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Polyurethane foam with synergistically enhanced antibacterial effect

A polyurethane foam, diisocyanate technology, applied in the direction of polyurea/polyurethane adhesives, adhesives, adhesive types, etc., can solve the problems of inability to meet safety, low production efficiency, poor heat resistance, etc. The effect of good thermal insulation, extended service life, excellent antibacterial effect

Inactive Publication Date: 2016-12-14
HEFEI E CHON METAL PLATE TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The traditional sealing process is to use the physical bonding method to bond the standard seal to the sealing position. This method has many defects such as low production efficiency, poor reliability, and unsightly appearance.
[0003] In the article "Preparation of Foaming Two-Component Polyurethane Adhesive", trihydroxypolyoxypropylene ether, castor oil and diphenylmethane diisocyanate are used as the main raw materials, glycerol is used as the chain extender, and water is used as the foaming agent. , through a suitable proportion, a foaming two-component polyurethane adhesive was synthesized by pre-polymerization method. The foamed adhesive foam was uniform and delicate, with high tensile and shear strength and excellent comprehensive performance. , but its heat resistance is poor and it is easy to burn. When it is used as the seal of a switch cabinet or a cabinet, it cannot meet the safety of use. This requires strengthening and modifying its thermal stability to improve its flame retardant performance.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment Construction

[0014] A polyurethane foam that synergistically enhances the antibacterial effect, made of the following raw materials in parts by weight (kg): 150 diphenylmethane diisocyanate, 100 trihydroxypolyoxypropylene ether, 100 castor oil, 5 glycerol, phosphoric acid Diethyl ester 40, 1mol / L sodium hydroxide solution, diatomaceous earth 13, distilled water 5, triethanolamine 2, dibutyltin dilaurate 3, TX-102.5, carboxymethyl cellulose 3, sulfonamide 4, sulfadiazine Silver 3, anatase nano titanium dioxide 8, appropriate amount of deionized water.

[0015] Described a kind of polyurethane styrofoam that synergistically strengthens antibacterial effect is made by following specific steps:

[0016] (1) Pour trihydroxypolypropylene oxide ether, castor oil and glycerin into the reaction kettle, heat it in a constant temperature water bath to 85°C, stir and react at a speed of 150 rpm for 60 minutes, then cool down to 40°C, slowly drop Add diethyl phosphate, add it within 30 minutes, drop i...

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PUM

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Abstract

The invention discloses polyurethane foam with a synergistically enhanced antibacterial effect. The polyurethane foam is prepared from, by weight, 150-160 parts of diphenylmethane diisocyanate, 100-105 parts of propoxylated glycerin, 100-110 parts of castor oil, 5-6 parts of glycerin, 40-43 parts of diethyl phosphate, appropriate amount of 1mol / L sodium hydroxide solution, 13-15 parts of diatomite, 5-6 parts of distilled water, 2-3 parts of triethanolamine, 3-4 parts of dibutyltin dilaurate, 2.5-3.5 parts of TX-10, 3-4 parts of carboxymethyl cellulose, 4-5 parts of sulfanilamide, 3-4 parts of silver sulfadiazine, 8-10 parts of anatase nano titania and appropriate amount of deionized water. The polyurethane foam is low in cost, simple in preparation process, available for onsite foaming and excellent in sealing effect on switch cabinets and has antibacterial and bactericidal effects, remarkable antibacterial effects can be kept for a long time even in a humid environment, and the service life of seal glue is prolonged.

Description

technical field [0001] The invention relates to the technical field of styrofoam, in particular to a polyurethane styrofoam synergistically enhancing the antibacterial effect. Background technique [0002] Two-component polyurethane adhesive is the most important type of polyurethane adhesive, usually composed of A component (main agent) and B component (curing agent), where A component is a hydroxyl component, B component For components containing free isocyanate groups, the two are packaged separately and can be formulated and used in a certain proportion. In our country, the research on foaming two-component polyurethane adhesives began in 1995 and was gradually put into use in the late 1990s. The foaming two-component polyurethane adhesive has the characteristics of porosity, low relative density, and high specific strength. According to different raw materials and formulas, it can be made into ordinary soft foam, hard foam, high-resilience foam and slow-rebound foam. ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J175/08C09J175/14C09J11/04C09J11/08C09J11/06C08G18/67C08G18/66C08G18/48C08G18/32C08G18/16C08G18/18C08G18/24C08J9/08C08G101/00
CPCC08G18/165C08G18/1825C08G18/246C08G18/3206C08G18/36C08G18/4829C08G18/6696C08G2101/00C08G2170/60C08G2190/00C08K2201/011C08L2201/02C08L2203/14C09J11/04C09J11/06C09J11/08C09J175/08C08L1/286C08K13/04C08K7/26C08K2003/2241C08K5/43C08K5/521
Inventor 陆厚平
Owner HEFEI E CHON METAL PLATE TECH CO LTD
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