Technology and system for treating petrochemical wastewater

A technology of petrochemical wastewater and treatment process, applied in the field of water treatment, can solve the problems of excessive effluent index, low biodegradability, and unsuitability to industry development requirements, etc., and achieve the ideal effect of removing residual COD content and degreasing effect

Pending Publication Date: 2018-12-21
HUADIAN WATER TECH CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, it is still difficult to meet the water quality indicators for subsequent water use or the new environmental protection discharge standards
CNOOC Huizhou, Sinopec Maoming and many other companies use the MBR method for engineering applications. The pre-treatment effect COD is stable below 60mg / L. After a period of operation, the membrane fouling is serious and the operation is unstable.
[0009] In addition, the expansion of production scale and the diversification of products in the petrochemical industry determine the diversity of waste water, which makes the waste water contain acids and esters, but the proportion of refractory substances such as hydrocarbons, sulfur nitrogen and benzene series Higher, these pollutants are difficult to remove by conventional biological means, and with the expansion of production scale and the continuous improvement of environmental protection standards, the original process has not adapted to the development requirements of the industry, and the effluent index seriously exceeds the standard. The traditional oil separation + air flotation + The biochemical "old three sets" process cannot meet the requirements. Therefore, in view of the water quality characteristics of high oil content, high COD content and low biodegradability (B / C<0.3) of the wastewater, the wastewater treatment process must be redesigned and implemented. Upgrade the treatment system to ensure the stability of the system operation while meeting the discharge standards

Method used

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  • Technology and system for treating petrochemical wastewater
  • Technology and system for treating petrochemical wastewater
  • Technology and system for treating petrochemical wastewater

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0049] A petrochemical wastewater treatment process, comprising the following steps:

[0050] (1) Primary treatment: the waste water is left to stand for more than 24 hours for preliminary oil removal, and then the loading coagulation method is used to further remove free insoluble oil;

[0051] (2) Secondary treatment: adopt air flotation and chemical treatment to process the oil-water emulsion treated in step (1), remove suspended solids (SS) and the oil separated from the emulsion;

[0052] (3) Biochemical treatment: the effluent of step (2) is treated by anoxic / aerobic (A / O) activated sludge method, which includes anoxic section and aerobic section During treatment, part of the effluent that has been fully reacted in the aerobic section needs to be returned to the anoxic section, mixed with the effluent from step (2) and treated together to remove organic matter and ammonia nitrogen; and the anoxic / aerobic active pollution The wastewater treated by mud method is sedimente...

Embodiment 2

[0055] A petrochemical wastewater treatment process, comprising the following steps:

[0056] (1) Primary treatment: the waste water is left to stand for more than 24 hours for preliminary oil removal, and then the loading coagulation method is used to further remove free insoluble oil, wherein the loading coagulation method is: throwing in the coagulation reaction process Add coagulant FeCl 3 Dosing Fe at the same time 3 o 4 Magnetic powder, Fe 3 o 4 The magnetic powder forms a crystal nucleus to absorb oil, improve the flocculation effect, remove free insoluble oil, and recover Fe through the magnetic separator 3 o 4 magnetic powder;

[0057] (2) Secondary treatment: add coagulant FeCl by air flotation and chemical treatment 3 Process the oil-water emulsion treated in step (1), remove suspended solids (SS) and oil separated from the emulsion;

[0058] (3) Biochemical treatment: the effluent of step (2) is treated by anoxic / aerobic (A / O) activated sludge method, which...

Embodiment 3

[0061] A petrochemical wastewater treatment process, comprising the following steps:

[0062](1) Primary treatment: the waste water is left to stand for more than 24 hours for preliminary oil removal, and then the loading coagulation method is used to further remove free insoluble oil;

[0063] (2) Secondary treatment: use H 2 SO 4 or NaOH to neutralize the pH value of the effluent in step (1) to 7, adjust the water quality and quantity, and then remove the sulfide through aeration and oxidation treatment, and then add coagulant FeCl by air flotation and chemical treatment 3 The oil-water emulsion treated in step (1) is processed to remove suspended solids and oil separated from the emulsion.

[0064] (3) Biochemical treatment: the effluent of step (2) is treated by anoxic / aerobic (A / O) activated sludge method, which includes anoxic section and aerobic section During treatment, part of the effluent that has been fully reacted in the aerobic section needs to be returned to t...

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Abstract

The invention provides a technology and a system for treating petrochemical wastewater. The technology is characterized in that a treatment method combining primary treatment, secondary treatment, biochemical treatment and deep treatment is adopted, the previous petroleum removal effect is enhanced, and the deep treatment type novel technology combination of 'ozone contact and aeration biologicalfilter tank' is additionally adopted, so that the contents of COD (chemical oxygen demand) and petroleum in the wastewater can be reduced, and the removal effect of petroleum and COD is enhanced; mostof NH3-N, TN, sulfide, volatile phenol and SS (suspended solids) can be removed, the drainage requirement is met, the petrochemical wastewater is effectively treated, and the drained water can stablyreach the standard. The treatment system comprises an adjusting petroleum removal tank, a loading and coagulation petroleum removal device, a coagulation and flocculation air floatation tank, an A/O(anoxic/oxic) biochemical tank, a secondary precipitation tank, a front ozone contact tank, an aeration biological filter tank, a clean water tank and the like. The system has the advantages that according to the conditions, the system can be newly built, or be modified on the original treatment system; the running is stable, the construction cost is effectively reduced, and the running cost is reduced.

Description

technical field [0001] The invention relates to the field of water treatment, in particular to a petrochemical wastewater treatment process and system. Background technique [0002] Petrochemical industry is a pillar industry of the national economy. With the rapid development of my country's economy, oil consumption continues to rise, the production scale of the petrochemical industry continues to expand, and the level continues to improve. The quality of petrochemical wastewater produced is complicated, diverse, and difficult to treat Keep increasing. Therefore, developing a reasonable and effective treatment process is a key way to meet people's ever-increasing environmental protection requirements. Petroleum chemical industry mainly uses petroleum as raw material, through a series of refining, fractionation, cracking, synthesis and other processing processes, to produce heavy oil, light oil, by-product gas, etc., and further react to synthesize various organic chemical p...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F9/14C02F103/36
CPCC02F9/00C02F2301/08C02F2305/02C02F2001/007C02F2103/365C02F1/78C02F1/72C02F1/66C02F1/5281C02F1/52C02F3/02C02F3/30C02F1/40C02F1/24
Inventor 郑一江王正平王建华孟露
Owner HUADIAN WATER TECH CO LTD
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