Active iron carbon catalyst for treating industrial wastewater

A carbon catalyst, industrial wastewater technology, applied in physical/chemical process catalysts, water/sewage treatment, water/sludge/sewage treatment, etc., can solve the problems of high cost, unfavorable electrolytic packing backwash, hardening, etc., to prevent The iron material is rusted and hardened, it is not easy to form channeling and passivation, and the effect of improving the specific surface area

Active Publication Date: 2017-11-17
杨昆
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] The electrolytic filler (also known as catalyst) in the iron-carbon micro-electrolysis technology mostly adopts a fixed iron-carbon bed, but because the iron particles in the iron-carbon bed are not evenly dispersed, the iron particles are prone to rust and harden, which makes it easy to rust during use. Hardening is easy to occur in the medium, which will not only cause the interruption of the micro-electrolysis process and affect the treatment effect, but also frequently replace the micro-electrolysis materials, which will result in heavy workload and high cost, and reduce the treatment efficien

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] Embodiment 1, the active iron-carbon catalyst of the present invention is used for the pretreatment of industrial printing and dyeing wastewater, and the active iron-carbon catalyst is composed of 50wt% iron-titanium alloy powder, 30wt% active fiber carbon powder, 7wt% aluminum alum Soil, 4wt% Guangdong black mud, 4wt% Pingxiang white mud, 2% wt% tin oxide powder and 3% plastic powder, and prepared as follows:

[0023] A. Firstly oxidize iron and titanium oxide to make iron-titanium alloy according to the mass ratio of 4:0.5. Ferro-titanium alloy powder above 80 mesh, activated fiber carbon powder above 80 mesh, bauxite, Guangdong black mud, Pingxiang white mud , tin oxide powder and plastic powder are mixed and stirred in proportion to make a mixture,

[0024] B. Add urea-formaldehyde of 1% of the weight of the mixture and an appropriate amount of water polo to the mixture to make mud.

[0025] C. Input the mud into the pellet machine, pelletize into a spherical green...

Embodiment 2

[0029] Embodiment 2, the active iron-carbon catalyst of the present invention is used for the pretreatment of coking waste water, and described active iron-carbon catalyst is made of 40wt% iron-titanium alloy powder, 40wt% activated fiber carbon powder, 10wt% bauxite , 3wt% Guangdong black mud, 3wt% Pingxiang white mud, 2% wt% tin oxide powder and 2% industrial rice flour, and are prepared as follows:

[0030] A. Firstly oxidize iron and titanium oxide to make ferro-titanium alloy according to the mass ratio of 4:1. Ferro-titanium alloy powder above 80 mesh, activated fiber carbon powder above 80 mesh, bauxite, Guangdong black mud, Pingxiang white mud , tin oxide and industrial rice flour are mixed and stirred in proportion to make a mixture,

[0031] B. Add urea-formaldehyde of 2% of the weight of the mixture and an appropriate amount of water polo to the mixture to make mud.

[0032] C. Input the mud into the pellet machine, pelletize into a spherical green body of φ3~φ20 mm,...

Embodiment 3

[0036] Embodiment 3, the active iron-carbon catalyst of the present invention is used for the pretreatment of pharmaceutical waste water, and described active iron-carbon catalyst is made of 60wt% iron-titanium alloy powder, 20wt% active fiber carbon powder, 5wt% bauxite , 5wt% Guangdong black mud, 4wt% Pingxiang white mud, 1% wt% tin oxide powder and 5% sawdust, and are prepared as follows:

[0037] A. Firstly oxidize iron and titanium oxide to make iron-titanium alloy according to the mass ratio of 5:1. Ferro-titanium alloy powder above 80 mesh, activated fiber carbon powder above 80 mesh, bauxite, Guangdong black mud, Pingxiang white mud Tin oxide powder and sawdust are mixed and stirred in proportion to make a mixture,

[0038] B. Add urea-formaldehyde of 1% of the weight of the mixture and an appropriate amount of water polo to the mixture to make mud.

[0039] C. Input the mud into the pellet machine, pelletize into a spherical green body of φ3~φ20 mm, and dry the pelle...

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PUM

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Abstract

The invention discloses an active iron carbon catalyst for treating industrial wastewater. The active iron carbon catalyst is prepared from 40 wt%-60 wt% of iron-titanium alloy powder, 20 wt%-40 wt% of active fiber carbon powder, 5 wt%-10 wt% of bauxite, 3 wt%-5 wt% of Guangdong black clay, 3 wt%-5 wt% of Pingxiang white clay, 1 wt%-2 wt% of tin oxide powder and 2%-3% of a pore forming agent. The active iron carbon catalyst is roasted at the high temperature, iron and carbon are fused together, the inside of the catalyst is of a honeycomb netty-hole structure, the catalyst has the high specific area and gap rate, it can be effectively avoided that the catalyst is hardened and passivated, wastewater is rapidly sucked through honeycomb netty holes inside the catalyst, the reacting efficiency is improved, micro currents are formed through the iron-carbon electric potential difference generated through microelectrolysis to excite industrial wastewater, and new ecological hydrogen and oxygen are generated; through the reducibility and the oxidability of hydrogen and oxygen, wastewater is subjected to a strong oxidation-reduction reaction, and therefore hardly degradable substances are converted into easily degradable substances.

Description

technical field [0001] The invention relates to water treatment, in particular to an active iron-carbon catalyst for industrial waste water pretreatment. Background technique [0002] As we all know, industrial metallurgy, coking, electroplating, papermaking, medicine, printing and dyeing and other industries will produce a large amount of organic industrial wastewater. These organic industrial wastewater is a kind of high-concentration refractory polymer organic industrial wastewater. It is a refractory product with poor biodegradability and high toxicity. In order to make the final discharge of organic industrial wastewater meet the national standards and ensure that the environment is not polluted, the organic industrial wastewater must be pretreated first to remove COD, NH3-N macromolecular harmful substances such as phenol, cyanide, oil, etc. The pressure of subsequent advanced treatment. At present, the treatment methods of organic industrial wastewater include physi...

Claims

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Application Information

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IPC IPC(8): B01J23/835C02F1/461C02F1/467
Inventor 杨昆杨新军杨剑
Owner 杨昆
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