Foamed type TPU (thermoplastic polyurethane elastomer) material and preparation method thereof

A technology of thermoplastic polyurethane and elastomer materials, which is applied in the field of foam materials, can solve problems such as inability to monitor and adjust product quality in the middle, difficulty in ensuring product quality stability between batches, and affecting the physical properties of foam materials. Achieve the effect of avoiding unstable product performance, high degree of automation and improving efficiency

Inactive Publication Date: 2016-08-24
MIRACLL CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

For the intermittent kettle pressure foaming process, the product quality inspection needs to be carried out after the production of each kettle is completed, and the central control monitoring and adjustment of product quality cannot be achieved, which will easily cause a large number of unqualified products; this process requires a very large volume. Large reactors and receiving tanks are used to meet the production capacity and receive expanded particles, and subsequent large-scale transportation, dehydration, and drying equipment are also required for post-processing, which leads to expensive equipment costs; the production time of each batch of materials is usually In 6-8 hours, there are problems such as low production efficiency; because kettle pressure foaming is a batch production process, it is difficult to ensure the stability of the quality of the final product batches, and the TPU material is soaked in high pressure for a long time during the production process. , High temperature water will lead to hydrolysis of TPU material, affecting the physical properties of subsequent foaming materials

Method used

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  • Foamed type TPU (thermoplastic polyurethane elastomer) material and preparation method thereof
  • Foamed type TPU (thermoplastic polyurethane elastomer) material and preparation method thereof
  • Foamed type TPU (thermoplastic polyurethane elastomer) material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0042] (1) Pass 100 parts by weight of polytetrahydrofuran polyol, 50 parts by weight of diphenylmethane-4,4'diisocyanate and 10 parts by weight of 1,4-butanediol through the pouring machine in a mass ratio of 100:50:10 Add it into the first reaction extruder, the aspect ratio of the first reaction extruder used is 18, the compression ratio is 2, and the temperature of the first reaction extruder screw is controlled to be 120-150°C, so that the above raw material mixture Polymerization for 10 seconds to obtain a TPU polymer melt, wherein a check valve is installed at the feeding port of the first reaction extruder;

[0043] (2) Inject 20 parts by weight of butane at the end of the first reaction extruder screw, and the TPU polymer melt is preliminarily mixed with butane;

[0044] (3) Add the initially mixed TPU polymer melt and butane into the second reaction extruder, and control the screw temperature of the second reaction extruder to be 150-120° C., and the screw speed is 1...

Embodiment 2

[0053] (1) 100 parts by weight of polybutylene adipate diol, 50 parts by weight of diphenylmethane-4,4' diisocyanate and 15 parts by weight of 1,4-butanediol in a mass ratio of 100 : The ratio of 50:15 is added in the first reaction extruder by pouring machine, and the aspect ratio of the first reaction extruder used is 40, and compression ratio is 5, and controls the first reaction extruder screw temperature to be 130-200°C; polymerize the above raw material mixture for 100 seconds to obtain a TPU polymer melt, wherein a check valve is installed at the feeding port of the first reaction extruder;

[0054] (2) Inject 25 parts by weight of carbon dioxide at the end of the first reaction extruder screw, and the TPU polymer melt and carbon dioxide are initially mixed;

[0055] (3) Add the initially mixed TPU polymer melt and carbon dioxide into the second reaction extruder, and control the screw temperature to be 150-125° C., and the screw speed to be 500 rpm, so that the carbon ...

Embodiment 3

[0062] (1) 100 parts by weight of bio-based poly-1,3-propylene glycol, 45 parts by weight of diphenylmethane-4,4'diisocyanate and 30 parts by weight of 1,4-butanediol in a mass ratio of 100:45 The ratio of :30 is added in the first reaction extruder by pouring machine, and the aspect ratio of the first reaction extruder used is 25, and compression ratio is 2.5, and the first reaction extruder screw temperature of control is 90- 220 ° C, the above-mentioned raw material mixture is polymerized for 150 seconds to obtain a TPU polymer melt, wherein a check valve is installed at the feeding port of the first reaction extruder;

[0063] (2) Inject 25 parts by weight of nitrogen at the end of the first reaction extruder screw, and the TPU polymer melt is initially mixed with nitrogen;

[0064] (3) Add the preliminarily mixed TPU polymer melt and nitrogen into the second reaction extruder, and control the screw temperature to 150-120°C, and the screw speed to 150rpm, so that the nitro...

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Abstract

The invention relates to a foamed type TPU (thermoplastic polyurethane elastomer) material and a preparation method thereof. The preparation method comprises the following steps: polymer polyol, diisocyanate and a chain extender are taken and poured into a casting machine to be mixed uniformly, then a mixture I is added to a first reactive extrusion machine for a polymerization reaction, and a TPU polymer melt is obtained; a physical foaming agent is injected into the tail end of a screw of the first reactive extrusion machine, the TPU polymer melt is mixed preliminarily with the physical foaming agent, and a mixture II is obtained; the mixture II is added to a second reactive extrusion machine, and the physical foaming agent and the TPU polymer melt are mixed uniformly to form a homogeneous system; the homogeneous system passes through a neck ring mold of the second reactive extrusion machine and then is subjected to underwater palletizing, and foamed thermoplastic polyurethane particles are obtained; the foamed thermoplastic polyurethane particles are dehydrated and dried, and the foamed type TPU material is obtained. The foamed type TPU material has stable foaming density, the batch-to-batch product quality is stable, central control monitoring is performed at any time, and the yield is increased.

Description

technical field [0001] The invention relates to a foaming thermoplastic polyurethane elastomer material and a preparation method thereof, belonging to the field of foaming materials. Background technique [0002] Using plastic as a matrix, a large number of air bubbles are filled inside the plastic by physical or chemical methods to obtain a polymer foam material. Foam materials have a series of advantages such as low density, heat and sound insulation, high specific strength, and cushioning, so they are widely used in packaging, industry, agriculture, transportation, military industry, aerospace industry, and daily necessities. Commonly used types of foam are polyurethane (PU) soft and rigid foam, polystyrene (PS) foam, polyethylene (PE) foam, polypropylene (PP) foam, etc. However, isocyanate is likely to remain in the foaming process of polyurethane foam, which is harmful to the human body, and the foamed material cannot be recycled. Polystyrene foam products are difficu...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G18/66C08G18/48C08G18/42C08G18/44C08G18/32C08J9/12C08J9/14
CPCC08G18/3206C08G18/4238C08G18/4825C08G18/4854C08G18/664C08G18/6674C08J9/122C08J9/141C08J2203/06C08J2203/14C08J2205/044C08J2375/06C08J2375/08C08G2110/0058C08G2110/0066
Inventor 王光阜孙其军战振生宋红玮王仁鸿
Owner MIRACLL CHEM
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