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Heat-conducting nylon material as well as preparation method and application thereof

A nylon and branched nylon technology, applied in the field of polymer materials, can solve the problems of inability to take into account the comprehensive requirements of heat dissipation and mechanical properties, difficulty in meeting the heat dissipation requirements of electronic products, and poor impact resistance of thermally conductive nylon plastics. Flammability, high bending performance, the effect of improving physical properties

Pending Publication Date: 2020-12-04
东莞市普万光电散热科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Traditional materials for heat conducting components include PC or PC / ABS alloys, which have good toughness and aging resistance, but the thermal conductivity is not ideal, and it is difficult to meet the heat dissipation requirements of electronic products for the development of miniaturization.
However, materials with relatively good thermal conductivity do not have high hardness and toughness, and cannot meet the comprehensive requirements of heat dissipation and mechanical properties for the development of existing electronic products and industrial products. Therefore, the preparation of high-performance thermal conductivity shell materials has become an urgent problem to be solved.
[0003] CN102757640A discloses a thermally conductive nylon composite material and a preparation method thereof. The thermally conductive nylon composite material includes: 20-60% nylon, 3-10% compatibilizer, 5-10% high thermally conductive fiber, 30-50% high thermally conductive filler % and 0.5-16% of additives; the heat-conducting nylon composite material is controlled by the addition ratio of branching agent and chain extender, so that the material has been slightly cross-linked during the modification process, and in the later injection molding process The effect of deep cross-linking in the medium can make the material directly transform from thermoplastic material to thermosetting product, which greatly improves the physical and mechanical properties of the product, thereby solving the problem that the high filling amount of thermal conductive components has too much influence on the physical properties of the material, but its thermal conductivity and resilience still needs to be improved
[0004] CN105419315A provides a reinforced nylon 6 material with high glass fiber content, which comprises: 55-70% of glass fiber, 16-38% of nylon 6, 5-10% of nylon copolymer, and 1-2% of lubricating aid , 0.05-1% star branching agent, 0.05-1% end-capping agent and 0.05-1% heat stabilizer. Nylon 6 and nylon copolymer are used as main materials, star branching agent is added, and the raw materials are cheap Easy to get, without white spots and glass fiber exposure, the product has excellent comprehensive performance, high mechanical strength, long-term heat resistance, dimensional stability and high rigidity, but it has not disclosed that it has good thermal conductivity
However, the thermally conductive nylon plastic has poor impact resistance, and as the content of thermally conductive fillers in the plastic increases, the mechanical properties of the plastic decrease rapidly, making it difficult to balance thermal conductivity and mechanical strength

Method used

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  • Heat-conducting nylon material as well as preparation method and application thereof
  • Heat-conducting nylon material as well as preparation method and application thereof
  • Heat-conducting nylon material as well as preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0040] This embodiment provides a thermally conductive nylon material, including the following components by weight:

[0041]

[0042] The nylon is a combination of branched nylon 6 and nylon 12 with a mass ratio of 7:3, wherein the relative viscosity of branched nylon 6 is 3.60, which is 3200H of Baling Petrochemical, and nylon 12 is purchased from Baling Petrochemical; The filler is a combination of aluminum nitride and silicon carbide at a mass ratio of 3:2.

[0043] The preparation method of the heat-conducting nylon material comprises the following steps:

[0044] (1) Mix branched nylon 6, nylon 12 and maleic anhydride for 10 minutes under stirring to obtain mixture A;

[0045] (2) Add a thermally conductive filler to the mixture A obtained in step (1), and mix for 15 minutes under stirring to obtain a mixture B;

[0046] (3) Add glass fiber (average diameter of 20 μm, dried after immersion in silane coupling agent KH550) and titanium dioxide to the mixture B obtaine...

Embodiment 2

[0048] This embodiment provides a thermally conductive nylon material, including the following components by weight:

[0049]

[0050] The nylon is a combination of branched nylon 6 and nylon 12 at a mass ratio of 2.5:1; the thermally conductive filler is a combination of zinc oxide, magnesium oxide, aluminum oxide, and aluminum hydroxide at a mass ratio of 1:1:1.5:1.5.

[0051] The preparation method of the heat-conducting nylon material comprises the following steps:

[0052] (1) Mix branched nylon 6, nylon 12 and maleic anhydride for 5 minutes under stirring to obtain mixture A;

[0053] (2) Add a thermally conductive filler to the mixture A obtained in step (1), and mix for 10 minutes under stirring conditions to obtain a mixture B;

[0054] (3) Add glass fiber (with an average diameter of 20 μm, dried after being soaked in silane coupling agent KH550) and titanium dioxide to the mixture B obtained in step (2), mix for 5 minutes under agitation, and then use a twin-scr...

Embodiment 3

[0056] This embodiment provides a thermally conductive nylon material, including the following components by weight:

[0057]

[0058] The nylon is a combination of branched nylon 6 and nylon 12 in a mass ratio of 2:1; the thermally conductive filler is zinc nitride, aluminum nitride, silicon carbide, and magnesium hydroxide in a mass ratio of 1:2:1:1 The combination.

[0059] The preparation method of the heat-conducting nylon material comprises the following steps:

[0060] (1) Mix branched nylon 6, nylon 12 and maleic anhydride for 15 minutes under stirring to obtain mixture A;

[0061] (2) Add a thermally conductive filler to the mixture A obtained in step (1), and mix for 20 minutes under stirring conditions to obtain a mixture B;

[0062] (3) Add glass fiber (average diameter is 15 μ m, dry after soaking through silane coupling agent KH550) and titanium dioxide in the mixture B that step (2) obtains, mix 15min under agitation condition, then adopt extruder at 195 U...

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Abstract

The invention provides a heat-conducting nylon material as well as a preparation method and application thereof. The heat-conducting nylon material is prepared from the following components in parts by weight: 30-40 parts of nylon, 20-25 parts of glass fiber, 5-10 parts of maleic anhydride and 30-40 parts of heat-conducting filler, wherein the nylon is a combination of branched nylon 6 and nylon 12, so that the crystallinity of the polymer can be effectively reduced, the dispersion of the glass fiber and the heat-conducting filler is facilitated, and the processability is improved; and meanwhile, the coating property of the material can be improved, so that a more stable cross-linked network structure is formed in the heat-conducting nylon material, and the bending property, the toughnessand the impact strength are further improved. According to the heat-conducting nylon material, through mutual cooperation of the nylon, the glass fibers, the maleic anhydride and the heat-conducting filler, good balance is achieved in the aspects of comprehensive performance such as heat conductivity, mechanical strength and flexibility, and the performance requirements of 5G routing and other electronic products for the polymer heat-conducting material can be fully met.

Description

technical field [0001] The invention belongs to the technical field of polymer materials, and relates to a heat-conducting nylon material and a preparation method and application thereof. Background technique [0002] With the continuous development of material science, the application proportion of thermal conductive materials in national defense industry and civilian materials is increasing year by year. Thermal conductive materials with the characteristics of light weight, good mechanical properties, strong electrical insulation and low price will become the trend of future development. Today, with the rapid development of industry, it has a wide range of application prospects. Electronic industrial products such as 5G routers, 3C electronic products, AI robots, sweeping robots, projectors, small base stations and semiconductor devices are constantly developing in the direction of miniaturization, lightness and intelligence. These products require high heat dissipation, e...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L77/02C08L35/00C08K13/06C08K9/06C08K7/14C08K3/28C08K3/34C08K3/22C08F283/04C08F222/06C09K5/14
CPCC08L77/02C08F283/04C09K5/14C08K2003/282C08K2003/2241C08L2205/03C08L2205/025C08L35/00C08K13/06C08K9/06C08K7/14C08K3/28C08K3/34C08K3/22C08F222/06
Inventor 靳涛
Owner 东莞市普万光电散热科技有限公司
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