Superhydrophobic coating spray for material surface protection and preparation and use methods thereof

A technology of super-hydrophobic coating and hydrophobic agent, applied in the direction of coating, can solve the problems of weak adhesion of super-hydrophobic coating, short protection time, complicated preparation process, etc., and achieve low cost of materials and preparation equipment and suitable temperature range. The effect of wide and simple preparation process

Inactive Publication Date: 2017-05-31
LANZHOU JIAOTONG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] Patents with publication numbers CN101734945, CN103923561, CN104231916A, CN102795786A, and CN104650725 use organosilicon, surface-modified nanoparticles, graphene, etc. to prepare protective agents. Short time, limited practicality when applied to engineering
[0007] However, these existing methods more or less have the following problems: (1) use expensive materials (such as fluoropolymers with a very low surface) or equipment, which have high cost and low practical value; Toxic solvents (such as toluene, xylene, etc.) are not conducive to construction and environmental protection app

Method used

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  • Superhydrophobic coating spray for material surface protection and preparation and use methods thereof
  • Superhydrophobic coating spray for material surface protection and preparation and use methods thereof

Examples

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Effect test

Embodiment 1

[0038] A superhydrophobic coating spray for aluminum surface protection and its preparation and use method, the material is composed of nano-alumina with a particle size of 30nm, talcum powder of 8μm, methyltriethoxysilane and acetone, and its preparation The process and method are as follows:

[0039] Add 0.3 parts of nano-alumina and 0.3 parts of talc powder in a weight ratio to 84.4 parts of acetone, ultrasonically treat for 8 minutes, and then disperse with a high-speed homogenizer for 10 minutes. Then, the pH was adjusted to 5 with nitric acid, and 15 parts of methyltriethoxysilane was added dropwise at a constant speed under magnetic stirring, and the dropping time was controlled at 20 minutes, followed by reaction under ultrasonic for 2 hours to prepare a superhydrophobic coating spray.

[0040]The prepared superhydrophobic spray was used to protect the surface of 6063 aluminum alloy plate. Before spraying the protective agent, first clean the surface of the aluminum a...

Embodiment 2

[0042] A super-hydrophobic coating spray for concrete surface protection and its preparation and use method. The material is composed of nano-silica with a particle size of 60nm, talcum powder with a particle size of 12μm, octadecyltrimethoxysilane and ethanol. The preparation process and method are as follows:

[0043] Add 0.5 parts of nano-silica and 0.2 parts of talc powder into 87.3 parts of ethanol, ultrasonically treat for 10 minutes, and then disperse with a high-speed homogenizer for 8 minutes. Then, adjust the pH to 6 with nitric acid, add 12 parts of octadecyltrimethoxysilane dropwise at a constant speed under magnetic stirring, and the dropping time is controlled at 25 minutes, and then react for 2 hours under ultrasonic to prepare a superhydrophobic coating spray .

[0044] The surface of C25 concrete was protected with the prepared superhydrophobic spray. Before spraying the protective agent, clean the slag and floating dust on the concrete surface with a brush,...

Embodiment 3

[0046] A superhydrophobic coating spray for glass surface protection and its preparation and use method. The material is composed of nano-titanium dioxide, sodium methyl silicate and tetrahydrofuran with a particle size of 30nm. The preparation process and method are as follows:

[0047] Add 0.4 parts by weight of nano-titanium dioxide into 89.6 parts of tetrahydrofuran, ultrasonicate for 5 minutes, and then disperse with a high-speed homogenizer for 6 minutes. Then, use sodium hydroxide solution to adjust the pH to 7.5, and under magnetic stirring, add 10 parts of sodium methyl silicate dropwise at a constant speed, and the dropping time is controlled at 16 minutes, and then react for 3 hours under ultrasonic to prepare a superhydrophobic coating spray .

[0048] The glass surface was treated with the prepared superhydrophobic spray. Before spraying the protective agent, first clean the glass surface with tap water and dry it, and then spray superhydrophobic spray, the nozzl...

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Abstract

The invention provides a superhydrophobic coating spray for material and facility surface protection and preparation and use methods thereof. The superhydrophobic coating spray is low-viscosity liquid, and is prepared from nanometer structure and micrometer structure particles and hydrophobic substances through a chemical reaction; a layer of superhydrophobic film can be formed on the surface of a base material to be protected through a spray coating process; the film has a micrometer-nanometer composite dual structure similar to the surface of a lotus leaf; the contact angle with water is not smaller than 150 degrees; the rolling angle is smaller than 10 degrees; good hydrophobic performance is realized. The superhydrophobic coating spray provided by the invention has the advantages that the cost is low; the materials and the process achieve the environment-friendly effects; the manufacturing and the spray coating processes are simple and convenient; the limitation by the base material or the facility shape is avoided; the industrialization can be easily realized; the protection effect durability is good. The superhydrophobic coating spray can be widely applied to the hydrophobic protection of the material base material surfaces of concrete, metal, glass and the like, so that the excellent hydrophobic effect can be shown on the surface of the base material; meanwhile, the functions of self-cleaning pollution resistance, the anti-corrosion function, the ice and frost condensing inhibiting function and the like can also be realized.

Description

technical field [0001] The invention relates to the surface hydrophobization protection of concrete, metal, glass, stone, textiles, plastics, wood and other material substrates, and its application scope is transportation facilities, buildings, vehicles, fabrics and the like. Specifically, it relates to a super-hydrophobic coating spray for surface protection of materials and facilities, and a preparation and use method thereof. Background technique [0002] Under the action of physical or chemical factors such as atmosphere, sunlight, acid rain, salt spray, high and low temperature, facilities made of concrete, metal, glass, stone, textiles, plastic, wood and other materials will have various problems during use. For example, the metal surface will be corroded and rusted, concrete and stone are easily corroded by moisture, high and low temperature changes, and alkali and acid, and will be weathered and cracked, glass surfaces will be fogged and frosted, textile surfaces wil...

Claims

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Application Information

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IPC IPC(8): C09D7/00C09D7/14C09D7/12C09D7/80
CPCC09D7/00C09D7/61C09D7/67C09D7/80
Inventor 冯利邦刘馨刘艳花史雪婷强小虎王彦平
Owner LANZHOU JIAOTONG UNIV
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