Epoxy grafted graphene finish paint for new energy automobile and preparation method of epoxy grafted graphene finish paint

A new energy vehicle, grafted graphite technology, applied in the field of new energy vehicle epoxy grafted graphene topcoat and its preparation, can solve the problem of not being exposed to outdoor use, unstable benzene ring of epoxy resin, and many times of coating and other issues, to achieve excellent outdoor durability, not easy to fall off, and strong scratch resistance

Inactive Publication Date: 2017-05-10
SHENZHEN GOVE CHEM & MATERIAL
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] General automotive paint has the functions of protection and beautiful decoration, such as high gloss, high weather resistance, gorgeous decoration, strong corrosion resistance, long-term color retention, mechanical collision resistance, scratch resistance, gasoline, engine oil resistance, acid rain resistance, Bird droppings, etc. Most of the current car paints use epoxy topcoats. The existing epoxy topcoats generally have poor weather resistance and cannot be exposed to the outdoors. They can only be used as primers. Long time and high cost
These deficiencies are due to the fact that epoxy resin contains unstable benzene rings, and the double bond breaks under the irradiation of ultraviolet rays to cause pulverization. When painting, it needs to be sprayed with a matching weather-resistant topcoat, which requires at least two constructions, and each time It takes a certain amount of time for the paint to dry;

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] A new energy vehicle epoxy grafted graphene topcoat, which is composed of components A and B with a mass ratio of 12:1;

[0022] Described A component is made up of the raw material of following parts by weight:

[0023] Graphene 14, bisphenol A epoxy resin 120, dicyclohexyl carbodiimide 0.3, acetyl tributyl citrate 4, trimethylolpropane 0.4, 8-hydroxyquinoline copper 0.6, alkenyl succinic anhydride 1, Benzotriazole 0.5, tribasic lead sulfate 0.2, calcium stearate 3, fumed silica 3, copper naphthenate 0.1, sodium alkylbenzene sulfonate 0.8, phthalate 1;

[0024] The B component is composed of 4,4'-diaminodiphenylmethane and polyethylene glycol in a mass ratio of 110:1.

[0025] A kind of preparation method of epoxy grafted graphene topcoat of new energy automobile, the preparation method of described A component comprises the following steps:

[0026] (1) adding the above graphene to a mixed solution of sulfuric acid and nitric acid with a mass ratio of 110 times its ...

Embodiment 2

[0041] A new energy vehicle epoxy grafted graphene topcoat, which is composed of components A and B with a mass ratio of 10-12:1;

[0042] Described A component is made up of the raw material of following parts by weight:

[0043] Graphene 14, bisphenol A epoxy resin 110, dicyclohexyl carbodiimide 0.3, acetyl tributyl citrate 3, trimethylolpropane 0.7, 8-hydroxyquinoline copper 0.8, alkenyl succinic anhydride 2, Benzotriazole 0.8, tribasic lead sulfate 0.1, calcium stearate 2, fumed silica 3, copper naphthenate 0.1, sodium alkylbenzene sulfonate 0.8, phthalate 1;

[0044] The B component is composed of 4,4'-diaminodiphenylmethane and polyethylene glycol in a mass ratio of 110:1.

[0045] A kind of preparation method of epoxy grafted graphene topcoat of new energy automobile, the preparation method of described A component comprises the following steps:

[0046](1) Add the above graphene to a mixed solution of sulfuric acid and nitric acid with a mass ratio of 110 times its w...

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PUM

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Abstract

The invention discloses epoxy grafted graphene finish paint for a new energy automobile. The epoxy grafted graphene finish paint is prepared from an ingredient A and an ingredient B according to a mass ratio of (10 to 12):1. Firstly, graphene is subjected to acidification treatment in concentrated nitric acid; then, formed carboxyl is subjected to acylating chlorination by thionyl chloride, and then takes an acylation reaction with ethylene glycol, so that hydroxy is introduced on a graphene surface; next, stearic acid is grafted by using dimethyl formamide as a solvent; a grafting matter capable of being effectively dispersed among epoxy resin is obtained. The epoxy finish paint has good corrosion resistance, excellent outdoor durability and high adhesive force; the surface hardness of the finish paint is good; the scratch resistance performance is high; the stability is good; the falling cannot easily occur; the comprehensive performance is excellent.

Description

technical field [0001] The invention belongs to the field of energy automobile topcoats, and in particular relates to an epoxy-grafted graphene topcoat for new energy automobiles and a preparation method thereof. Background technique [0002] General automotive paint has the functions of protection and beautiful decoration, such as high gloss, high weather resistance, gorgeous decoration, strong corrosion resistance, long-term color retention, mechanical collision resistance, scratch resistance, gasoline, engine oil resistance, acid rain resistance, Bird droppings, etc. Most of the current car paints use epoxy topcoats. The existing epoxy topcoats generally have poor weather resistance and cannot be exposed to the outdoors. They can only be used as primers. Long time and high cost. These deficiencies are due to the fact that epoxy resin contains unstable benzene rings, and the double bond breaks under the irradiation of ultraviolet rays to cause pulverization. When painting...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D163/00C09D5/08C09D7/12
CPCC09D5/08C09D7/62C09D7/63C09D7/65C09D163/00C08L71/02C08K13/06C08K9/02C08K9/04C08K5/11C08K3/04C08K3/36C08K5/098
Inventor 向红先
Owner SHENZHEN GOVE CHEM & MATERIAL
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