Corrosion resistant unsaturated polyester resin and preparation method thereof

A polyester resin and corrosion-resistant technology, which is applied in the field of corrosion-resistant unsaturated polyester resin and its preparation, can solve problems such as insufficient corrosion resistance of unsaturated polyester resin, and achieve the effect of improving corrosion resistance

Inactive Publication Date: 2018-06-22
定远汇利化工有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] In order to solve the technical problems existing in the background technology, the present invention proposes a kind of corrosion-resistant unsaturated polyester resin and its preparation method, to solve the problems in the Chinese patent application document "A kind of unsaturated polyester resin and its preparation method (application publication number : CN102532424A)" the problem of insufficient corrosion resistance of the disclosed unsaturated polyester resin

Method used

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  • Corrosion resistant unsaturated polyester resin and preparation method thereof
  • Corrosion resistant unsaturated polyester resin and preparation method thereof

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preparation example Construction

[0021] The preparation method of described corrosion-resistant unsaturated polyester resin, comprises the following steps:

[0022] S1. Mix unsaturated polyester resin, silicone resin, trimethyl phosphate, alkyd resin, dicyclopentadiene, dibutyl ethyl tin oxide, isophthalic anhydride, and triisocyanuric acid ester evenly, Raise the temperature to 70-80°C, keep it warm for 20-30min, then add polycarbonate, cobalt isooctanoate, cobalt cyclopentanoate, hexafluorobutyl methacrylate, methyl ethyl ketone peroxide, oleic acid, dibutyl ethyl tin oxide, formazan Mix hexafluorobutyl acrylate, trimethylolpropane diallyl ether, castor oil, precipitated barium sulfate, and glass flakes evenly, continue to heat up to 70-80°C, keep warm for 30-50min, and then heat at 350-450r / min Stir at a rotating speed for 10-20min, cool to room temperature to obtain the base material;

[0023] S2. Mix cellulose acetate, zinc acetate, silane coupling agent KH-560, and corrosion-resistant modification addi...

Embodiment 1

[0027] A corrosion-resistant unsaturated polyester resin, in parts by weight, comprising the following raw materials: 100 parts of unsaturated polyester resin, 6 parts of silicone resin, 6 parts of trimethyl phosphate, 4 parts of alkyd resin, dicyclopentadiene 6 parts of alkene, 6 parts of dibutyl ethyl tin oxide, 4 parts of isophthalic anhydride, 3 parts of triisocyanuric acid ester, 4.5 parts of polycarbonate, 3 parts of cobalt isooctanoate, 6 parts of cobalt cyclopentanoate, 4.5 parts of hexafluorobutyl methacrylate, 3 parts of methyl ethyl ketone peroxide, 4.5 parts of oleic acid, 6 parts of dibutyl ethyl tin oxide, 6 parts of hexafluorobutyl methacrylate, trimethylolpropane diallyl ether 3.5 parts, castor oil 3 parts, precipitated barium sulfate 6 parts, glass flakes 4 parts, cellulose acetate 11 parts, zinc acetate 7.5 parts, silane coupling agent KH-560 3 parts, corrosion resistance modification additive 22 parts.

[0028] The corrosion-resistant modification additive i...

Embodiment 2

[0034] A corrosion-resistant unsaturated polyester resin, in parts by weight, comprising the following raw materials: 80 parts of unsaturated polyester resin, 8 parts of silicone resin, 3 parts of trimethyl phosphate, 6 parts of alkyd resin, dicyclopentadiene 4 parts of alkene, 9 parts of dibutyl ethyl tin oxide, 2 parts of isophthalic anhydride, 5 parts of triisocyanuric acid ester, 3 parts of polycarbonate, 5 parts of cobalt isooctanoate, 4 parts of cobalt cyclopentanoate, 6 parts of hexafluorobutyl methacrylate, 1 part of methyl ethyl ketone peroxide, 6 parts of oleic acid, 4 parts of dibutyl ethyl tin oxide, 9 parts of hexafluorobutyl methacrylate, trimethylolpropane diallyl ether 2 parts, 5 parts of castor oil, 4 parts of precipitated barium sulfate, 6 parts of glass flakes, 8 parts of cellulose acetate, 9 parts of zinc acetate, 2 parts of silane coupling agent KH-560, 26 parts of corrosion resistance modification additive.

[0035] The corrosion-resistant modification ad...

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Abstract

The invention discloses a corrosion resistant unsaturated polyester resin, and belongs to the technical field of preparation of resins. The corrosion resistant unsaturated polyester resin comprises the following raw materials: unsaturated polyester resin, organic silicon resin, trimethyl phosphate, alkide resin, dicyclopentadiene, dibutyltin oxide, isophthalic anhydride, triiso-tricyanurate ester,polycarbonate, cobalt iso-octoate, cobalt cyclopentanecarboxylate, hexafluorobutyl methacrylate, methyl ethyl ketone peroxide, oleic acid, dibutyltin oxide, hexafluorobutyl methacrylate, trihydroxymethyl propane diallyl ether, castor oil, precipitated barium sulphate, glass flake, cellulose acetate, zinc acetate, a silane coupling agent KH-560, and a corrosion resistant modified auxiliary, and the corrosion resistant unsaturated polyester resin is prepared by the steps of preparing a matrix, preparing a modified material, mixing the matrix and the modified material, etc. The prepared unsaturated polyester resin has an excellent property of corrosion resistance.

Description

technical field [0001] The invention relates to the technical field of resin preparation technology, in particular to a corrosion-resistant unsaturated polyester resin and a preparation method thereof. Background technique [0002] Unsaturated polyester is a kind of mature and industrialized thermosetting resin, and the corresponding products are widely used in laminates, building materials, adhesives, coatings, construction industry and electric power industry. Unsaturated polyester raw materials have wide sources and low cost; they can be cured at room temperature, the curing time is controllable, and the molding process is simple; after curing, the surface of the product is bright and plump, with high hardness, good wear resistance, excellent electrical properties and weather resistance. Although unsaturated polyesters have many advantages, there are also some disadvantages. For example, traditional unsaturated polyester materials are usually brittle, poor in toughness, ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L67/06C08L83/04C08L67/08C08L1/12C08L61/06C08K13/02C08K5/098C08K3/22C08K3/28
CPCC08L67/06C08K2003/2241C08K2003/282C08K2201/011C08K2201/014C08L2205/02C08L2205/035C08L83/04C08L67/08C08L1/12C08L61/06C08K13/02C08K5/098C08K3/22C08K3/28
Inventor 耿志芹
Owner 定远汇利化工有限公司
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