Visible light catalysis hollow fiber ultrafiltration membrane based on doped nano ZnO and preparation method

Abstract

The invention discloses a visible light catalysis hollow fiber ultrafiltration membrane based on doped nano ZnO and a preparation method and belongs to the technical field of membrane separation. 10.0%-25.0% (w / w) of polysulfone or polyether sulfone, 8.0%-17.0% (w / w) of pore-foaming agent, 0.1%-2.0% (w / w) of surfactant, 0.1%-5.0% (w / w) of doped nano ZnO and 51.0%-81.8% (w / w) of solvent are added into a dissolution tank according to a certain sequence, the materials are stirred and dissolved for 5-16 hours at the temperature of 35-95 DEG C till being completely dissolved, standing for defoaming is carried out for 8-36 hours, and a membrane casting solution is prepared; the visible light catalysis hollow fiber ultrafiltration membrane is prepared through a traditional dry-wet spinning process. The pure water flux of the prepared ultrafiltration membrane is larger than or equal to 300 L / m<2>.hr.0.1 MPa, the bovine serum albumin reject rate is larger than or equal to 90.00%, the fulvic acid degradation removal rate is larger than or equal to 65% (operation is carried out for 1 hour under simulated visible light), and good anti-contamination performance and visible light catalysis performance are achieved. The product is especially suitable for micro-polluted source water deep treatment, seawater desalination pretreatment and deep treatment, reuse and the like of waste water in the fields of biochemical engineering and medicine.

Description

technical field [0001] The invention relates to a polymer mixed matrix ultrafiltration membrane and a preparation method thereof, in particular to a visible light catalytic hollow fiber ultrafiltration membrane based on doped nano ZnO and a preparation method thereof. Background technique [0002] The scarcity of water resources and increasingly serious water pollution have become bottlenecks restricting social progress and economic development. The development of new water sources and the utilization of waste water resources have also become issues of global concern. Due to the extremely rich water resources in Shanghai and the large amount of waste water generated, the recycling of sewage and seawater desalination have become strategic choices to solve the water resource crisis. Among many sewage resource technologies, membrane separation technology is one of the best choices. [0003] Mixed matrix membrane, also known as hybrid membrane, is a membrane formed by chemical ...

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Problems solved by technology

[0004] Chinese patent CN104383821A uses graphene oxide to support magnetic particles with a core-shell structure @TiO 2 The modified separation membrane was prepared, and it was considered that the separation membrane showed good photocatalytic degradation performance and anti-protein pollution performance for the target pollutant bovine serum albumin, but the separation performance and visible light catalytic degradation performance of the prepared membrane were not clarified in the patent application advantages and disadvantages, and the preparation process of the separation membrane is complicated; at the same time, the magnetic particles @TiO 2 The preparation method is complicated and the cost is high

Chinese patent CN102989329A passed AgNO 3 、TiO 2 Blending modification to prepare ultrafiltration membranes, in fact, mainly uses AgNO 3 Visible light catalytic activity, and the degradation rate is relatively slow (in the patent, the degradation rate of methylene blue is characterized by light for 10 hours), and it is impossible to prepare a separation membrane for separation and visible light catalysis at the same time; 3 PO 4 / TiO 2 Complex (Ag 3 PO 4 Nanoparticle deposition onto TiO 2 Surface) and polyvinylidene fluoride materials are blended and modified, so that the modified film has visible light catalytic antibacterial and antifouling properties, mainly using the deposited on TiO 2 Ag on the surface 3 PO 4 Particles degrade the organic matter adsorbed during the application of the separation membrane to reduce membrane fouling, and have not been used to prepare a separation membrane with both separation and visible light catalytic properties; at the same time, neither of these two patents has a synergistic effect to make full use of silver salts and TiO 2 The catalytic performance of silver salt or silver salt and TiO is only utilized by blending or deposition 2 Respective catalytic activity, visible light catalytic efficiency is low

[0006] The present invention uses doped nano-ZnO to improve the photocatalytic properties of polymer ultrafiltration membranes, and prepares hollow fiber mixed matrix ultrafiltration membranes with visible light catalytic activity. There is no similar production of visible light catalytic hollow fiber ultrafiltration membrane products in China so far. There is no relevant literature report at home and abroad