Impact-resistant wear-resistant rubber material

A wear-resistant rubber and impact-resistant technology, applied in the rubber field, can solve the problems of difficult chemical reaction, uneven dispersion, poor affinity, etc., and achieve the effect of low apparent viscosity, good compatibility and enhanced fluidity

Inactive Publication Date: 2015-12-02
合肥市再德高分子材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] With the rapid development of the industrial field, traditional rubber materials can no longer meet the requirements of use. At present, inorganic powder minerals are often used to strengthen rubber materials. Ground calcium carbonate, as a commonly used powdered inorganic filler for rubber, has high chemical purity, high inertness, and is not easy to chemical Reaction, good thermal stability, no decomposition below 400°C, non-toxic, good dispersibility, etc., have been widely used for many years to solve various problems, and heavy calcium carbonate has been more and more widely used as a rubber filling material Application, heavy calcium carbonate is ground from natural carbonate minerals such as calcite, marble, and limestone. Adding heavy calcium carbonate to rubber can increase rubber volume, reduce product cost, improve dimensional stability of rubber, and improve heat resistance However, because the surface of heavy calcium carbonate powder has a hydroxyl group with strong hydrophilicity, it is hydrophilic and oleophobic, which makes its affinity with rubber worse, and it is unevenly dispersed in rubber. With the increase of the filling amount, these shortcomings become more obvious. How to prepare a rubber material with good compatibility between materials, excellent mechanical properties and excellent reinforcing properties has become a technical problem that needs to be solved at present.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0016] A kind of impact-resistant wear-resistant rubber material that the present invention proposes, its raw material comprises by weight: 40 parts of silicone rubber, 25 parts of EPDM rubber, 10 parts of fluorine rubber, 2 parts of tert-butyl peroxybenzoate, 2- 1.5 parts of thiol imidazoline, 2 parts of silane coupling agent, 1 part of N-cyclohexyl-2-benzothiazole sulfenamide, 6 parts of nano zinc oxide, 40 parts of silica, 20 parts of modified heavy calcium carbonate 13 parts of fly ash, 30 parts of calcined clay, 1 part of antioxidant OD, 1.5 parts of antioxidant NBC, 1 part of trioctyl trimellitate, 2 parts of dioctyl phthalate;

[0017] In the preparation process of modified heavy calcium carbonate, 50 parts of heavy calcium carbonate powder are placed in an oven to dry in parts by weight, the drying temperature is 108°C, and the drying time is 30min. Add 140 parts of deionized water for ultrasonic treatment for 30 minutes, send the obtained material into the reactor, he...

Embodiment 2

[0019] A kind of impact-resistant wear-resistant rubber material that the present invention proposes, its raw material comprises by weight: 70 parts of silicone rubber, 15 parts of EPDM rubber, 20 parts of fluorine rubber, 1.5 parts of tert-butyl peroxybenzoate, 2- 2.3 parts of thiol imidazoline, 1 part of silane coupling agent, 2 parts of N-cyclohexyl-2-benzothiazole sulfenamide, 3 parts of nano zinc oxide, 60 parts of silica, 15 parts of modified heavy calcium carbonate 18 parts of fly ash, 20 parts of calcined clay, 1.4 parts of anti-aging agent OD, 1 part of anti-aging agent NBC, 1.5 parts of trioctyl trimellitate, 1 part of dioctyl phthalate;

[0020]In the preparation process of the modified heavy calcium carbonate, 80 parts of heavy calcium carbonate powder are placed in an oven to dry in parts by weight, the drying temperature is 102°C, and the drying time is 50min, and the dried heavy calcium carbonate powder is added Add 100 parts of deionized water for ultrasonic tr...

Embodiment 3

[0022] A kind of impact-resistant wear-resistant rubber material that the present invention proposes, its raw material comprises by weight: 56 parts of silicone rubber, 22 parts of EPDM rubber, 17 parts of fluorine rubber, 1.7 parts of tert-butyl peroxybenzoate, 2- 2.1 parts of thiol imidazoline, 1.6 parts of silane coupling agent, 1.3 parts of N-cyclohexyl-2-benzothiazole sulfenamide, 4.5 parts of nano zinc oxide, 47 parts of silica, 17 parts of modified heavy calcium carbonate , 15 parts of fly ash, 26 parts of calcined clay, 1.24 parts of antioxidant OD, 1.3 parts of antioxidant NBC, 1.3 parts of trioctyl trimellitate, 1.6 parts of dioctyl phthalate;

[0023] In the preparation process of modified heavy calcium carbonate, 62 parts of heavy calcium carbonate powder were placed in an oven to dry in parts by weight, the drying temperature was 105°C, and the drying time was 42min. Add 124 parts of deionized water for ultrasonic treatment for 41 minutes, send the obtained materi...

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Abstract

The invention discloses an impact-resistant wear-resistant rubber material. The material comprises the following raw materials by weight: 40 to 70 parts of silicone rubber, 15 to 25 parts of ethylene-propylene-diene rubber, 10 to 20 parts of fluororubber, 1.5 to 2 parts of tert-Butyl peroxy benzoate, 1.5 to 2.3 parts of 2-mercaptoimidazoline, 1 to 2 parts of a silane coupling agent, 1 to 2 parts of N-cyclohexyl-2-benzothiazole sulfonamide, 3 to 6 parts of nanometer zinc oxide, 40 to 60 siliceous earth, 15 to 20 parts of modified heavy calcium carbonate, 13 to 18 parts of fly ash, 20 to 30 parts of calcined clay, 1 to 1.4 parts of an antiaging agent OD, 1 to 1.5 parts of an antiaging agent NBC, 1 to 1.5 part of trioctyl trimellitate and 1 to 2 parts of dioctyl phthalate. The impact-resistant wear-resistant rubber material provided by the invention has good mechanical property, excellent reinforcing property and good compatibility among materials.

Description

technical field [0001] The invention relates to the technical field of rubber, in particular to an impact-resistant and wear-resistant rubber material. Background technique [0002] With the rapid development of the industrial field, traditional rubber materials can no longer meet the requirements of use. At present, inorganic powder minerals are often used to strengthen rubber materials. Ground calcium carbonate, as a commonly used powdered inorganic filler for rubber, has high chemical purity, high inertness, and is not easy to chemical Reaction, good thermal stability, no decomposition below 400°C, non-toxic, good dispersibility, etc., have been widely used for many years to solve various problems, and heavy calcium carbonate has been more and more widely used as a rubber filling material Application, heavy calcium carbonate is ground from natural carbonate minerals such as calcite, marble, and limestone. Adding heavy calcium carbonate to rubber can increase rubber volume...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L83/04C08L23/16C08L27/12C08K13/06C08K5/14C08K5/37C08K5/47C08K3/22C08K3/34C08K3/26C08K5/12
Inventor 邱再明
Owner 合肥市再德高分子材料有限公司
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