High stability concrete silicone joint glue and preparation method thereof

A high stability, concrete technology, applied in adhesives, polymer adhesive additives, non-polymer adhesive additives, etc., can solve the problems of easy pollution, increased crosslink density, increased modulus, etc., to achieve performance And the effect of improved stability, excellent plasticizing performance, and simple preparation method

Active Publication Date: 2017-08-25
CHENGDU GUIBAO SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] However, the existing silicone joint adhesives have considerable defects: 1. In order to reduce costs or increase construction performance, a large amount of plasticizers (such as white oil, low-viscosity methyl silicone oil, etc.) are often added to the joint adhesives. , resulting in the comprehensive performance of the joint adhesive not meeting the requirements for use
2. The "oil" contained in the silicone sealant is easy to dissociate to the dust adhered to the surface of the colloid due to static electricity, and the dust will spread to the surrounding of the bonding surface with the rain and wind
Since concrete is a porous material, it is very easy to be polluted, resulting in banded pollution around the joints of the concrete slab, which affects the appearance
3. The high-elongation and low-modulus joint adhesive will increase in modulus, decrease in plasticity, and decrease in elongation at break with time in the later period of use.
This is because over time, the cross-linking reaction in the joint adhesive system is becoming more and more perfect, resulting in an increase in cross-linking density, so that the seam adhesive loses the characteristics of high elongation and low modulus during service.

Method used

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  • High stability concrete silicone joint glue and preparation method thereof
  • High stability concrete silicone joint glue and preparation method thereof
  • High stability concrete silicone joint glue and preparation method thereof

Examples

Experimental program
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Effect test

preparation example Construction

[0049] Preparation of raw materials:

[0050] Add 209.9g (4.58mol) of absolute ethanol and 500mL of petroleum ether into a 3L three-necked flask, keep the nitrogen flow rate at 0.1ml / min, stir evenly in an ice-water bath, control the internal temperature at about 10℃, and then add 300g dropwise (1.85mol) (chloromethyl)methyldichlorosilane, about 1h after the dripping is completed, continue to react at 40°C for 3h. Then, the solvent and unreacted ethanol were evaporated under a vacuum of 0.05Mpa, and then rectified under normal pressure to collect the product at 94-95°C to obtain 320g of colorless and transparent (chloromethyl)methyldiethoxysilane with a yield. 96%.

[0051] (Chloromethyl) methyl ethoxy butanone oxime silane preparation

[0052] Add 300g (1.85mol) (chloromethyl)methyldichlorosilane, 500ml petroleum ether and 387.2g (3.83mol) triethylamine into a 3L three-necked flask, stir well in an ice-water bath, and control the internal temperature at 10 ℃, then add 85.1g (1.85...

Embodiment 1

[0055] Put 290.8g (1.59mol) (chloromethyl)methyldiethoxysilane, 152.2g (1.75mol) morpholine, 178.2g (1.75mol) triethylamine, 0.4gKI and 800mL petroleum ether into a 3L three-necked flask After reacting at 60℃ for 4h under nitrogen protection. The generated triethylamine hydrochloride is filtered off, the filtrate is rotary evaporated to remove the solvent and unreacted triethylamine and morpholine, and then rectified to collect the product at 125-132°C / 10mmHg to obtain orange-yellow transparent (morpholinomethyl) ) 294.1 g of methyldiethoxysilane, with a yield of 79.4%.

[0056] 1 H NMR(300MHz, CDCl 3 ), δ3.67(4H), 3.60(4H), 2.45(4H), 2.20(2H), 1.10(6H), 0.16(3H)

[0057] Elemental analysis: C% 51.39, H% 9.88, N% 5.94.

Embodiment 2

[0059] Put 132g (0.5mol) (chloromethyl) methyl dibutyl ketoxime silane, 46.2g (0.53mol) morpholine, 53.6g (0.53mol) triethylamine, 0.2gKI and 300ml petroleum ether into a 1L three-necked flask After reacting at 75℃ for 6h under the protection of nitrogen, filter to remove the generated triethylamine hydrochloride, rotate the filtrate to remove the solvent and unreacted triethylamine, morpholine, and then rectify, collect 143-150℃ / 8mmHg The product obtained 118.2 g of orange-yellow transparent (morpholinomethyl) methyl dibutyl ketoxime silane with a yield of 74.9%.

[0060] 1 H NMR(300MHz, CDCl 3 ), δ3.63(4H), 2.40(14H), 2.18(2H), 1.08(6H), 0.18(3H)

[0061] Elemental analysis: C% 53.31, H% 9.25, N% 13.29.

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Abstract

The invention discloses a high-stability concrete silicone joint glue and a preparation method thereof. The joint glue consists of 100 parts by mass of α,ω-dihydroxy polydimethylsiloxane, 50-150 parts of filler 0.5-10 parts of thixotropic agent, 0.5-10 parts of chain extender, 5-15 parts of curing agent, 0.1-5 parts of tackifier, 0.01-3 parts of catalyst, 1-10 parts of liquid nitrile rubber, First, α, ω-dihydroxy polydimethylsiloxane, thixotropic agent and filler are made into a base material in a kneader, and then the base material is transferred into a high-speed disperser, and the remaining raw materials are added to react to obtain the base material. seam glue. The invention uses liquid nitrile rubber modified silicone joint adhesive, and adopts a specific chain extender to endow the joint adhesive with permanent toughness and mechanical property retention, and the plasticizer does not migrate, does not damage the bonding, and greatly improves Improve the bonding strength, excellent aging resistance, environmental protection and pollution-free.

Description

Technical field [0001] The embodiment of the present invention relates to the field of polymer materials. More specifically, the embodiment of the present invention relates to a high-stability concrete silicone joint glue and a preparation method thereof. Background technique [0002] In recent years, the frequent occurrence of global resource and environmental crises has made people pay more and more attention to resource conservation and environmental protection. With the low-carbon economy beginning to become the world's mainstream economic development mode, my country can no longer seek economic leapfrog development at the expense of the environment. As one of the industries with high energy consumption and high pollution, my country's construction industry must follow the path of sustainable development, and the development of industrialized buildings is imminent. [0003] As a joint product between traditional buildings and industrialized buildings, it has a decisive effect ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09J183/06C09J11/08C09J11/04C09J11/06
Inventor 霍威张淼锋熊婷王有治
Owner CHENGDU GUIBAO SCI & TECH
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