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A method of preparing photocatalytic sheet using 3D molding technology

A photocatalytic and technical technology, which is applied in the field of photocatalytic sheet preparation using 3D molding technology, can solve the problems of complex preparation process and high cost, and achieve the effect of simple preparation process, controllable shape and high catalytic efficiency

Active Publication Date: 2021-01-15
HEFEI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The preparation process of this method is complex, the cost is high, and there are obvious technical differences from the patent of the present invention
Therefore, the existing methods of preparing photocatalytic sheets using 3D molding technology need to be improved

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] Cryogenic crushing of nylon polymer pellets, classification by vibrating sieve (powder particle size: 50 μm), selection of nylon polymer powders with different particle sizes, adding 2% antioxidant, mixing evenly, and crystallization treatment. The crystallization treatment process is to keep warm for 6 hours under the protection of an atmosphere at 80°C, and then cool with the furnace. The obtained nylon polymer powder was dispersed in a sulfuric acid solution and stirred for 5 hours at a concentration of 50 g / L. After etching, it was washed with water until it was neutrally dried. The etched nylon polymer powder was deposited on the surface of the photocatalytic medium TiO by co-precipitation method. 2 , dried under the protection of atmosphere at 200°C, add 0.5% zinc stearate glidant and mix well. The homogeneously mixed polymer powder was prepared by a selective laser sintering process with a photocatalytic function. The laser power was 30W and the sintering temper...

Embodiment 2

[0032]The polypropylene polymer pellets are cryogenically crushed and subjected to cyclone classification treatment (the particle size of the powder is 80 μm), and polypropylene polymer powders of different particle sizes are selected, mixed with 0.5% antioxidant, and crystallized. The crystallization treatment process is to keep warm for 1 hour under the protection of atmosphere at 200°C, and then cool with the furnace. Disperse the obtained polypropylene polymer powder in hydrochloric acid solution and stir for 0.1 hour, the concentration is 200g / L, after etching, wash with water until neutral drying. Deposit the photocatalytic medium ZnO on the surface of the etched polypropylene polymer powder by co-precipitation method, dry it under the protection of atmosphere at 80°C, add 1.5% magnesium stearate flow aid and mix well. The homogeneously mixed polypropylene polymer powder was prepared into a sheet with photocatalytic function by a selective laser sintering process. The la...

Embodiment 3

[0035] The polyethylene polymer pellets were cryogenically crushed and subjected to vibrating sieve classification (the particle size of the powder was 60 μm), and nylon polymer powders of different particle sizes were selected, mixed with 1.8% antioxidant, and crystallized. The crystallization treatment process is to keep the temperature for 4.5 hours under the protection of an atmosphere at 100°C, and then cool with the furnace. Disperse the obtained polyethylene polymer powder in nitric acid solution and stir for 4 hours, the concentration is 80g / L, after etching, wash with water until neutral drying. The photocatalytic medium SnO was deposited on the surface of the etched polyethylene polymer powder by co-precipitation method. 2 , dried under the protection of atmosphere at 180 ℃, add 0.7% magnesia flow aid and mix well. The homogeneously mixed polymer powder was prepared into a sheet with photocatalytic function by selective laser sintering process, the laser power was 2...

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Abstract

The invention discloses a method for preparing a photocatalytic sheet by using a 3D forming technology. The method comprises the following steps: (1) deeply cooling and crushing polymer aggregates, classifying the crushed aggregates to select polymer powder having different particle sizes, adding 0.5 to 2 percent of an antioxidant, uniformly mixing the polymer powder with the antioxidant, and crystallizing the mixture; (2) dispersing the polymer powder into an acidic solution for stirring for 0.1 to 5 hours, and washing the polymer powder to be neutral after corrosion, and drying the polymer powder; (3) depositing a photocatalytic medium on the surface of the polymer powder by adopting a coprecipitation method; (4) preparing a sheet with a photocatalytic function from the polymer powder byadopting a selective laser sintering process. Compared with the prior art, the method disclosed by the invention has the beneficial effects that in the polymer powder prepared by the method, the photocatalytic medium and the polymer powder are high in dispersing performance, and the surface adhesive property of the same group is excellent; the preparation process is simple and can realize efficient production; the shape of the polymer sheet is controllable; the sheet printed by the prepared polymer powder is more suitable for photocatalysis and high in catalytic efficiency.

Description

technical field [0001] The invention relates to the fields of chemical plating and composite material preparation, in particular to a method for preparing a photocatalytic sheet using 3D forming technology. Background technique [0002] 3D prototyping is a kind of rapid prototyping technology. It is a technology based on digital model files and using bondable materials such as powdered metal or plastic to construct objects by layer-by-layer printing. [0003] Photocatalytic materials include titanium dioxide, zinc oxide, tin oxide, iron oxide, zirconium dioxide, cadmium sulfide and other oxide sulfide semiconductors, but zinc oxide and cadmium sulfide are unstable, and titanium dioxide photocatalysts have low quantum efficiency and can only absorb ultraviolet rays. Light, low utilization rate of solar energy, CuO 2 Light energy utilization rate is low. Therefore, improvements are needed to obtain materials more suitable for photocatalysis. [0004] At present, the process...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L77/00C08L23/12C08L23/06C08L81/02C08L55/02C08K3/22C08K5/098B29C64/135B33Y10/00
CPCB33Y10/00B29C64/135C08K3/22C08K5/098C08K2003/2231C08K2003/2241C08K2003/2272C08K2003/2296C08L77/00C08L23/12C08L23/06C08L81/02C08L55/02
Inventor 赵兴科钱瑞环谭永贞黄俊俊黄梦茹郑子银
Owner HEFEI UNIV