The invention discloses a novel
solid-state three-phase catalyst. The novel
solid-state three-phase catalyst comprises organic ligands L for synthesizing
metal organic frameworks based on Cd(II),
metal organic frameworks Cd-MOF-1 based on Co(II) and
metal organic frameworks Cd-MOF-1' based on Co(II). A method for preparing the novel
solid-state three-phase catalyst includes synthesizing the metal organic frameworks Cd-MOF-1 by the aid of the organic ligands L; arranging the metal organic frameworks CD-MOF-1 and 1-dodecyl
bromide in a double-opening flask with the volume of 25 ml, adding 10 ml of
anhydrous acetonitrile into the double-opening flask and heating the metal organic frameworks CD-MOF-1, the 1-dodecyl
bromide and the
anhydrous acetonitrile until the temperatures of the metal organic frameworks CD-MOF-1, the 1-dodecyl
bromide and the
anhydrous acetonitrile reach 80-90 DEG C; carrying out stirring reaction on the metal organic frameworks CD-MOF-1, the 1-dodecyl bromide and the anhydrous acetonitrile for 48 h; stopping heating the metal organic frameworks CD-MOF-1, the 1-dodecyl bromide and the anhydrous acetonitrile; arranging reaction systems in room-temperature environments; centrifugally separating the reaction systems; collecting precipitates; washing the precipitates by the aid of acetonitrile twice; washing the precipitates by the aid of
methanol twice; washing the precipitates by the aid of
diethyl ether twice to obtain the novel solid-state three-phase catalyst Cd-MOF-1'. The anhydrous acetonitrile is used as a
solvent. The novel solid-state three-phase catalyst has the advantages that azidation reaction on 1-bromobutane can be effectively catalyzed by the novel solid-state three-phase catalyst without reaction of the traditional phase transfer catalysts, the
reaction temperature is mild, and the novel solid-state three-phase catalyst is short in reaction time, low in usage and free of other additives, is easy to recycle as compared with the traditional phase transfer catalysts and can be reused by more than three times.