Unlock instant, AI-driven research and patent intelligence for your innovation.

Method for preparing papermaking sludge recycling agent

A papermaking sludge and catalyst technology, applied in sludge treatment, chemical instruments and methods, water/sludge/sewage treatment, etc., can solve the problems of wasting raw materials, polluting the environment with solid waste, and low interest rate in preparing sludge plates , to achieve the effect of saving energy consumption and cost, improving the utilization rate of raw materials, and improving the retention rate of raw materials

Active Publication Date: 2019-07-12
青岛祥泽化学科技有限公司
View PDF7 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] During the papermaking process, with the flow of sewage circulating water, a large amount of fine fibers, calcium carbonate, talcum powder, starch, sizing agent, etc. are lost with the water, and the lost materials will be polluted by anaerobic bacteria in the water body for a long time and become sludge , the formation of solid waste not only wastes a lot of raw materials, but also seriously pollutes the environment.
[0003] For the treatment of existing papermaking sludge, most of them adopt filter press landfill incineration or use papermaking sludge to prepare other low-interest sludge boards, etc. The treatment method of filter press landfill cannot essentially eliminate pollution, and incineration will produce A large amount of flue gas causes new pollution. The interest rate of preparing sludge plates is low and sludge cannot be used efficiently, which affects economic benefits and is not suitable for industrial production. What is more important is that the above treatment methods cannot make full use of raw materials for The purpose of making paper, saving costs and improving paper quality

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Method for preparing papermaking sludge recycling agent
  • Method for preparing papermaking sludge recycling agent
  • Method for preparing papermaking sludge recycling agent

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] The invention provides a preparation method of a papermaking sludge recycling agent, which specifically adopts the following steps:

[0035] (1) Mix polyvinyl alcohol and methacrylic acid in a molar ratio of 1: (1.1-1.3) with p-toluenesulfonic acid accounting for 5‰-1.5% of the molar mass of polyvinyl alcohol and methacrylic acid mixture and stir evenly , placed in a closed container and reacted at 130-165°C in a nitrogen atmosphere for 2-3 hours, and cooled to room temperature to obtain a mixture of polyvinyl alcohol methacrylate and polyvinyl alcohol dimethacrylate;

[0036] (2) In the mixture of polyvinyl alcohol methacrylate and polyvinyl alcohol dimethacrylate obtained in step (1), add excess deionized water and account for 3-5 % cationic monomer DMC, then add acrylamide accounting for 2-3% of the molar mass of the mixture of polyacryl alcohol and methacrylic acid, and stir the mixture evenly;

[0037] (3) Add ammonium persulfate accounting for 1.7-2.6% of the mol...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention discloses a method for preparing a papermaking sludge recycling agent. The method comprises the following steps: carrying out an esterification reaction on polyvinyl alcohol and methacrylic acid to form an ester polymer, polymerizing the ester polymer, a cationic monomer DMC and acrylamide under the action of an initiator ammonium persulfate to obtain a high-molecular polymer, and grafting the surface of the high-molecular polymer with chitosan to obtain the recycling agent. The recycling agent can efficiently recover fine fibers, calcium carbonate, talcum powder, starch, a sizing agent and other papermaking raw materials in the papermaking sludge, lost with circulating water, so the papermaking pulp is saved, the retention rate and the utilization rate of the raw materials are increased, the quality of obtained paper products is improved, and the generation amount of the sludge is reduced, thereby the energy consumption and the cost for sludge treatment are saved, and industrial production is facilitated.

Description

technical field [0001] The invention relates to the technical field of clean production and waste treatment, in particular to a preparation method of a papermaking sludge recycling agent. Background technique [0002] During the papermaking process, with the flow of sewage circulating water, a large amount of fine fibers, calcium carbonate, talcum powder, starch, sizing agent, etc. are lost with the water, and the lost materials will be polluted by anaerobic bacteria in the water body for a long time and become sludge , the formation of solid waste not only wastes a lot of raw materials, but also seriously pollutes the environment. [0003] For the treatment of existing papermaking sludge, most of them adopt filter press landfill incineration or use papermaking sludge to prepare other low-interest sludge boards, etc. The treatment method of filter press landfill cannot essentially eliminate pollution, and incineration will produce A large amount of flue gas causes new pollu...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): C02F11/00C08F290/12C08F220/34C08F220/56C02F103/28
CPCC02F11/00C02F2103/28C08F290/12C08F220/34C08F220/56
Inventor 刘阳杜祥森陈立莹
Owner 青岛祥泽化学科技有限公司