A kind of element master batch suitable for anti-counterfeiting chemical fiber and preparation method thereof

A chemical fiber and element technology, which is applied in the field of anti-counterfeiting chemical fiber element masterbatch and its preparation, can solve the problems of poor concealment of anti-counterfeiting features, easy to be imitated and forged, and easy to be interfered by other substances, so as to reduce processing difficulty and process cost, increase the concealment of anti-counterfeiting, and increase the effect of anti-counterfeiting

Active Publication Date: 2022-07-22
SUZHOU UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

With the continuous advancement of science and technology, the anti-counterfeiting features of single-color fluorescent fibers and dual-band fluorescent fibers are relatively simple and easy to forge, and their anti-counterfeiting strength cannot adapt to high-end security fields such as banknotes and passports; Poor, and it is a colored fluorescent fiber, the anti-counterfeiting feature is poorly concealed, and it is not suitable for high-end security fields such as banknotes and passports; photochromic and infrared absorption are easy to forge and are also susceptible to interference from other substances
[0003] At present, someone has also proposed a method for preparing marked cellulose fibers-CN101942707B, which discloses a dispersion liquid added in the preparation process of cellulose fibers. The dispersion liquid includes a metal-inorganic compound, a dispersant and water. The agent is fatty alcohol polyoxyethylene phosphate, sodium hexametaphosphate, nonylphenol polyoxyethylene ether, sodium polyacrylate or sodium butylnaphthalene sulfonate; it is determined by comparing the retention and addition of metal inorganic compounds in the fiber Judging, distinguishing and identifying textiles; however, on the one hand, it also has the defect of insufficient anti-counterfeiting, it is easy to be imitated and forged, and it is difficult to have memory tracking properties; on the other hand, the dispersion mentioned in it is only suitable for use in the preparation of cellulose fibers , and the preparation method of chemical fiber is completely different from that of cellulose fiber, so that it can be used in the anti-counterfeiting of chemical fiber

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] Example 1 Preparation of element masterbatch suitable for anti-counterfeiting chemical fiber

[0031]This example provides an element masterbatch suitable for anti-counterfeiting chemical fibers. In parts by mass, it includes 66.01 parts of polyethylene terephthalate, 2.49 parts of zinc oxide (2 parts of zinc), and 4.05 parts of zirconium dioxide. parts (3 parts of zirconium element), 9.45 parts of aluminum oxide (5 parts of aluminum element), 8 parts of polyethylene wax, 5 parts of antioxidant, 5 parts of coupling agent; wherein content of zinc element: content of zirconium element: Aluminum element content = 2:3:5;

[0032] The preparation method is as follows: (1) weighing each component in the element master batch according to the formula amount; using the weighed polyethylene terephthalate to form a powder with an average particle size of 350±30nm by a pulverizer ;

[0033] (2) Mix the ingredients weighed in step (1) and add them to a screw extruder for extrusion...

Embodiment 2

[0035] Example 2 Preparation of element masterbatch suitable for anti-counterfeiting chemical fiber

[0036] This example provides an element masterbatch suitable for anti-counterfeiting chemical fibers. In parts by mass, it includes 61.01 parts of recycled PET, 2.49 parts of zinc oxide (2 parts of zinc), and 4.05 parts of zirconium dioxide (3 parts of zirconium). parts), 9.45 parts aluminum oxide (5 parts aluminum content), 7 parts calcium oxide (5 parts calcium content), 8 parts polyethylene wax, 4 parts antioxidants, 4 parts coupling agent; among which zinc element Content: zirconium content: aluminum content: calcium content = 2:3:5:5;

[0037] The preparation method is as follows: (1) each component in the element master batch is weighed according to the formula; the weighed recycled PET is made into powder with an average particle size of 350±30nm by a pulverizer;

[0038] (2) Mix the ingredients weighed in step (1) and add them to a screw extruder for extrusion, the ex...

Embodiment 3

[0040] Example 3 Preparation of element masterbatch suitable for anti-counterfeiting chemical fiber

[0041] This example provides an element masterbatch suitable for anti-counterfeiting chemical fibers. In parts by mass, it includes 55.59 parts of polyamide, 1.24 parts of zinc oxide (1 part of zinc element content), and 4.05 parts of zirconium dioxide (3 parts of zirconium element content) ), 10.71 parts of vanadium pentoxide (6 parts of vanadium element), 14.41 parts of germanium dioxide (10 parts of germanium element), 6 parts of polyethylene wax, 4 parts of antioxidant, 4 parts of coupling agent; among which zinc element Content: zirconium content: vanadium content: germanium content = 1:3:6:10;

[0042] The preparation method is as follows: (1) weighing each component in the element master batch according to the formula amount; using a pulverizer to form the weighed polyamide into powder with an average particle size of 350±30nm;

[0043] (2) Mix the ingredients weighed ...

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PUM

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Abstract

The invention discloses an element master batch suitable for anti-counterfeiting chemical fibers, comprising a matrix polymer, an anti-counterfeiting tracking agent and a polyolefin dispersant. The contained metal elements have a fixed mass ratio of feeding materials, and the metal oxygen compounds are zinc oxide, molybdenum trioxide, zirconium dioxide, aluminum oxide, calcium oxide, strontium oxide, germanium dioxide or vanadium pentoxide; In terms of mass percentage content, the sum of the content of metal elements contained in various metal oxides accounts for 5-50% of the element master batch; the element master batch of the present invention can endow chemical fibers with both memory tracking properties and identification functions and The advantages of high anti-counterfeiting strength and good anti-counterfeiting concealment.

Description

technical field [0001] The invention belongs to the field of chemical fibers with anti-counterfeiting function, and particularly relates to an element master batch suitable for anti-counterfeiting chemical fibers and a preparation method thereof. Background technique [0002] As a common anti-counterfeiting technology, anti-counterfeiting chemical fibers have been widely used in securities, banknotes, passports and other fields. At present, anti-counterfeiting chemical fibers are mainly monochromatic fluorescent fibers, dual-band fluorescent fibers and multi-color dyeing fibers, photochromic, infrared absorption anti-counterfeiting and other products have also appeared one after another, such as Chinese patents CN2731620Y, CN103850144B, CN104963241B. With the continuous progress of science and technology, the anti-counterfeiting characteristics of single-color fluorescent fibers and dual-band fluorescent fibers are relatively simple, and they are easy to be counterfeited. I...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L67/02C08L23/06C08K3/22C08J3/22D01F1/10
CPCC08J3/226D01F1/10C08J2467/02C08J2423/06C08K2003/2296C08K2003/2244C08K2003/2227
Inventor 刘宇清徐传奇刘凌云潘志娟张开威郑松明
Owner SUZHOU UNIV
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