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Long glass fiber reinforced flame-retardant ABS composite material and preparation method thereof

A composite material and long glass fiber technology, which is applied in the field of long glass fiber reinforced flame retardant ABS composite material and its preparation, can solve the problems of poor flame retardant performance of composite materials, and achieve high practicability, excellent flame retardant performance and mechanical properties. performance effect

Inactive Publication Date: 2020-12-01
瞿雨捷
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Nowadays, PC / ABS on the market generally adds glass fiber for reinforcement during processing, but the flame retardant performance of the composite material is poor and cannot meet our actual needs. Therefore, this application discloses a long glass fiber reinforced flame retardant ABS composite material and its preparation method to solve the problem

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0048] S1: Prepare raw materials;

[0049] S2: Preparation of pretreated fibers:

[0050] Take glass fibers, soak in 25°C acetone solution for 20 minutes, wash with water, then soak in 50°C sodium hydroxide solution for 30 minutes, wash with water, then place in 30°C stannous chloride solution, soak for 25 minutes, and then place in 30°C chlorine Soak in the palladium chloride solution for 18min, wash and dry to obtain material A;

[0051] Take material A, place it in a mixed solution of cobalt chloride and sodium citrate, adjust the pH to 8 with ammonia water, then add sodium hypophosphite, shake in a water bath at 75°C, react at a constant temperature for 80 minutes, wash, and dry to obtain material B;

[0052] Take the material B, put it in the PECVD reaction chamber, evacuate to 4Pa, raise the temperature to 600°C under the protection of hydrogen, keep it for 30min, then raise the temperature to 700°C, feed methane and hydrogen, grow carbon nanowires on the surface of the...

Embodiment 2

[0062] S1: Prepare raw materials;

[0063] S2: Preparation of pretreated fibers:

[0064] Take glass fibers, soak in 28°C acetone solution for 25 minutes, wash with water, then soak in 55°C sodium hydroxide solution for 35 minutes, wash with water, then place in 35°C stannous chloride solution, soak for 28 minutes, and then place in 35°C chlorine Soak in the palladium chloride solution for 24min, wash and dry to obtain material A;

[0065] Take material A, place it in a mixed solution of cobalt chloride and sodium citrate, adjust the pH to 9 with ammonia water, then add sodium hypophosphite, shake in a water bath at 78°C, react at a constant temperature for 82 minutes, wash, and dry to obtain material B;

[0066] Take the material B, put it in the PECVD reaction chamber, evacuate to 5Pa, raise the temperature to 605°C under the protection of hydrogen, keep it warm for 34min, then raise the temperature to 708°C, feed methane and hydrogen, grow carbon nanowires on the surface o...

Embodiment 3

[0076] S1: Prepare raw materials;

[0077] S2: Preparation of pretreated fibers:

[0078] Take glass fibers, soak in 30°C acetone solution for 30 minutes, wash with water, then soak in 60°C sodium hydroxide solution for 40 minutes, wash with water, then place in 40°C stannous chloride solution, soak for 30 minutes, and then place in 40°C for chlorination Soak in palladium solution for 26min, wash and dry to obtain material A;

[0079] Take material A, place it in a mixed solution of cobalt chloride and sodium citrate, adjust the pH to 10 with ammonia water, then add sodium hypophosphite, shake in a water bath at 80°C, react at a constant temperature for 85 minutes, wash, and dry to obtain material B;

[0080] Take the material B, put it in the PECVD reaction chamber, evacuate to 5Pa, raise the temperature to 610°C under the protection of hydrogen, keep it for 35 minutes, then raise the temperature to 710°C, feed methane and hydrogen, grow carbon nanowires on the surface of th...

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Abstract

The invention discloses a long glass fiber reinforced flame-retardant ABS composite material and a preparation method thereof. The composite material comprises polycarbonate, ABS, a flame retardant material, modified fibers, modified graphene oxide and other components, and the surface of the modified graphene oxide is treated with a silane coupling agent, so that the compatibility of the grapheneoxide and matrix components (polycarbonate and ABS) is improved, the graphene oxide and the matrix components can be uniformly dispersed in a system, the modified fiber is mainly prepared from blackphosphorene, dopamine, absolute ethyl alcohol and pretreated fiber, the pretreated fibers are glass fibers with carbon nanowires growing on the surfaces, and the glass fibers are continuous glass fibers. By utilizing the synergistic effect of the aluminum hydroxide, the magnesium hydroxide, the polysiloxane, the modified graphene oxide and the black phosphorene, the ABS composite material has excellent flame retardance, and is low in smoke, low in toxicity and higher in practicability during combustion.

Description

technical field [0001] The invention relates to the technical field of ABS processing, in particular to a long glass fiber reinforced flame-retardant ABS composite material and a preparation method thereof. Background technique [0002] PC / ABS, polycarbonate and acrylonitrile-butadiene-styrene copolymer and mixture, is a thermoplastic plastic formed by combining polycarbonate (Polycarbonate) and polyacrylonitrile (ABS), combined with ABS material Formability and mechanical properties of PC, impact strength and temperature resistance, anti-ultraviolet (UV) and other properties. [0003] PC / ABS, as the commercialized polymer alloy with the largest sales volume in the world, has been growing at a demand rate of about 10% in recent years. Compared with PC, PC / ABS has improved fluidity, improved processing performance, and reduced the sensitivity of products to stress. It can be widely used in automotive interior parts, business machines, communication equipment, home appliances...

Claims

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Application Information

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IPC IPC(8): C08L55/02C08L69/00C08L83/04C08K13/06C08K9/06C08K3/04C08K7/14C08K9/02C08K9/10C08K9/08C08K3/22C08K3/02
CPCC08K2003/026C08K2003/2224C08K2003/2227C08K2201/011C08L55/02C08L2201/02C08L2205/035C08L69/00C08L83/04C08K13/06C08K9/06C08K3/042C08K7/14C08K9/02C08K9/10C08K9/08C08K3/22C08K3/02C08K3/046
Inventor 瞿雨捷
Owner 瞿雨捷
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