Foam graphene skeleton reinforced aluminum-base composite material and preparation method thereof
A foamed graphene and composite material technology, applied in metal material coating process, gaseous chemical plating, coating and other directions, can solve the problems of many processing steps, high cost, and difficulty in finely controlling the connectivity of three-dimensional porous skeletons. , to achieve the effects of improved electrical conductivity and mechanical strength, improved thermal and mechanical properties, and excellent continuous thermal conductivity.
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Embodiment 1
[0048] Foamed graphene skeleton reinforced aluminum-based composite material, in this example, foamed copper with a pore size of 0.3 mm is used as the substrate, and the foamed graphene reinforcement accounts for 6% of the volume fraction of the composite material. First, according to step (1), the foamed copper three-dimensional network substrate is Carry out cleaning, then adopt magnetron sputtering technology to deposit a molybdenum film with a thickness of 50 nm on the surface of the foamed copper three-dimensional network framework according to step (2) as an intermediate transition layer; then obtain a large number of nanocrystals and microns inlaid in the middle of the mesh according to step (3) A foam skeleton substrate of crystalline diamond particles; (4) using hot-wall CVD to deposit a graphene film, specifically: heating to 950°C in an atmosphere of H2 and Ar (the flow rates of H2 and Ar during the heating process are 200 and 500 mL / min, respectively) , the heating ...
Embodiment 2
[0050] Foamed graphene covers diamond skeleton reinforced aluminum matrix composite material. In this example, nickel foam with a pore diameter of 0.5 mm is used as the substrate, and the foamed graphene reinforcement accounts for 30% of the volume fraction of the composite material. The network substrate is cleaned, and then a chromium film with a thickness of 300 nm is deposited on the surface of the foamed nickel three-dimensional network skeleton by means of evaporation according to step (2) as an intermediate transition layer; then a large number of nanocrystals are inlaid in the middle of the mesh according to step (3). and microcrystalline diamond particle foam skeleton substrate; (4) use hot wire CVD to deposit diamond film, deposition process parameters: hot wire distance 6mm, substrate temperature 850 °C, hot wire temperature 2200 °C, deposition pressure 3KPa, CH4 / H2 volume The flow ratio was 1:99, and the deposition time was controlled to obtain a diamond film thickn...
Embodiment 3
[0052]Foamed graphene / carbon nanotube skeleton reinforced aluminum matrix composite material, in this example, foamed tungsten with a pore size of 1 mm is used as the substrate, and the foamed graphene reinforcement accounts for 12% of the volume fraction of the composite material. The network substrate is cleaned, without adding an intermediate transition layer afterwards, directly utilizing chemical vapor deposition to grow the graphene film in-situ; then obtain a foam skeleton substrate inlaid with a large number of nanocrystalline and microcrystalline diamond particles in the middle of the mesh according to step (3); (4) The graphene film is deposited by hot-wall CVD, specifically: heating to 950°C in an atmosphere of H2 and Ar (the flow rates of H2 and Ar are respectively 200 and 500mL / min during the heating process, and the heating rate is 33°C / min) , and heat treatment for 10 min after the furnace temperature rises to 950 °C; after the heat treatment is completed, a mixe...
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