Alpha-diimine nickel metal organic ligand, porous organic polymer and application of porous organic polymer

A metal-organic and nickel diimide technology, which is applied in the direction of nickel-organic compounds, preparation of organic compounds, organic compound/hydride/coordination complex catalysts, etc., can solve the problems of high cost and low catalytic activity of palladium catalysts, etc. Short reaction time, excellent stability, and improved catalytic effect
CN110229080AActive Publication Date: 2019-09-13SHANDONG NORMAL UNIV
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
SHANDONG NORMAL UNIV
Publication Date
2019-09-13

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Abstract

The disclosure provides an alpha-diimine nickel metal organic ligand, a porous organic polymer and application of the porous organic polymer. The porous organic polymer has a chemical structural formula as shown in the description. The porous organic polymer can be applied to preparation of a catalyst for catalyzing a Suzuki coupling reaction, and the catalyst has high catalytic activity, low cost, low usage amount and repeated use.
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Description

technical field

[0001] The disclosure belongs to the technical field of catalyst preparation, and relates to α-diimine nickel metal-organic ligands, porous organic polymers and applications thereof. Background technique

[0002] The statements herein merely provide background information related to the present disclosure and may not necessarily constitute prior art.

[0003] Suzuki reaction, also known as Suzuki coupling reaction, Suzuki-Miyaura reaction (Suzuki-Miyaura reaction), is an organic coupling reaction in which aryl or alkenyl boronic acid or boron is catalyzed by a zero-valent palladium complex Esters cross-couple with chlorine, bromine, iodoarenes or alkenes. The Suzuki reaction was first reported by Akira Suzuki in 1979. It is widely used in organic synthesis, has strong substrate adaptability and functional group tolerance, and is often used to synthesize derivatives of polyenes, styrene and biphenyl, thus applying In the synthesis of many natural products an...

Claims

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