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Photocatalyst hydrosol with high catalytic degradation performance and its production process

A technology of catalytic degradation and production process, applied in the field of photocatalyst, can solve the problems of limited catalytic activity and practical use conditions, inability of electron holes to migrate in time, and inability to achieve catalytic effect, etc., to improve photocatalytic properties, excellent electrical properties, Reduce the effect of reducing efficiency

Active Publication Date: 2021-09-17
浙江空将环境科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, titanium dioxide has a large band gap (3.0eV for the rutile phase and 3.2eV for the anatase phase) and can only be excited by ultraviolet light, which severely limits its catalytic activity and practical use conditions; on the other hand, when titanium dioxide is subjected to When light is irradiated, the excited electron-hole pairs cannot migrate to the surface in time, and rapidly recombine inside, which cannot play a catalytic effect and also reduces its catalytic activity.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] The production process of photocatalyst hydrosol with high catalytic degradation performance comprises the following steps: add 1g sodium hexametaphosphate to 200g water, stir at 80 rpm for 10 minutes to obtain a mixed solution; add 5g titanium dioxide to the mixed solution, and continue to stir at 80 rpm Stir for 15 minutes per minute; then add 6g of 20% hydrogen peroxide solution in mass fraction, shear and emulsify for 30 minutes at 5000 rpm, and leave it for 12 hours to obtain an emulsion; add 0.6g acetylacetone to the emulsion, and continue to Stir at 80 rpm for 10 minutes, then adjust the pH to 7 with 1% hydrochloric acid or 1% sodium hydroxide aqueous solution by mass fraction to obtain the photocatalyst hydrosol with high catalytic degradation performance.

[0034] Use a pipette to pipette 0.5mL of the photocatalyst hydrosol with high catalytic degradation performance of Example 1 into a beaker, add water to make up to 400mL, ultrasonically treat for 20 minutes, ...

Embodiment 2

[0037] The production process of photocatalyst hydrosol with high catalytic degradation performance comprises the following steps: add 1g of sodium hexametaphosphate to 200g of water, stir at 80 rpm for 10 minutes to obtain a mixed solution; add 4g of titanium dioxide and 1g of molybdic acid to the mixed solution Bismuth, continue to stir with 80 rpm for 15 minutes; then add 6g of hydrogen peroxide solution with a mass fraction of 20%, shear and emulsify with 5000 rpm for 30 minutes, and leave it for 12 hours to obtain an emulsion; add 0.6 g acetylacetone, continue to stir at 80 rpm for 10 minutes, then adjust the pH to 7 with 1% hydrochloric acid or 1% aqueous sodium hydroxide solution by mass fraction to obtain the photocatalyst hydrosol with high catalytic degradation performance.

[0038] The preparation process of the bismuth molybdate is as follows: 4.85g bismuth nitrate pentahydrate and 0.97g sodium molybdate dihydrate are added to 400mL deionized water, after stirring f...

Embodiment 3

[0042] The production process of photocatalyst hydrosol with high catalytic degradation performance comprises the following steps: add 1g sodium hexametaphosphate to 200g water, stir at 80 rpm for 10 minutes to obtain a mixed solution; add 4g titanium dioxide and 1g selenium loading to the mixed solution Bismuth molybdate, continue to stir with 80 rpm for 15 minutes; then add 6g of hydrogen peroxide solution with a mass fraction of 20%, shear and emulsify with 5000 rpm for 30 minutes, and leave it for 12 hours to obtain an emulsion; Add 0.6g acetylacetone, continue stirring at 80 rpm for 10 minutes, then adjust the pH to 7 with 1% hydrochloric acid or 1% aqueous sodium hydroxide solution by mass fraction to obtain the photocatalyst hydrosol with high catalytic degradation performance.

[0043] The preparation process of the described selenium-loaded bismuth molybdate is as follows: 4.85g bismuth nitrate pentahydrate, 0.97g sodium molybdate dihydrate and 0.25g selenium powder ar...

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Abstract

The invention discloses a photocatalyst hydrosol with high catalytic degradation performance and a production process thereof. The production process of the photocatalyst hydrosol with high catalytic degradation performance comprises the following steps: adding sodium hexametaphosphate in water, stirring to obtain a mixed solution; adding titanium dioxide or titanium dioxide / graphene composite material, and bismuth molybdate or selenium to the mixed solution Load bismuth molybdate and continue to stir; then add hydrogen peroxide solution, shear emulsify, and stand to obtain an emulsion; add a stabilizer to the emulsion, continue to stir, and then adjust the pH to obtain the photocatalyst hydrosol with high catalytic degradation performance. The photocatalyst hydrosol with high catalytic degradation performance obtained by the invention has uniform particle size, good dispersion, high stability, excellent light absorption performance and good photocatalytic effect, and stable performance, simple preparation process, mild preparation conditions, and has the advantages of: Good application value.

Description

technical field [0001] The invention relates to the technical field of photocatalysts, in particular to a photocatalyst hydrosol with high catalytic degradation performance and a production process thereof. Background technique [0002] Photocatalyst is a nano-scale metal oxide material, which is coated on the surface of the substrate, and under the action of light, it produces a strong catalytic function, which can effectively degrade toxic and harmful gases in the air; kill a variety of bacteria, and can Toxins released by bacteria or fungi are decomposed or harmlessly treated; at the same time, photocatalysts also have functions such as deodorization and antifouling. The necessary conditions for photocatalysis to work are photocatalysts and light with suitable wavelength conditions. At present, the most commonly used photocatalyst is titanium dioxide material. The reason why titanium dioxide can play a photocatalytic role is determined by its own physical and chemical p...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J31/38C02F1/30C02F101/38C02F101/34
CPCB01J31/38B01J35/0013B01J35/004C02F1/30C02F2101/34C02F2101/38C02F2101/40C02F2305/10
Inventor 张润高
Owner 浙江空将环境科技有限公司
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