Method for preparing melamine resin finishing agent

A technology of melamine resin and finishing agent, which is applied in microsphere preparation, microcapsule preparation, fiber treatment and other directions, can solve the problems of short fragrance retention time, low fragrance encapsulation rate, low mechanical strength of capsule wall, etc. The effect of simplifying the finishing process

Inactive Publication Date: 2018-05-29
贺州宝兴新材料股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Traditional microcapsule technology usually uses physical methods to prepare various open-cell flavor microcapsules, and then uses adhesives and crosslinking agents to mechanically adhere the microcapsules to fabric fibers, and the fragrance retention time is not long; at the same time Due to the existence of the adhesive, the hand feeling is not good, which affects the comfort when wearing
[0004] However, the fragrance microcapsules sold on the market today often have disadvantages such as low packaging rate of fragrance, low mechanical strength of the capsule wall, short fragrance retention time, low affinity with fabric fibers, and difficult bonding.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0034] (3) Preparation of melamine resin prepolymer

[0035] Put 5-10 parts of melamine and 10-20 parts of 37% formaldehyde solution into a four-necked bottle in parts by weight, heat up to 60-80°C under stirring conditions, and add 0.1-1 part of triethanolamine after the melamine is completely dissolved, Adjust the pH to 7-10, and react for 10-30 minutes to obtain a transparent and viscous melamine resin prepolymer;

[0036] (4) Preparation of self-adhesive double-wall essence microcapsules

[0037] By weight, 10-30 parts of essence, 2-5 parts of methyl methacrylate, 2-5 parts of acrylonitrile, 1-3 parts of butyl acrylate, 1-3 parts of isooctyl acrylate, 0.2-0.5 parts of methyl Acrylic acid, 0.2-0.5 parts of hydroxyethyl acrylate, 0.1-0.3 parts of diacetone acrylamide, 0.1-0.3 parts of adipic acid dihydrazide, and 0.02-0.05 parts of azobisisobutyronitrile are placed in a beaker at a temperature of 30 Stir and mix at -50°C to form a homogeneous oil solution;

[0038] Mix th...

Embodiment 1

[0045] (1) Preparation of styrene-maleic anhydride copolymer powder

[0046] Under the condition of nitrogen protection, add monomer maleic anhydride and initiator into the medium to fully dissolve, then add monomer styrene to dissolve in the system, and react at 50°C for 0.5h to obtain high molecular weight styrene and horse The dispersion system of maleic anhydride polymer microspheres is centrifuged and vacuum-dried to obtain a white solid of alternating copolymers of high molecular weight styrene and maleic anhydride;

[0047] Wherein, the initiator is an organic peroxide or an azo compound; the medium is an organic acid alkyl ester, or a mixed solution of a ketone and an alkane;

[0048] The consumption relation of maleic anhydride and styrene, molar ratio is 5: 1, and the mass concentration sum of two kinds of monomer maleic anhydride and styrene in the reaction system is 15%; In the reaction system, the mass concentration of initiator is 0 %; The volume fraction of ket...

Embodiment 2

[0061] (1) Preparation of styrene-maleic anhydride copolymer powder

[0062] Under the condition of nitrogen protection, add monomer maleic anhydride and initiator into the medium to fully dissolve, then add monomer styrene to dissolve in the system, and react at 90°C for 72h to obtain high molecular weight styrene and maleic acid The dispersion system of acid anhydride polymer microspheres is centrifuged and vacuum-dried to obtain a white solid of alternating copolymer of high molecular weight styrene and maleic anhydride;

[0063] Wherein, the initiator is an organic peroxide or an azo compound; the medium is an organic acid alkyl ester, or a mixed solution of a ketone and an alkane;

[0064] The consumption relation of maleic anhydride and styrene is 1: 5 by molar ratio, and the mass concentration sum of two kinds of monomer maleic anhydride and styrene is 43% in the reaction system; The mass concentration of initiator is 0.4 in the reaction system %; The volume fraction o...

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PUM

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Abstract

The invention discloses a method for preparing a melamine resin finishing agent. The method comprises respectively carrying out encapsulation on essence as a capsule core through melamine resin and polyacrylate as shell materials and a styrene-maleic anhydride copolymer as an emulsifier through an in-situ polymerization method and an interfacial polymerization method. The method can prepare self-adhesive double-walled essence microcapsules with solid content of 35% to 38%, which is 10% to 15% higher than those of other solid microcapsules on the market, through safe and eco-friendly processes.Through the in-situ polymerization method and the interfacial polymerization method, double-layer wall building is realized and the essence encapsulation rate is 91-95%. The product emulsion has goodstability. The self-adhesive double-walled essence microcapsules have self-adhesive properties while maintaining the unique advantages of microcapsules and simplify the finishing process of cotton fabrics. The finished cotton fabric has a good fragrance retention effect, can be stood for 8 months for fragrance retention and can still maintain the pleasant fragrance after being washed 12 times.

Description

technical field [0001] The invention belongs to the technical field of textile finishing, and specifically relates to a process for preparing a melamine resin finishing agent prepared by an in-situ polymerization method using low-methyl etherified melamine resin as a wall material and essence as a core material. Background technique [0002] With the development of the economy and the improvement of living standards, people's requirements for textiles have undergone great changes. From the past practical type to the decoration, enjoyment, and health care type, textile perfuming conforms to this trend. Because scented textiles have the functions of antibacterial and insect repellent, covering peculiar smell, and making body and mind comfortable, they are generally liked by people. In ancient my country, there was the habit of sewing sachets on clothes; Europe has sprayed perfume on clothes since the Middle Ages as an elegant style, and later, there was a method of incense; fo...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D06M23/12D06M13/00D06M15/263D06M15/233D06M15/423B01J13/16B01J13/18D06M101/06
CPCD06M23/12B01J13/16B01J13/18D06M13/005D06M15/233D06M15/263D06M15/423D06M2101/06
Inventor 张万龙
Owner 贺州宝兴新材料股份有限公司
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