Method for preparing cobaltous selenide super-capacitor material through chemical vapor deposition method

Abstract

The invention discloses a method for preparing a Co0.85Se super-capacitor material through a chemical vapor deposition method, wherein the Co0.85Se super-capacitor material is a nano film-shaped structure covering a nickel mesh. The specific growth process comprises the following steps: 1), grinding and mixing selenium powder and cobalt powder, putting the mixture of selenium powder and cobalt powder into a quartz boat, and putting the quartz boat into a chemical vapor deposition reacting furnace quartz tube; 2), enabling a foamed nickel mesh to be placed at a position, close to the mouth of the quartz tube, of a downstream side of an air flow; 3), letting in argon gas, exhausting the air in the furnace, stopping the supply of the gas, carrying out heating for some time, and then letting a certain amount of argon gas in the quartz tube for heat preservation, and finally cooling the furnace to the room temperature naturally; 4), taking out foamed nickel, repeatedly washing the foamed nickel through deionized water and ethyl alcohol, drying the foamed nickel, and obtaining the material. The method is simple in operation and does not need complex equipment, and the Co0.85Se uniformly covers the nickel mesh. The material can be prepared in a large area. A composite Co0.85Se nano material electrode is tested in a three-electrode system, presents a high specific capacity of 4462F / g under the current density of 1A / g, and still can maintain 80% or more of the specific capacitance value after 5000-time circulating charging and discharging under a high current of 20A / g, wherein the charge transfer impedance is 0.82 ohm / cm<2>.

Description

technical field [0001] The invention relates to supercapacitor electrode materials, in particular to the field of electrode materials for nanostructured selenide supercapacitors. Background technique [0002] Energy is the basis for the survival and development of human society. With the advancement of science and technology, the development of social economy and the continuous improvement of living standards, human beings have an increasing demand for energy. Since the beginning of the new century, with the continuous consumption of non-renewable energy such as oil, natural gas and coal, the contradiction between economic development and energy supply has obviously intensified, and environmental problems such as the greenhouse effect caused by the burning of fossil fuels have become increasingly prominent. In order to improve To improve the ecological environment and realize the sustainable development of society, the focus of the energy supply structure of human society w...

AI Technical Summary

Problems solved by technology

At present, supercapacitor electrode materials mainly include carbon materials, conductive polymers, oxides, sulfides, etc., but these materials have their own shortcomings, such as low specific capacitance of carbon materials, poor cycle stability of conductive polymers, high resistivity of oxides, Sulfide also has the disadvantage of high resistivity, so finding a supercapacitor electrode material with high specific capacitance, low resistivity and good cycle stability has become the goal of research and industrialization.

[0004] Selenide is a potential supercapacitor material. At present, the research and development of selenide for supercapacitor electrode materials is still very rare, and there are few reports

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