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Dry desulfurization dust removing technology method for catalytic cracking regenerated flue gas

A technology for catalytic cracking and regenerating flue gas, applied in chemical instruments and methods, chemical elements of heterogeneous catalysts, separation methods, etc., can solve problems such as falling rain, low SOx removal rate from flue gas, freezing and salty wastewater, etc. , to achieve the effect of good effect, high flue gas purification efficiency and dust emission reduction

Active Publication Date: 2019-02-19
CHINA UNIV OF PETROLEUM (BEIJING) +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This method can solve the problems of low SOx removal rate in the flue gas, easy formation of "blue smoke", "white smoke", "rainfall" from the scrubber, freezing and discharge of salty wastewater and other secondary pollution problems in the prior art ; and the dust in the regenerated flue gas is effectively removed at the front end to ensure the long-term safe operation of catalytic cracking smoke machines, waste heat boilers, SCR denitrification and other equipment

Method used

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  • Dry desulfurization dust removing technology method for catalytic cracking regenerated flue gas
  • Dry desulfurization dust removing technology method for catalytic cracking regenerated flue gas
  • Dry desulfurization dust removing technology method for catalytic cracking regenerated flue gas

Examples

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Effect test

Embodiment 1

[0056] This embodiment provides a method for preparing a desulfurization catalyst, which specifically includes the following steps:

[0057] Step one, aluminum magnesium spinel (MgAl 2 o 4 ) preparation:

[0058] Add 5000g of H in a 10-liter three-neck flask 2 O, 228g of NaOH and 89g of Na 2 CO 3 , Stir well at 65°C, add 3000g of H 2 O, 221g of Mg(NO 3 ) 2 ·6H 2 O, 187g of Al(NO 3 ) 3 9H 2 The dropwise addition time of the O solution is 0.6h. After the dropwise addition, continue to stir for nucleation and crystallization for 18h, then cool, filter with suction, wash until neutral and dry to obtain magnesium aluminum spinel.

[0059] Step 2, preparation of manganese magnesium aluminum hydrotalcite (MnMgAl-LDH):

[0060] Add 5000g of H in a 10-liter three-neck flask 2 O, 252g of NaOH and 53g of Na 2 CO 3 , Stir well at 75°C, add 3000g of H 2 O, 9.5g of Mn(NO 3 ) 2 4H 2 O, 524g of Mg(NO 3 ) 2 ·6H 2 O, 247g of Al(NO 3 ) 3 9H 2 O solution, the dropwise add...

Embodiment 2

[0064] This embodiment provides a dry desulfurization and dust removal process for catalytic cracking regenerated flue gas, such as figure 1 as shown, figure 1 It is a schematic flow chart of the desulfurization and dust removal process in this embodiment, and the dust removal process specifically includes the following steps:

[0065] Step 1, the catalytic cracking flue gas is passed into the moving bed desulfurization reactor, and the desulfurization reaction is carried out with the desulfurization catalyst prepared in Example 1 loaded in the moving bed desulfurization reactor, and the sulfur oxide in the flue gas is catalytically reacted to generate metal sulfuric acid Salt, and adsorbed on the desulfurization catalyst, while the desulfurization catalyst further intercepts the dust in the flue gas, and the desulfurized and purified flue gas is returned to the smoke machine or the waste pot.

[0066] The reaction of the following formula (1) is carried out in the moving bed...

Embodiment 3

[0073] This embodiment is the laboratory simplified simulation experiment of embodiment 2, a kind of catalytic cracking regenerated flue gas dry desulfurization dedusting process method, adopts micro-quartz reactor simulation moving bed desulfurization reactor; Take simulated flue gas (by SO 2 and 3.5v%O 2 , 96.5v% N 2 The mixed gas) simulates the catalytic cracking flue gas. The specific operation is as follows:

[0074] Weigh 1.0g of the desulfurization catalyst prepared in Example 1 and put it into a Φ8×1mm quartz tube reactor, heat the catalyst to a certain temperature while feeding nitrogen, then stop the nitrogen, and feed the 2 The mixed gas was collected for 60 minutes, and the gas was collected and analyzed for SO 2 Concentration, this process is the reaction stage. After the reaction, stop the SO 2 Mixed gas, purging with nitrogen for 10 minutes, passing regeneration gas (including one or more of hydrogen, carbon monoxide or methane, etc.) at a certain temperatu...

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Abstract

The invention provides a dry desulfurization dust removing technology method for catalytic cracking regenerated flue gas. The method comprises the steps that catalytic cracking flue gas is introducedin a moving bed desulfuration reactor, the catalytic cracking flue gas and a loaded desulfurization catalyst are subjected to the desulfurization reaction, oxysulfide in the flue gas is subjected to the catalytic reaction to produce metal sulfate, and the metal sulfate is adsorbed on the desulfurization catalyst; the desulfurization catalyst containing the metal sulfate is conveyed to a desulfurization catalyst reproducer, reductive regeneration gas is introduced in the reproducer, and after the metal sulfate on the desulfurization catalyst is reduced to metallic oxide, a part of purified fluegas is utilized for lifting the regenerated desulfurization catalyst into a dust elutriating apparatus through a catalyst lifter, and after dust is recovered through elutriation, desulfurization catalyst is conveyed into moving bed desulfuration reactor for recycling; regenerated acid gas containing hydrogen sulfide is introduced in a dry gas desulfurizer to produce sulphur. According to the method, the desulfuration and dust removal of the catalytic cracking flue gas can be effectively achieved, and the desulfurization rate reaches 99% or above.

Description

technical field [0001] The invention belongs to the technical field of desulfurization catalyst environmental protection technology, and in particular relates to a dry desulfurization and dust removal process method of catalytic cracking regenerated flue gas. Background technique [0002] Catalytic cracking is one of the important secondary processing processes in refineries, mainly composed of reactors and regenerators. Under the action of the catalyst, the raw oil is cracked into light fractions in the catalytic cracking reactor. During the reaction, the catalyst is deactivated due to coking, and the deactivated catalyst is fluidized and transported to the regenerator for coke regeneration, and then circulated back to the reactor. The catalytic reaction continues. During the catalytic cracking reaction, part of the sulfide in the raw material is deposited on the catalyst. When the catalyst is burnt and regenerated in the regenerator, the sulfide on the catalyst burns to f...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D53/86B01D53/83B01D53/50B01J23/889
CPCB01D53/83B01D53/8609B01J23/002B01J23/8892B01J2523/00B01J2523/17B01J2523/22B01J2523/31B01J2523/3712B01J2523/72
Inventor 卢春喜陈伟范怡平闫子涵
Owner CHINA UNIV OF PETROLEUM (BEIJING)
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