Two-dimensional PLZST antiferroelectric photonic crystal and preparation method thereof
A photonic crystal and antiferroelectric technology, applied in optics, nonlinear optics, instruments, etc., can solve the problems of photonic crystals with many defects, low electron mobility and breakdown field strength, and no obvious changes, and achieve accurate optical parameters , Precise parameters, regular shape effect
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[0039] Such as figure 1 As shown, the two-dimensional PLZST antiferroelectric photonic crystal preparation method provided by the embodiment of the present invention specifically includes:
[0040] (1) Select zirconium n-propoxide, tetrabutyl titanate, lead acetate, tin acetate, lanthanum nitrate, etc. as raw materials, use acetic acid, ethylene glycol ether, acetylacetone, and formamide as solvents, and prepare PLZST by Sol-Gel method Sol.
[0041] (2) Fix the SSO template on the homogenizer, drop PLZST sol, and fill the SSO template by spin coating.
[0042] (3) Heating for the first time on the electric heating plate, the heating temperature is set at 60-80°C, and lasts for 15min at 80°C.
[0043] (4) Fix the sample on the homogenizer after cooling, perform the second spin coating filling, and repeat step (3).
[0044] (5) Repeat step (4) 4 to 5 times.
[0045] (6) Put the sample into a tubular heating furnace, fill it with argon, sinter, and then cool naturally.
[00...
Embodiment
[0060] Such as image 3 As shown, it is a schematic diagram of the preparation method of the two-dimensional PLZST antiferroelectric photonic crystal provided by the embodiment of the present invention.
[0061] Figure 4 It is a schematic diagram of the preparation method of the SSO template provided by the embodiment of the present invention.
[0062] Figure 5 It is a top view of a two-dimensional PLZST antiferroelectric photonic crystal attached to a silicon substrate provided by an embodiment of the present invention.
[0063] In the SEM image of the experimental sample of the present invention, the designed photonic crystal aperture is 500 nanometers. In the case of ignoring the measurement error, the aperture of the photonic crystal air column is almost the same, and the deviation from the experimental design parameters can be ignored. From the perspective of the realization effect, the two-dimensional PLZST photonic crystal prepared by the method provided by the inv...
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