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A kind of resourceful utilization of coal chemical waste gas and waste water to prepare the method for sodium bisulfate

A technology of coal chemical wastewater and sodium bisulfate, which is applied in the direction of sulfate/bisulfate preparation, etc., to achieve the effect of saving energy and improving resource utilization rate

Active Publication Date: 2020-06-09
HARBIN INST OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Yet the above-mentioned first invention only relates to the preparation of sodium chloride and sodium nitrate, and the second invention only relates to the preparation of concentrated sulfuric acid in the cement industry

Method used

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  • A kind of resourceful utilization of coal chemical waste gas and waste water to prepare the method for sodium bisulfate
  • A kind of resourceful utilization of coal chemical waste gas and waste water to prepare the method for sodium bisulfate
  • A kind of resourceful utilization of coal chemical waste gas and waste water to prepare the method for sodium bisulfate

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specific Embodiment approach 1

[0029] Specific embodiment one: a kind of resource utilization of coal chemical industry waste gas and waste water of the present embodiment prepares the method for sodium bisulfate, and it is carried out according to the following steps:

[0030] 1. Regulating pool: the coal chemical industry wastewater is passed into the regulating pool to adjust the effluent water volume and stabilize the water quality;

[0031] 2. Passivation process: Calcium oxide, magnesium, sodium carbonate, coagulant and coagulant aid are added to the coal chemical wastewater. The dosage of the calcium oxide is 100-150 mg / L; the carbonic acid The dosage of sodium is 60-70mg / L; the dosage of the coagulant is 50mg / L-100mg / L; the dosage of the coagulant is 0.5-1.0mg / L; the dosage of the magnesium agent and SiO in coal chemical wastewater 3 2- The mass ratio is 12:1; among them, the hardness of the effluent is less than 50mg / L, and the silicon is less than 25mg / L;

[0032] 3. Multi-media filtration: pas...

specific Embodiment approach 3

[0061] Embodiment 3: This embodiment differs from Embodiment 1 in that the structure of the nanofiltration membrane includes a roll-type nanofiltration membrane, a disc tube-type nanofiltration membrane, or a vibrating membrane. Others are the same as in the first embodiment.

specific Embodiment approach 4

[0062] Embodiment 4: The difference between this embodiment and Embodiment 1 is that the coagulant described in step 2 is polyferric chloride or ferrous sulfate, and the coagulation aid is polyacrylamide. Others are the same as Embodiment 1. .

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Abstract

The invention discloses a method for preparing sodium hydrogen sulfate from coal chemical waste gas and waste water through resource utilization, and relates to the field of waste water, waste gas andresource utilization. The invention aims at solving the problem that no method that can effectively treat and recycle the coal chemical waste gas and concentrated saltwater at the same time exists currently. By adopting the method to treat the waste gas and the concentrated saltwater of the coal chemical industry, the resource utilization rate of coal chemical water body and gas is improved. According to the invention, raw materials for preparing the sodium hydrogen sulfate, that is, sulfur dioxide in the coal chemical waste gas and sodium chloride in the concentrated saltwater, are both produced in a coal chemical production process, so that the method has economic feasibility; and the sulfur dioxide in the waste gas is directly utilized to produce sulfuric acid, thereby avoiding a sulfur recovery process of exhaust gas treatment in the coal chemical industry, and saving the energy consumption.

Description

technical field [0001] The invention relates to the fields of waste water, waste gas and resource utilization, in particular to a method for preparing sodium bisulfate by using waste gas from coal chemical industry and concentrated brine. Background technique [0002] China is a country with large coal resources, and the reserves of coal resources account for more than 75% of the total energy resources. In recent years, China's coal chemical industry has developed rapidly, and at the same time, the state has strengthened environmental protection and supervision of the coal chemical industry. The country's new coal chemical industry is oriented towards high energy conversion rates, with the characteristics of low discharge of "waste water, waste gas, and waste liquid", and at the same time strengthens the recycling and utilization of by-products and resources in the production process. [0003] Coal chemical concentrated brine is produced in the reclaimed water system of coa...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C01D5/02
CPCC01D5/02
Inventor 韩洪军李琨徐春艳
Owner HARBIN INST OF TECH