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Blast furnace molten hot slag recycling technology adopting hot molten salt method

A technology of melting heat and hot molten salt, applied in recycling technology, process efficiency improvement, ammonium sulfate and other directions, can solve the problems of solid waste accumulation, a large amount of solid acid-base waste residue, high product cost and uneconomical problems

Pending Publication Date: 2020-12-29
青岛核盛智能环保设备有限公司
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, most of the elements in the blast furnace molten hot slag are extracted by acid and alkali methods, but a large amount of solid acid-base waste residue and a large amount of acid-base liquid cannot be processed.
Moreover, the equipment investment is large, the product cost is high and uneconomical, resulting in the accumulation of solid waste

Method used

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  • Blast furnace molten hot slag recycling technology adopting hot molten salt method
  • Blast furnace molten hot slag recycling technology adopting hot molten salt method
  • Blast furnace molten hot slag recycling technology adopting hot molten salt method

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Embodiment Construction

[0069] Such as figure 1 and 2 As shown, the present invention provides a kind of blast furnace molten hot slag hot molten salt method recycling process, comprises ammonium chloride process and / or ammonium sulfate process, and ammonium chloride process comprises the following steps:

[0070] S11: Blast furnace molten hot slag is desulfurized (1400-1600°C) at the same time as iron is recovered by high temperature pyrolysis in the hot molten slag quenching and tempering pool under the condition of oxygen or gas, and the hot molten slag is adjusted by electric heating. The mass pool is heated to maintain the appropriate temperature of the blast furnace molten hot slag. At high temperature, the activity of the oxide is high, and the reaction with the subsequent ammonium chloride is more thorough; new blast furnace molten hot slag, carbon dioxide and sulfur dioxide are generated, and after waste heat recovery , the sulfur dioxide is washed by the ammonia washing tower to generate l...

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Abstract

The invention discloses a blast furnace molten hot slag recycling technology adopting a hot molten salt method and belongs to the technical field of recycling of blast furnace molten hot slag. According to the technical scheme of the technology, the technology comprises an ammonium chloride technology and / or an ammonium sulfate technology. According to the technology, hydrochloric acid, sulfuric acid and alkali are not used, and thus while the acid and alkali expense is saved, the problem of corrosion resistance of equipment is effectively solved; while iron in the blast furnace molten hot slag is deposited and recycled through a high-temperature fire method, enthalpy of the hot slag is utilized for extracting and separating rare elements in the blast furnace molten hot slag; and elementssuch as calcium, magnesium, aluminum, titanium, silicon, manganese and fluorine in the slag can also be extracted and separated, heat energy of the blast furnace molten hot slag is fully utilized, allthe elements in the blast furnace molten hot slag can be recycled economically and reasonably, pollution is avoided, and energy and resources of the blast furnace molten hot slag are utilized.

Description

technical field [0001] The invention relates to the technical field of recycling blast furnace molten hot slag, in particular to a hot molten salt recycling process for blast furnace molten hot slag. Background technique [0002] Blast furnace molten hot slag is a by-product discharged from the blast furnace in the process of smelting pig iron. The blast furnace molten hot slag is usually released at a temperature of 1400-1600°C, and its heat content is 58-70Kg standard coal / ton slag. The sensible heat taken away by the blast furnace accounts for about 10% of the heat balance of the blast furnace, which accounts for about 4% of the total energy consumption of the iron and steel industry. Based on the current level of my country's metallurgical technology, for every ton of pig iron smelted, the amount of molten hot slag produced in the blast furnace is between 300-350Kg. Calculated as 900 million tons of iron per year, the molten hot slag of the blast furnace is about 300 mil...

Claims

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Application Information

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IPC IPC(8): C22B7/04C21B3/06C21B13/00C22B1/11C22B21/00C22B26/20C22B34/12C22B34/22C22B47/00C22B58/00C22B59/00C01C1/16C01C1/24C01C1/26C01F5/24C01F11/18C01G45/00
CPCC22B7/04C21B3/06C22B1/11C21B13/00C22B7/002C22B21/00C22B34/1218C22B26/20C22B47/00C22B34/22C22B58/00C22B59/00C01C1/24C01C1/26C01C1/164C01F11/18C01F5/24C01G45/00Y02P10/20Y02P20/129Y02W30/50
Inventor 胡长春龚景仁卢伟
Owner 青岛核盛智能环保设备有限公司
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