Crosslinkable naphthal-diimide-based all-polymer solar cell receptor material and preparation method and application thereof

A solar cell and naphthalene diimide technology, which is applied in the fields of electric solid-state devices, semiconductor/solid-state device manufacturing, circuits, etc., can solve the problems of hindering charge separation and transmission, efficiency attenuation, and the service life gap of all-polymer solar cells. , achieve high photoelectric conversion efficiency, improve thermal stability, and improve thermal stability

Active Publication Date: 2018-11-02
FUJIAN NORMAL UNIV
View PDF7 Cites 7 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there is still a certain gap between the service life of all-polymer solar cells and inorganic photovoltaic cells, and it is necessary to further improve the thermal stability of all-polymer solar devices in order to realize the application
Although the photothermal stability of all-polymer cells has been greatly improved compared with fullerene and small molecule acceptor cells, the efficiency of the reported devices still decays in a short period of time

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Crosslinkable naphthal-diimide-based all-polymer solar cell receptor material and preparation method and application thereof
  • Crosslinkable naphthal-diimide-based all-polymer solar cell receptor material and preparation method and application thereof
  • Crosslinkable naphthal-diimide-based all-polymer solar cell receptor material and preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] Synthesis of Polymer C-PNDI-T-0.05

[0038] The chemical reaction flow chart of the present embodiment is as figure 1 Shown, concrete reaction steps and reaction conditions are as follows:

[0039] Under nitrogen protection, 0.01045 mmol monomer A (4,9-dibromo-2,7-bis(2-hexyldecyl)-benzo[lmn][3,8]o-phenanthroline-1, 3,6,8-tetranitro), 0.0055mmol monomer B (4,9-dibromo-2,7-di(undecenyl)-benzo[lmn][3,8]o-diazepine After mixing phenanthrene-1,3,6,8-tetranitro and 0.11mmol monomer C (2,5-bis(trimethylstannyl)thiophene), add 5mol% catalyst tris(dimethoxyphene) in sequence Benzylacetone) Dipalladium (Pd 2 (dba) 3 ) and 10mol% ligand tris(o-methylphenyl)phosphine (P(o-tyl) 3) were mixed and dissolved in 3 mL of a mixed solvent of toluene and N,N dimethylformamide (5:1). Then allow the reaction solution to stir and reflux at 110°C for 48 hours, then add 0.11 mmol of phenylboronic acid to cap it, and continue the reaction for 6 hours; stop responding. After the reaction ...

Embodiment 2

[0052] Synthesis of Polymer C-PNDI-T-0.03

[0053] The chemical reaction flow chart of the present embodiment is as figure 1 Shown, concrete reaction steps and reaction conditions are as follows:

[0054] Under nitrogen protection, 0.1012 mmol of monomer A (4,9-dibromo-2,7-bis(2-hexyldecyl)-benzo[lmn][3,8]o-phenanthroline-1, 3,6,8-tetranitro), 0.0088mmol monomer B (4,9-dibromo-2,7-di(undecenyl)-benzo[lmn][3,8]o-diazepine After mixing phenanthrene-1,3,6,8-tetranitro and 0.11 mmol monomer C (2,5-bis(trimethylstannyl)thiophene), add 5 mol% catalyst tris(dibenzyl Dipalladium (Pd 2 (dba) 3 ) and 10mol% ligand tris(o-methylphenyl)phosphine (P(o-tyl) 3 ) were mixed and dissolved in 3mL of toluene and N,N dimethylformamide (5:1) mixed solvent; then the reaction solution was stirred and refluxed at 110°C for 48h, then capped with 0.11mmol phenylboronic acid, and the reaction was continued After 7 hours, add 0.3~0.5mL of bromobenzene to block, and then react at 110°C for 4 hours, ...

Embodiment 3

[0061] Synthesis of Polymer C-PNDI-Se-0.05

[0062] The chemical reaction flow chart of the present embodiment is as image 3 Shown, concrete reaction steps and reaction conditions are as follows:

[0063] Under nitrogen protection, 0.1045 mmol of monomer A (4,9-dibromo-2,7-bis(2-hexyldecyl)-benzo[lmn][3,8]phenanthroline-1, 3,6,8-tetranitro), 0.0055mmol monomer B (4,9-dibromo-2,7-di(undecenyl)-benzo[lmn][3,8]o-diazepine After mixing phenanthrene-1,3,6,8-tetranitro and 0.11 mmol monomer C (2,5-bis(trimethylstannyl)selenophene), 5 mol% catalyst tris(di Benzylideneacetone) Dipalladium (Pd 2 (dba) 3 ) and 10mol% ligand tris (o-methylphenyl) phosphine (P (o-tyl) 3) are mixed and dissolved in 3 mL of toluene and N,N dimethylformamide (5:1) mixed solvent; then Stir and reflux the reaction solution at 110°C for 36 hours, then add 0.11 mmol of phenylboronic acid to block, and continue the reaction for 4 hours; then add 0.3 to 0.5 mL of bromobenzene to block, then react at 110°C fo...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
Molecular weightaaaaaaaaaa
Molecular weightaaaaaaaaaa
Molecular weightaaaaaaaaaa
Login to view more

Abstract

The invention discloses a crosslinkable naphthal-diimide-based all-polymer solar cell receptor material and a preparation method and application thereof. A ternary random polymer with different olefinic bond contents is prepared by adjusting the composition of monomers containing olefinic bonds and is subjected to high-temperature thermal treatment; also disclosed is how to acquire a crosslinked-structure active layer material at the premise of maintaining high photoelectric conversion efficiency in order to except to obtain an all-polymer solar device having high photoelectric conversion efficiency and excellent thermal stability; application in the field of organic solar cells is achieved. In addition, the preparation method is simple; the material acquired has better resistance to hightemperature and better thermal stability when applied to photovoltaic material active layers as compared to common polymer donor/receptor photovoltaic material active layers; therefore, the material herein can be applied to the field of all-polymer solar cells to provide significantly improved stability for devices.

Description

technical field [0001] The invention belongs to the field of photoelectric materials, in particular to an organic solar photoelectric material, and more specifically to a crosslinkable naphthalene diimide-based all-polymer solar cell acceptor material, a preparation method and an application thereof. Background technique [0002] All-polymer solar cells (All-PSCs) made of p-type conjugated polymer donor materials and n-type polymer acceptor materials blended as photosensitive active layers, due to good film-forming properties, good stability, etc. advantages have been extensively studied. At present, the photoelectric conversion efficiency of All-PSCs has surpassed that of fullerene-based batteries in just a few years, indicating its great potential. However, there is still a certain gap between the service life of all-polymer solar cells and inorganic photovoltaic cells, and to realize the application, it is necessary to further improve the thermal stability of all-polymer...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
IPC IPC(8): C08G61/12H01L51/42H01L51/46
CPCC08G61/126C08G2261/91C08G2261/3223C08G2261/1412C08G2261/1414C08G2261/122H10K85/151H10K30/00Y02E10/549
Inventor 王文凌启淡崔建玉
Owner FUJIAN NORMAL UNIV
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap