask and preparation method thereof
A peeling and unsaturated technology, used in adhesives, monocarboxylate copolymer adhesives, graft polymer adhesives, etc. Film is too hard and other problems
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preparation example 1
[0066] Prepare polystyrene-polyurethane-unsaturated polyester copolymer, its synthetic steps are:
[0067] (1) Synthesis of unsaturated polyester containing terminal hydroxyl groups
[0068]40 parts of soy oil, 30 parts of fumaric acid, 40 parts of maleic anhydride, 20 parts of phthalic anhydride, 80 parts of ethylene glycol, 100 parts of pentaerythritol, 20 parts of glycerin, 100 parts of cyclohexanone, 2.6 parts of concentrated sulfuric acid Sequentially add to the reaction vessel equipped with electric stirring, water separator, thermometer and electric heating mantle, heat, stir, heat up to 140°C, react for 2.5 hours; heat up to 155°C for 0.5 hour, cool down to 100°C and add 20 parts Propylene glycol (so that the terminal group of the polycondensate is -OH), react for 1 h, and vacuumize to obtain an unsaturated polyester containing terminal hydroxyl groups, cool and set aside.
[0069] (2) Synthesis of Polyurethane Unsaturated Polyester Copolymer
[0070] Take 60 parts o...
Embodiment 1
[0074] The peelable glue contains the following raw materials:
[0075] 28 parts of chlorinated polypropylene-ethylene random copolymer; 25 parts of vinyl chloride-vinyl acetate-acrylate terpolymer; 37 parts of silicone modified acrylate rubber; 30 parts of polystyrene-polyurethane-unsaturated polyester resin 2 parts; 2 parts of pigment; 0.2 part of thixotropic agent; 0.3 part of defoamer; 0.5 part of antioxidant; 40 parts of solvent.
[0076] Its preparation method is:
[0077] 1) Accurately weigh various raw materials;
[0078] 2) Uniformly disperse the main film former and solvent (mass ratio, NMP:PGMEA:MEK=60:20:20) to obtain mixed solution 1;
[0079] 3) Then add pigments, defoamers, antioxidants, and grind with a three-roll mill to obtain a mixed solution 2;
[0080] 4) Then add the thixotropic agent, disperse and discharge evenly.
Embodiment 2
[0082] The peelable glue contains the following raw materials:
[0083] 30 parts of chlorinated polypropylene-ethylene random copolymer; 30 parts of vinyl chloride-vinyl acetate-acrylate terpolymer; 35 parts of silicone modified acrylate rubber; 25 parts of polystyrene-polyurethane-unsaturated polyester resin cellulose acetate butyrate, 10 parts; epoxy resin, 10 parts, closed polyurethane, 15 parts; organotin, 1 part; pigment 3 parts; thixotropic agent, 0.4 part; defoamer, 0.5 part; antioxidant agent, 0.4 parts; solvent 20 parts.
[0084] Its preparation method is:
[0085] 1) Accurately weigh various raw materials;
[0086] 2) uniformly dispersing the main film former and the solvent to obtain a mixed solution 1;
[0087] 3) Then add pigments, defoamers, antioxidants, and secondary film formers, and grind with a three-roll mill to obtain a mixed solution 2;
[0088] 4) Then add the thixotropic agent, disperse and discharge evenly.
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