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A kind of solar cell composite back film and preparation method thereof

A technology for solar cells and composite films, applied in the field of solar cells, can solve the problems of poor anti-fouling ability, poor heat dissipation, material vaporization, etc. Effect

Active Publication Date: 2017-05-03
EOPLLY NEW ENERGY TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Chinese patent 201110188877.4 discloses a solar battery back sheet, including a gas barrier layer, a process-resistant layer and several outer coating layers, and at least one outer coating layer is a composite film made of polyimide and Teflon, so The above composite film can be composed of polyimide film and Teflon film, or a co-extrusion film of polyimide and Teflon. The gas barrier layer can effectively block water vapor and is resistant to processing. The layer is suitable for laminating processing or providing a cushioning effect, polyimide resin has weather resistance properties, can protect the gas barrier layer, and Teflon can further block water vapor and anti-ultraviolet rays, but the solar cell prepared by the scheme of the prior art The backplane has poor heat dissipation and poor anti-fouling ability, which reduces the service life of solar cells to a certain extent
The solar backsheet prepared by this prior art has good tensile strength, high water vapor transmission rate, and high thermal shrinkage rate, but there are still problems such as poor heat dissipation and poor anti-fouling ability, which will affect the electrical performance of solar cells
[0006] In the prior art, part of the solar cell back film (back sheet) will turn yellow under the irradiation of ultraviolet light, resulting in the destruction of the molecular components of the back film layer, the overall performance of the back film is reduced, and the reflectivity of the back film is reduced at the same time. , which affects the overall output of the component
Moreover, if the heat transfer coefficient of the cell material is poor, the high local temperature will cause the material to vaporize, resulting in a bulge on the back film, and the bulge will gradually expand, causing the surrounding materials to oxidize and deteriorate, affecting the service life of the module

Method used

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  • A kind of solar cell composite back film and preparation method thereof

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] like figure 1 As shown, a composite back film for solar cells comprises a first back film 1, a second back film 2, a third back film 3, between the first back film 1 and the second back film 2, the second back film 2 There is also an adhesive layer 4 between the third back film 3 and the first back film 1 is adjacent to the EVA adhesive film of the solar cell. Moreover, the first back film is a polytetrafluoroethylene film; the second back film is a composite film made of polyethylene terephthalate film and fumed silica; the third back film is polycarbonate-zirconia -Composite membrane composed of polytetrafluoroethylene.

[0037] In addition, the zirconia in the third back film 3 is nano zirconia. The zirconia is nano zirconia modified by hexafluoropropylene oxide oligomer surfactant, titanate coupling agent and polymer compatibilizer. Polycarbonate is coated on the surface of the surface active agent zirconia to form a structure with zirconia as the core and polycarb...

Embodiment 2

[0041] refer to figure 1 , a solar cell composite back film, comprising a first back film 1, a second back film 2, a third back film 3, between the first back film 1 and the second back film 2, between the second back film 2 and the second back film There is also an adhesive layer 4 between the three back films 3, and the first back film 1 is adjacent to the EVA adhesive film of the solar cell. Moreover, the second back film is a composite film composed of polyethylene terephthalate film and fumed silica; the first and third back films are made of polycarbonate-zirconia-polytetrafluoroethylene Composite film.

[0042] In addition, the zirconia in the first and third back films 3 is nano zirconia. The zirconia is nano zirconia modified by hexafluoropropylene oxide oligomer surfactant, titanate coupling agent and polymer compatibilizer.

[0043] The solar battery back film provided by the invention uses a modified polytetrafluoroethylene film, which has superior electrical pe...

Embodiment 3

[0045] A preparation method for a solar cell composite back film, characterized in that: comprising the following steps:

[0046] 1) Zirconia modification: Dry the nano-zirconia at 110°C for 30 minutes, then put it into a container filled with toluene solvent, ultrasonically disperse it for 20 minutes, then add a titanate coupling agent (the weight accounts for 0.5% of the weight of the nano-zirconia) ), kept in a water bath at 100°C for 3 hours, cooled naturally, filtered with suction, dried, and the product was placed in a desiccator for subsequent use;

[0047] 2) Preparation of zirconia-polycarbonate composite particles: add the modified zirconia to deionized water, acrylic polymer compatibilizer (accounting for 2.0% of the weight of nano zirconia), hexafluoropropylene oxide oligomer type Surfactant (accounting for 0.6% of the weight of nanometer zirconia), stirred at normal temperature for 30min, the copolymer was dispersed evenly, and the temperature was raised to 60°C, ...

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Abstract

Disclosed is a composite back membrane for a solar cell, comprising a first back membrane (1), a second back membrane (2) and a third back membrane (3) successively. Adhesive layers (4) are also arranged between the first back membrane and the second back membrane and between the second back membrane and the third back membrane; and the first back membrane is adjacently connected to an ethylene-vinyl acetate copolymer adhesive membrane for a solar cell. The composite back membrane is characterized in that the first back membrane is a polytetrafluoroethylene membrane; the second back membrane is a composite membrane formed by compounding a polyethylene terephthalate membrane with fumed silica; and the third back membrane is a composite membrane composed of polycarbonate-zirconia-polytetrafluoroethylene. Also disclosed is a preparation method of the composite back membrane for a solar cell. The composite back membrane for a solar cell has a good mechanical property and a higher operating temperature; and the polarity of the surface of the composite membrane is also reduced; the adhesive force of dust is reduced; the dust deposition on the surface of the back membrane is reduced; and the service life of the back membrane is prolonged.

Description

technical field [0001] The invention relates to the technical field of solar cells, in particular to a solar cell composite back film and a preparation method thereof. Background technique [0002] Solar photovoltaic modules are mainly composed of glass cover, ethylene-vinyl acetate copolymer (EVA), cells, backplane, junction box and frame. Since the backsheet supports and protects the cells, and the backsheet is a packaging material that is in direct contact with the external natural environment on a large area, its performance directly determines the power generation efficiency and service life of the photovoltaic module. The backsheet must have excellent insulation , water vapor barrier and weather resistance, etc., so the impact of backsheet performance on solar photovoltaic modules is very important. The backplane plays a key role in battery life, output power, safety and reliability. Solar battery backsheets with poor performance will appear delamination, cracking, b...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01L31/049H01L31/18
CPCH01L31/18H01L31/049Y02E10/50Y02P70/50
Inventor 施成军张津孟晓华卢宝荣
Owner EOPLLY NEW ENERGY TECH
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