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A kind of preparation method of mesoporous-graphene oxide/unsaturated polyester molding compound

A graphene, unsaturated technology, applied in the field of preparation of mesoporous-graphene oxide/unsaturated polyester molding compounds, can solve problems affecting the accuracy and reliability of components, failure of component systems, material wear, etc. Dimensional accuracy and heat-resistant and wear-resistant insulation performance are stable and excellent, the cross-linking density is large, and the effect of good heat resistance

Active Publication Date: 2017-12-12
GUILIN UNIVERSITY OF TECHNOLOGY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, as electrical components continue to develop in the direction of miniaturization, large capacity, multi-function, high reliability, and environmental protection and safety, there are still some deficiencies in the practical application of dry unsaturated polyester electrical plastics, especially in environments with large temperature differences and Under the action of alternating mechanical force (such as the contact bracket of the AC contactor, the switch, the action insulation structure of the thermostat, etc.), the material will be worn and deformed, which will affect the accuracy and reliability of the component action, causing components even the failure of the entire system

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0016] (1) Take each component according to the following mass percentage content:

[0017] components

Mass percentage content

Remark

Mesoporous-Graphene Oxide / Unsaturated Polyester Resin

35

1,3,5-Triallyl-s-triazine-2,4,6-trione

7

crosslinking agent

tert-butyl peroxy 2-ethylhexanoate

2.8

Hardener

Niobium Potassium Oxide KNbO 3

0.2

Accelerator

Mixed fiber of sisal microcrystalline and aramid fiber with a mass ratio of 1:1

12

enhancer

Calcium stearate

2

filler

Aluminum oxide

15

filler

Kaolin

26

filler

[0018] The mesoporous-graphene oxide / unsaturated polyester resin is composed of 4,4'-diphenyl ether dicarboxylic acid, fumaric acid, ethylene glycol, butanediol and bisphenol A diisocyanate with mesoporous-oxidized The graphene hybrid is obtained by in-situ polymerization; its main technical indicators: ①Mesoporous-graphene oxide powder content 3%...

Embodiment 2

[0021] (1) Take each component according to the following mass percentage content:

[0022] components

Mass percentage content

Remark

Mesoporous-Graphene Oxide / Unsaturated Polyester Resin

40

1,3,5-Triallyl-s-triazine-2,4,6-trione

10

crosslinking agent

tert-butyl peroxy 2-ethylhexanoate

3.6

Hardener

Niobium Potassium Oxide KNb 3 o 8

0.4

Accelerator

Mixed fiber of sisal microcrystalline and aramid fiber with a mass ratio of 1:1

15

enhancer

Calcium stearate

2

filler

Aluminum oxide

15

filler

Kaolin

14

filler

[0023] The mesoporous-graphene oxide / unsaturated polyester resin is composed of 4,4'-diphenyl ether dicarboxylic acid, fumaric acid, ethylene glycol, butanediol and bisphenol A diisocyanate with mesoporous-oxidized The graphene hybrid is obtained by in-situ polymerization; its main technical indicators: ①Mesoporous-graphene oxide powder...

Embodiment 3

[0026] (1) Take each component according to the following mass percentage content:

[0027] components

Mass percentage content

Remark

Mesoporous-Graphene Oxide / Unsaturated Polyester Resin

40

1,3,5-Triallyl-s-triazine-2,4,6-trione

10

crosslinking agent

tert-butyl peroxy 2-ethylhexanoate

3.6

Hardener

Niobium Potassium Oxide KNb 3 o 8

0.4

Accelerator

Mixed fiber of sisal microcrystalline and aramid fiber with a mass ratio of 1:1

20

enhancer

Calcium stearate + molybdenum disulfide (mass ratio 1:1)

4

filler

Aluminum oxide

15

filler

Kaolin

7

filler

[0028] The mesoporous-graphene oxide / unsaturated polyester resin is composed of 4,4'-diphenyl ether dicarboxylic acid, fumaric acid, ethylene glycol, butanediol and bisphenol A diisocyanate with mesoporous-oxidized The graphene hybrid is obtained by in-situ polymerization; its main technical indicat...

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Abstract

The invention discloses a preparation method of mesoporous-graphene oxide / unsaturated polyester molding compound. Weigh each component according to the following mass percentage content: 30~45% mesoporous-graphene oxide / unsaturated polyester resin, 6~12% crosslinking agent, 2~6% initiator, 0.1~1% Accelerator, 10-25% enhancer, 25-52% filler, the sum of the mass percentages of the above components is 100%. The mesoporous-graphene oxide / unsaturated polyester molding compound is prepared through high-speed mixing, melt kneading, extrusion granulation, sieving batch mixing, magnetic separation packaging and other processes. The mesoporous-graphene oxide / unsaturated polyester molding compound prepared by the present invention has the advantages of good molding and curing processability, complete curing, high product crosslinking density, high thermal strength, dimensional accuracy, heat-resistant and wear-resistant insulation performance, etc. Advantages, it can be used as an electrical insulation structure with high performance requirements.

Description

technical field [0001] The invention relates to a preparation method of mesoporous graphene oxide / unsaturated polyester molding compound, which belongs to the technical field of polymer composite materials. Background technique [0002] Dry unsaturated polyester molding compound is a thermosetting unsaturated polyester (UP) resin prepared by polycondensation reaction of polyol, polybasic saturated acid and unsaturated acid (anhydride), and then combined with crosslinking agent, reinforcing fiber and other Additives are blended. This type of plastic has excellent mechanical and electrical properties, insulation and heat resistance, and excellent dimensional stability. It is one of the fastest-growing types of electrical plastics in recent years and is suitable for the manufacture of complex and complex insulating structural components in electrical products. [0003] However, as electrical components continue to develop in the direction of miniaturization, large capacity, mu...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08F283/01C08K13/02C08K3/04C08K5/098C08K3/22C08K3/34C08L51/08C08L97/02C08L77/10C08G63/52C08G63/78
Inventor 韦春吕建廖帅刘庆徐旭
Owner GUILIN UNIVERSITY OF TECHNOLOGY
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