Ultra-low loss high temperature resistant low intermodulation cable and its preparation process
A high temperature resistant and cable technology, applied in the direction of cable/conductor manufacturing, insulated cables, cables, etc., can solve the problems of increased cable loss, large loss, discount, etc., and achieve the effect of improving shielding, reducing loss, and good conductivity
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Embodiment 1
[0016] Example 1 About Copper Foil Longitudinal Clad
[0017] In this embodiment, the copper foil used for the copper foil longitudinal cladding has been passivated, which not only provides excellent corrosion resistance, but also has a good anti-tarnish effect, can maintain the metallic luster of copper, and does not affect Subsequent hot dip tin process.
[0018] In this embodiment, the passivation solution used is composed of 0.05-0.30wt% benzotriazole, 0.05-0.15wt% hydroxysuccinimide, 0.10-0.20wt% oxalic acid, and the balance water composition. The passivation treatment temperature is 60-80° C., and the treatment time is 4-20 seconds. Table 1 gives several non-limiting specific examples and comparative examples.
[0019] Table 1
[0020]
[0021] In Table 1, the passivation treatment temperature is 65° C., and the treatment time is 10 seconds. Among them, " / " means that this component is not added, and EDTA means ethylenediaminetetraacetic acid.
[0022] Place t...
Embodiment 2
[0025] Example 2 About Hot Dip Tin Plating
[0026] Conventional immersion tin usually uses pure tin or tin-lead alloy. However, the pure tin immersion coating has poor corrosion resistance at high temperatures, and its adhesion to copper becomes poor at sub-zero low temperatures, and it is prone to peeling off and even powdering. For environmental reasons, the use of lead is restricted or even banned. In this embodiment, adding a small amount of Ge and Ni to tin can not only prevent powdering or coating peeling at low temperature, but also improve the uniformity of the coating, and also improve its high temperature resistance. Specifically, hot-dip tin is operated in a tin-dipping furnace. In order to prevent oxidation, it is carried out under nitrogen conditions. The hot-dip plating temperature is controlled at 280-285°C; the hot-dip plating bath is: 0.05-0.50wt% Ge , 0.15-0.50wt% Ni, and the remainder Sn; the thickness of the tin plating layer is 10 μm.
Embodiment 3
[0028] In the present invention, a halogen-free insulating sheath is used to ensure its stability and durability under high and low temperature conditions. The invention adopts ABS resin modified polyethylene sheath. The raw material composition of the sheath in this embodiment is: 8.0-10.0wt% ABS resin, 3.0-5.0wt% Et-MAH-acrylic resin, 2.5-3.5wt% styrene-butadiene-mass Anhydride copolymer, 12-15wt% calcium carbonate, 2.0-2.5wt% antimony trioxide, 1.0-1.5wt% magnesium oxide, 0.5-1.0wt% acetoxysilane, 0.5-1.0wt% Triallyl isocyanurate, 1.5-2.0 wt% of lubricant, 0.10-0.30 wt% of antioxidant, and the balance of high-density polyethylene. In this embodiment, by adding a small amount of triallyl isocyanurate and acetoxysilane, the compatibility of polyethylene and ABS is ensured, and good mechanical properties and high and low temperature resistance properties are endowed to it. Put the above components into the mixer according to the ratio and mix them evenly, and then send the m...
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Abstract
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