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Single-component aqueous silicon steel sheet paint

A silicon steel sheet paint, one-component technology, used in coatings, epoxy resin coatings, etc., can solve the problems of inconvenience on the construction site, small lamination coefficient of iron cores, poor stability, etc., to improve adhesion or bonding performance. , to avoid measurement errors, the effect of stable performance

Active Publication Date: 2019-05-10
SHANDONG ACAD OF ENVIRONMENTAL SCI ENVIRONMENTAL TESTING CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Most of the traditional epoxy resin coating materials are two-component systems, which need to be used and prepared immediately, which brings inconvenience to the construction site (Zhao Hui, Chen Zhiming, Wang Qiuying, Wu Xia. Modified imidazole latent epoxy resin Preparation of Curing Agent[J]. Coating Industry, 2004, 7:23-25)
Moreover, the existing single-component silicon steel sheet paint has poor stability, and the hardness and heat resistance level of the paint film also need to be improved.
[0004] In addition, the adhesion or bonding performance between the existing silicon steel sheet paint film and the silicon steel sheet is not good enough, the adhesion effect is not good enough, and the leveling performance is poor, resulting in a large paint film thickness and a small lamination coefficient of the iron core
[0005] Moreover, most of the existing silicon steel sheet paints are added with organic solvents, which have peculiar smell and even toxicity

Method used

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  • Single-component aqueous silicon steel sheet paint
  • Single-component aqueous silicon steel sheet paint

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0042] Weigh 80.0g water; 5.2g modified dicyandiamide; 1.0g morpholine-4-methylbenzenesulfonate; 260g epoxy resin Waterpoxy1422; 20g diluent 1,4-butanediol diglycidyl ether, 15g Diluent benzyl glycidyl ether; 7g nano-silica, 5g nano-tin dioxide; 0.8g ethylene glycol mixed with 2.5g 1-(2-butoxyethoxy)ethanol as wetting agent; 0.6g defoaming agent Agent B-0520; 1.0g leveling agent ethyl acetoacetate; 0.5g preservative KATHON LXE; 1.8g anti-flash rust agent R-760F; 10g Dow Corning silane coupling agent Z-6011; 0.3g neutralizing agent dimethyl Ethanolamine DMEA.

[0043] Add modified dicyandiamide, morpholine-4-methylbenzenesulfonate, water-based epoxy emulsion, wetting agent, defoamer, preservative, leveling agent and anti-flash rust agent to the reaction kettle in sequence Stir at medium and high speed (about 5000r / min) for 5 hours, stir at low speed and add silane coupling agent and neutralizing agent, stir well and set aside. Inorganic filler nano-silica SiO 2 and nano-tin ...

Embodiment 2

[0045]Weigh 100g water; 10g curing agent modified dicyandiamide; 1.0g morpholine-4-methylbenzenesulfonate; 200g epoxy resin Waterpoxy1422; 15g diluent 1,4-butanediol diglycidyl ether, 15g Diluent benzyl glycidyl ether; 7g nano-silica, 10g nano-tin dioxide; 1.8g 2-(2-butoxyethoxy)ethanol and 2.5g 1-(2-butoxyethoxy) Ethanol mixed as a wetting agent; 0.5g defoamer B-0519; 2.0g leveling agent 4-chloroacetoacetate ethyl ester; 0.7g preservative KATHON LXE; 2.0g anti-flash rust agent R-760F; 10g Dow Corning silane Joint agent Z-6121; 1.4g neutralizing agent dimethylethanolamine DMEA.

[0046] Add modified dicyandiamide, morpholine-4-methylbenzenesulfonate, water-based epoxy emulsion, wetting agent, defoamer, preservative, leveling agent and anti-flash rust agent to the reaction kettle in sequence Stir at medium and high speed (about 5000r / min) for 5 hours, stir at low speed and add silane coupling agent and neutralizing agent, stir well and set aside. Inorganic filler nano-silica ...

Embodiment 3

[0048] Weigh 120g water; 15g curing agent modified dicyandiamide; 1.5g morpholine-4-methylbenzenesulfonate; 300g epoxy resin Waterpoxy1455; 10g diluent 1,4-butanediol diglycidyl ether, 30g Diluent benzyl glycidyl ether; 10g nano-silica, 10g nano-tin dioxide; 2.5g propylene glycol and 2.5g 1-methoxy-2-propanol mixed as wetting agent; 1.0g defoamer B-0518 ; 1.0g leveling agent ethyl acetoacetate, 1.0g methyl 4-chloroacetoacetate; 1.0g preservative KATHONLXE; 2.8g anti-flash rust agent R-760F; 20g Dow Corning silane coupling agent Z-6020; 2.6g medium And the agent dimethylethanolamine DMEA.

[0049] Add modified dicyandiamide, morpholine-4-methylbenzenesulfonate, water-based epoxy emulsion, wetting agent, defoamer, preservative, leveling agent and anti-flash rust agent to the reaction kettle in sequence Stir at medium and high speed (about 5000r / min) for 5 hours, stir at low speed and add silane coupling agent and neutralizing agent, stir well and set aside. Inorganic filler na...

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Abstract

The invention discloses a single-component aqueous silicon steel sheet paint, and belongs to the field of aqueous paints. The single-component aqueous silicon steel sheet paint comprises the followingcomponents in parts by weight: 150-350 parts of bisphenol type-A epoxy resin, 3-30 parts of modified dicyandiamide, 0-10 parts of morpholine-4-methylbenzenesulfonate, 50-200 parts of deionized water,10-60 parts of an epoxy resin diluent, 5-20 parts of inorganic filler, 1-8 parts of a wetting agent, 0.5-2 parts of a defoaming agent, 0.5-2 parts of a leveling agent, 0.5-1 part of a preservative, 1-4 parts of a flash rust preventing agent, 5-25 parts of a silane coupling agent and 0.3-3 parts of a neutralizing agent. The single-component aqueous silicon steel sheet paint has the characteristicsof stable performance, high hardness, good heat resistance, good leveling property, stable long-term storage property, high bonding property, no peculiar smell, low toxicity and environmental friendliness at the normal temperature, and is simple and convenient to produce, store and transport.

Description

technical field [0001] The invention relates to the field of water-based coatings, in particular to a single-component water-based paint for silicon steel sheets, which covers the surface of silicon steel sheets for insulation and protection, and is especially suitable for insulating silicon steel sheets of large generators and motors. Background technique [0002] Silicon steel sheets are used in motor and transformer iron cores. In order to reduce the eddy current loss of the iron cores and enhance the anti-rust and corrosion resistance, it is necessary to coat the silicon steel sheets with insulating varnish. As an insulating paint, it should have good dielectric properties, oil resistance, moisture resistance, strong adhesion, and sufficient mechanical strength and hardness. In addition, the paint film should be as thin as possible under the premise of satisfying the performance, so as to increase the lamination coefficient of the iron core and increase the effective len...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D163/00C09D7/20C09D7/61C09D7/47C08G59/40
Inventor 苏日艳王晓明孙慧玲
Owner SHANDONG ACAD OF ENVIRONMENTAL SCI ENVIRONMENTAL TESTING CO LTD
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