Temperature-resistant salt-tolerant viscous-oil biological viscosity reducer and preparation method thereof

A bio-viscosity reducer, temperature-resistant and salt-resistant technology, applied in chemical instruments and methods, drilling compositions, etc., can solve the problems of large catalyst damage, high development cost, difficult biodegradation, etc., to prevent pipeline scaling Corrosion, no secondary pollution, easy biodegradable effect

Active Publication Date: 2015-12-16
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, the commonly used viscosity reduction methods at home and abroad include: heating method, thin oil method and chemical agent viscosity reduction, etc., but these methods have the following problems: (1) Heating method, that is, using steam or hot fluid to heat crude oil method, this method consumes a lot of energy, has high development costs, and low construction safety; (2) the method of mixing thin oil, the source of thin oil is limited, and special pipelines are needed to transport the thin oil from the production area to the oil field to be mixed with the heavy oil, and the heavy oil Adding thin oil into the medium has a great impact on the oil quality of both heavy oil and thin oil; (3) chemical viscosity reducer, this method has low energy consumption and low cost, but the existing reported heavy oil emulsification viscosity reducer mainly Composed of non-ionic alkylphenol ether (OP) and anionic petroleum sulfonate (NP), these chemical agents contain structures such as refractory and highly toxic benzene rings, and have limited high temperature and salt resistance
[0003] According to the patent search, there are few viscosity reducers with temperature and salt resistance, the publication number is "CN1560176", the patent name is "temperature and salt resistance type thick oil viscosity reducer and its preparation method", the content of the patent invention is based on Polyoxyethylene ether acetate as the main component of the viscosity reducer, the preparation process is complex, and the production process uses organic chlorine components such as chloroacetic acid, organic chlorine is very harmful to the catalyst in the downstream refining process and has been banned in oil field development
[0004] The patent publication number is "CN1560177", and the patent title is "High-temperature heavy oil viscosity reducer and its preparation method". The patent uses N-alkyl-γ-bisquaternary ammonium cationic surfactant as the viscosity reducer. The active agent has poor salt tolerance and is difficult to biodegrade

Method used

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  • Temperature-resistant salt-tolerant viscous-oil biological viscosity reducer and preparation method thereof
  • Temperature-resistant salt-tolerant viscous-oil biological viscosity reducer and preparation method thereof
  • Temperature-resistant salt-tolerant viscous-oil biological viscosity reducer and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] A temperature-resistant and salt-resistant heavy oil biological viscosity reducer A, its composition and mass percentage components are as follows:

[0029]

[0030] The rest is water.

[0031] The yeast is Candida globosa, and the composition and components of the seed liquid medium are: glucose 300g, yeast powder 120g, KH 2 PO 4 60g, MgSO 4 ·7H 2 020g, the composition and components of the fermentation broth medium are: sucrose 1200g, peptone 400g, potassium dihydrogen phosphate 350g and potassium sulfate 50g.

[0032] A preparation method of a temperature-resistant and salt-resistant heavy oil bio-viscosity reducer A, specifically comprising the following steps:

[0033] (1) Preparation of yeast seed solution

[0034] First, clean and sterilize the 20L Erlenmeyer flask, add 10L distilled water to the sterilized Erlenmeyer flask, then add 50g yeast, 300g glucose, 120g yeast powder, 60gKH 2 PO 4 and 20gMgSO 4 ·7H 2 O, cultivated on a constant temperature sh...

Embodiment 2

[0045] A temperature-resistant and salt-resistant heavy oil biological viscosity reducer B, its composition and mass percentage components are as follows:

[0046]

[0047] The rest is water.

[0048] The yeast is Candida globosa, and the composition and components of the seed liquid medium are: glucose 480g, yeast powder 192g, KH 2 PO 4 54g, MgSO 4 ·7H 2 024g, the composition and components of the fermentation medium are: molasses 1200g, corn steep liquor 360g, dipotassium hydrogen phosphate 380g, sodium sulfate 60g.

[0049] A preparation method of a temperature-resistant and salt-resistant heavy oil bioviscosity reducer B, specifically comprising the following steps:

[0050] (1) Preparation of yeast seed solution

[0051]First, clean and sterilize the 20L Erlenmeyer flask, add 10L distilled water to the sterilized Erlenmeyer flask, then add 50g yeast, 480g glucose, 192g yeast powder, 54gKH 2 PO 4 , 24gMgSO 4 ·7H 2 O, cultivated on a constant temperature shaker ...

Embodiment 3

[0062] A temperature-resistant and salt-resistant heavy oil biological viscosity reducer C, its composition and mass percentage components are as follows:

[0063]

[0064] The rest is water.

[0065] The yeast is Candida globosa, and the composition and components of the seed liquid medium are: glucose 620g, yeast powder 250g, KH 2 PO 4 95g, MgSO 4 ·7H 2 035g, the composition and components of the fermentation broth culture medium are: oil 2000g, peptone 450g, potassium phosphate 470g, potassium phosphate 80g.

[0066] A preparation method of temperature-resistant and salt-resistant heavy oil bioviscosity reducer C, specifically comprising the following steps:

[0067] (1) Preparation of yeast seed solution

[0068] First, clean and sterilize the 20L Erlenmeyer flask, add 10L distilled water to the sterilized Erlenmeyer flask, then add 50g yeast, 620g glucose, 250g yeast powder, 95gKH 2 PO 4 and 35gMgSO 4 ·7H 2 O, cultivated on a constant temperature shaker at a t...

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Abstract

The invention discloses a temperature-resistant salt-tolerant viscous-oil biological viscosity reducer and a preparation method thereof, and belongs to the technical field of petroleum exploitation. The temperature-resistant salt-tolerant viscous-oil biological viscosity reducer is composed of microzyme, a seed liquid medium, a fermentation liquor medium and water. The microzyme is torulopsis candida. The preparation method of the viscosity reducer comprises (1) preparation of a microzyme seed liquid; (2) early-stage preparation of the fermentation liquor medium; (3) fermentation production of microzyme; (4) collection of a fermentation product; and (5) preparation of the viscous-oil biological viscosity reducer. The viscous-oil biological viscosity reducer is green and free of pollution by employing agricultural and sideline products as raw materials. The provided viscous-oil biological viscosity reducer possesses the temperature resistance up to 150 DEG C, the salt tolerance up to 2*10<5> mg / L, and the viscous-oil viscosity reduction rate up to 99% or more. The enforcement method of the viscous-oil biological viscosity reducer is simple. The viscous-oil biological viscosity reducer is substantial in effect, is capable of saving energy, reducing consumption and preventing pipelines from fouling and being corroded, and the subsequent crude-oil demulsification dewatering processing is easy. Therefore, the viscous-oil biological viscosity reducer is widely applicable to shaft elevation of a viscous oil well and ground pipeline conveying technology.

Description

technical field [0001] The invention belongs to the technical field of petroleum exploitation, and in particular relates to a temperature-resistant and salt-resistant heavy oil biological viscosity reducer and a preparation method thereof. technical background [0002] Heavy oil refers to degassed crude oil with a viscosity greater than 100mPa·S at the oil reservoir temperature. Because of its high colloidal asphaltene content and high viscosity characteristics, some technical difficulties have been encountered in various aspects of development and application. It is necessary to adopt various methods in various links of mining, transportation and refining to reduce its viscosity. At present, the commonly used viscosity reduction methods at home and abroad include: heating method, thin oil method and chemical agent viscosity reduction, etc., but these methods have the following problems: (1) Heating method, that is, using steam or hot fluid to heat crude oil method, this me...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K8/584
CPCC09K8/584
Inventor 林军章王静宋欣徐鹏王刚徐闯段传慧徐登霆冯云孙刚正张守献曹功泽
Owner CHINA PETROLEUM & CHEM CORP
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