439results about "Ammonium chloride" patented technology

Methods and systems for a zero discharge waste water treatment system are provided. The system includes a filtration train including filter media having successively smaller diameter filtration elements, a reverse osmosis apparatus including a pump and a membrane coupled in flow communication with said filtration train, a vapor compressor coupled in flow communication with said reverse osmosis apparatus, and a spray dryer coupled in flow communication with said vapor compressor, said spray dryer configured to separate moisture in a brine solution from particulate suspended in the brine solution.

The invention discloses a method for preparing magnesium aluminate spinel by using secondary aluminum ash. The method comprises the following steps: (1) preparing the secondary aluminum ash as a raw material; (2) calcining for 1-3 h in 900-1200 DEG C, after cooling, ball-milling and preparing secondary aluminum ash fine powder; (3) adding the secondary aluminum ash fine powder to water, under theconditions of a temperature of 50-98 DEG C and stirring, and performing water leaching by applying an ultrasonic wave; feeding an ammonia gas generated by the water leaching to a reaction tank and generating ammonium chloride with hydrochloric acid; (4) filtering and separating a leaching residue, after washing and drying, mixing with a material containing magnesium oxide, and levigating; (5) pressing as pellets; and (6) sintering the pellets in a high temperature or smelting in an electric arc furnace so as to prepare the magnesium aluminate spinel. The method is rapid in reaction speed, andcapable of enabling nitrogen to be converted to the ammonia gas which is discharged and recycled, enabling soluble impurities to enter a liquid phase, and realizing the further impurity removal. The prepared magnesium aluminate spinel is high in purity, and less in impurity content.

The invention discloses a circuit board acid-base etching waste liquid recycling treatment technology. Acidic etching waste liquid and alkaline etching waste liquid are neutralized to generate copperoxychloride, copper oxychloride reacts with an alkaline solution to generate copper oxide, copper oxide reacts with concentrated sulfuric acid to generate copper sulfate, and filtrate and washing water in the reactions are collected. The circuit board acid-base etching waste liquid recycling treatment technology makes copper ions precipitate to generate different copper-containing products througha plurality of steps, operation is easy, the cost is low, etching waste liquid ca be treated on a large scale, meanwhile, the treated filtrate is sufficiently utilized to prepare etching liquid again, the economic benefit is enhanced, emission is reduced, and environmental protection is facilitated.

The present invention provides a reactor for the gas-phase reaction of commercially available gases in the presence of an inert carrier gas to form product gas. The reactor has a streamlined, compact configuration and at least one solids collection and removal system downstream of the reactor, where solids are efficiently removed from the product gas stream, leaving high purity product gas. The removal system allows for a simple reactor design, which is easy to clean and operates continuously over longer periods of time.

The invention provides a method for preparing gypsum whiskers, magnesium chloride, ammonium magnesium phosphate and ammonium chloride from phosphate tailings. The method comprises the following steps:adding an acidizing fluid into phosphate tailings in batches, dropwise adding hydrochloric acid to react, separating silicon slag and an acidolysis solution, and cooling and crystallizing the acidolysis solution to obtain calcium chlorophosphate and acidolysis solution; adding concentrated sulfuric acid into the acidizing fluid, dropwise adding the acidolysis fluid for reaction, and performing centrifugal separation after reaction to obtain gypsum whiskers and the acidizing fluid; heating and concentrating the acidizing fluid, crystallizing to obtain a magnesium chloride solution, and centrifugally separating the magnesium chloride solution to obtain magnesium chloride hexahydrate and a magnesium chloride mother liquor; adding ammonium sulfate and calcium chlorophosphate into the magnesium chloride mother liquor for reaction, filtering to obtain gypsum and a filtrate after the reaction is finished, dropwise adding ammonia water into the filtrate, cooling and filtering to obtain ammonium magnesium phosphate and an ammonium chloride solution; heating, concentrating, and cooling the ammonium chloride solution to obtain ammonium chloride crystals and a crystallization mother liquor, and after centrifugal separation, preparing a 5 to 20% ammonia water solution from the crystallization mother liquor and ammonia water. According to the technical scheme, the recovery rate of phosphorus reaches 99%, and the recovery rate of calcium reaches 95%.

The invention discloses a harmless treatment and utilization method for aluminum ash. On the basis of a conventional process, the method comprises the following steps: additionally pretreating an aluminum ash raw material, namely performing primary disliquid washing treatment on the aluminum ash with a diluted alkali liquid or water, performing gas-water separation on a gas with ammonia gases, hydrogen and acetylene in the disliquid washing process, collecting the gas, recycling the ammonia gases with a diluted acid liquid for preparing an ammonium salt, and utilizing a combustible gas after ammonia removal as fuel of later procedures; dissolving cyanide, dissoluble fluoride and chloride in the aluminum ash into a liquid phase in disliquid washing to form an alkali pretreatment liquid, thereby separating the dissoluble substances from insoluble solid phases in the aluminum ash. Due to addition of a specific procedure of harmless treatment on environment danger sources, main danger sources, namely cyanide and dissoluble fluoride in the aluminum ash are separated from the aluminum ash, convenience is brought to later harmless treatment, meanwhile the chloride in the aluminum ash is dissolved, and the situation that later disliquid process is affected by the chloride is avoided; and therefore, the purpose that potential danger is eliminated while the aluminum ash is recycled is achieved.

The invention discloses a technology for producing sodium bicarbonate and ammonium chloride by using triamine tail gas. The technology takes ammonia and carbon dioxide-containing melamine tail gas aswell as bittern or brine as raw materials, and adopts the technical processes of bittern or brine purification, tail gas deamination, triamine tail gas ammonia suction, ammoniacal brine carbonation, sodium bicarbonate separation, sodium bicarbonate pulp-mixing, wet decomposition, clarification and refined filtration, alkali liquor re-carbonation, sodium bicarbonate centrifugal drying, sodium bicarbonate filtrate deamination, multiple-effect evaporation and concentration salt manufacturing, multiple-effect flash vaporization ammonium manufacturing and separating and drying and the like to enable the tail gas generated through melamine production by urea is effectively used. The technology provided by the invention overcomes the defects that the spent liquor discharge amount of an ammonia-soda process is large and the mother solution of a combined alkaline manufacturing method is difficult to balance, the floor space of a device is small, and only low grade steam is used.

The invention discloses a device for treating biurea condensation sewage generated from preparation of an ADC (Azodicarbonamide) foaming agent with a urea method and a use method of the device, relates to a sewage treatment device and a use method thereof, and aims to solve the problem that COD (Chemical Oxygen Demand) in effluent of the biurea condensation sewage generated when the ADC foaming agent is prepared by using the urea method is hard to meet standards. The device consists of an evaporation crystallizer, a high-temperature salt bath decomposition and gas absorption system and a pressure hydrolysis-flash evaporation system. The use method disclosed by the invention comprises the following steps: feeding sewage into the evaporation crystallizer, performing cooling crystallization on concentrated liquid, feeding into an ammonia distillation tower for ammonia distillation, discharging the bottom liquid of the ammonia distillation tower into the pressure hydrolysis-flash evaporation system for decomposition treatment, and feeding salt generated from evaporation crystallization into the high-temperature salt bath decomposition and gas absorption system for purification treatment. By adopting the device and the use method, urea and hydrazine hydrate of the ADC condensation sewage can be recycled, sodium chloride can be purified, the water circulation utilization rate can be increased, and standards of indexes such as COD in the effluent can be met.

The invention discloses a deep hydrolysis method of aluminum nitride in aluminum ash. The deep hydrolysis method comprises the following steps of 1) crushing the aluminum ash to form aluminum ash withthe particle size being 10mm or below, then heating the aluminum ash to a certain temperature, and uniformly mixing the heated aluminum ash and water according to a certain ratio; 2) performing grinding and hydrolyzing on obtained high-temperature slurry, and collecting ammonia gas produced by hydrolyzing at the same time to obtain corresponding ammonia water or ammonium salt; and 3) performing dewatering and filtering on the slurry after hydrolyzing to obtain a filter cake and a filtrate, and performing evaporation to recover industrial salt after circulating enrichment of the filtrate. According to the deep hydrolysis method provided by the invention, through the hydrolysis process of high temperature grinding and strengthening the aluminum nitride, deep hydrolysis of the aluminum nitride is realized, ammonia recovery is realized at the same time, so that a new way of harmless and resource utilization of the aluminum nitride in the aluminum ash is opened up.

The invention discloses a method for producing silicon nitride powder. The method comprises the following steps: 1) reacting silicon tetrachloride and ammonia which are used as raw materials in order to synthesize a silicon nitride precursor Si(NH)2 solid, and obtaining pure Si(NH)2 powder; 2) transferring the Si(NH)2 into a high temperature furnace, and calcining the Si(NH)2 to obtain amorphous silicon nitride powder; and 3) refining and briquetting the obtained silicon nitride powder, transferring the briquetted powder into a high temperature crystallization furnace, and performing calcination to obtain crystalline silicon nitride powder. The method can continuously synthesize the silicon nitride precursor, and can flexibly control the particle size, the shape and the phase composition of the final product silicon nitride powder by adopting two calcination treatments which are low temperature decomposition of the Si(NH)2 and high-temperature crystallization of the amorphous silicon nitride powder; no organic solvents participate in the whole process, so carbon impurities in the silicon nitride powder are avoided; and the raw materials used for the product are produced in large scale in China, so low-cost production of high-purity sub-micron isometric silicon nitride powder is achieved.

The invention relates to an energy-saving ammonium chloride wastewater freeze-concentration crystallizing system and a technology thereof. The system comprises a stock solution precooler, a freezing forced circulation heat exchanger, a freezing crystallization separator and a solid-liquid separation device which are connected in sequence, an ice crystal melting tank is connected between the freezing crystallization separator and the stock solution precooler, and the solid-liquid separation device is connected with the freezing forced circulation heat exchanger. The system is an energy-saving and emission-reducing apparatus, and has a high heat efficiency and a low power consumption; compared with an existing ammonium chloride evaporative crystallization technology, the technology of the invention has the advantages of low temperature and normal pressure conditions, no consumption of steam, reduction of the dependence on a boiler, reduction of pollutants, energy saving and environmentalfriendliness; and compared with conventional technologies, the technology provided by the invention has the advantages of realization of the continuous wastewater treatment effect, low energy consumption, freeness of steam consumption, few pollutants, greenness and environmental friendliness.

The invention relates to a cyclic manufacturing method for coproduction of baking soda and ammonium chloride. The cyclic manufacturing method comprises the steps of primary precipitating of baking soda, cold precipitation crystallization, salt precipitation crystallization and mother liquor cycling which are conducted sequentially; and the cyclic manufacturing method further comprises the step that the step of secondary precipitating of baking soda is arranged between the salt precipitation crystallization step and the mother liquor cycle step, and the step of secondary precipitating of bakingsoda is used for further precipitating the baking soda from baking soda mother liquor (I-II) generated after salt precipitation crystallization. By adopting the cyclic manufacturing method, energy consumption of ammonium chloride recovering through cold precipitation crystallization can be decreased, the baking soda and the ammonium chloride are efficiently produced, meanwhile, full cycle of motor liquor generated in a reaction in the production process is achieved, the process is easy, and the production cost is low.

The invention discloses a comprehensive recycling utilization method of potassium-containing wastewater generated in a synthesis process of dicamba. The comprehensive recycling utilization method comprises the following steps: adding acid into potassium-containing wastewater I generated in the synthesis process of the dicamba, and naturally depositing; conveying a water layer obtained by layering into a macroporous adsorption resin bed through a pump; adsorbing and recycling dicamba intermediates, namely 2,5-dichlorophenol and 3,6-dichlorosalicylic acid, in the water layer through the macroporous adsorption resin bed; adding active carbon and stirring and filtering; adding alkali liquid to adjust the pH (Potential of Hydrogen); adding active carbon into potassium-containing wastewater IV; stirring and filtering; conveying the wastewater into a chelating resin bed through the pump; removing high-valent metal cations in the alkaline potassium-containing wastewater IV through ion exchange; conveying the wastewater into a cation exchange resin bed through the pump; carrying out the ion exchange to obtain a potassium hydrogen carbonate solution and an ammonium chloride solution respectively; and drying an obtained potassium hydrogen carbonate wet product to obtain potassium hydrogen carbonate, or calcining the potassium hydrogen carbonate wet product at a high temperature to obtain potassium carbonate.

The invention relates to a low-grade mixed rare earth ore concentrate chemical dressing and chemical dressing waste water resource comprehensively recycling method, which is characterized by comprising the steps of: A) performing mixed chemical dressing to the low-grade ore concentrate (REO -50%, 8% <= CaO <= 15%) with a hydrochloric acid solution and an enhanced impurity remover; B) adding a sulfuric acid solution to chemical dressing waste water to remove Ca<2+> to form calcium sulphate dihydrate; C) treating the low-grade mixed rare earth ore concentrate with the chemical dressing waste water after calcium removal; D) after the calcium removal of the cyclic chemical dressing waste water, neutralizing the waste water with ammonia water or liquid ammonia step-by-step to respectively recycle iron, rare earths, a phosphorus enriched product and a crude calcium fluoride side product; and E) evaporating and concentrating the waste water to obtain ammonium chloride crystal and distilled water. In the method, through enhanced chemical dressing technology, the low-grade mixed rare earth ore concentrate is enriched according to 62% <= REO grade <= 70% and CaO <= 2.5%. With the difference of physical and chemical properties of the salts in the mixture liquid and the characters of the rare earth ore treatment process, the method enriches the ore and achieves resource comprehensive utilization easily and high-effectively.

The invention discloses a method for efficiently separating fluorine, chlorine and nitrogen components from aluminum ash for co-production of aluminum oxide concentrate. The method comprises the following steps: putting aluminum ash and water into a reaction kettle, performing desalination denitrification treatment, performing solid-liquid separation on slurry after desalination denitrification treatment, sufficiently mixing a solid phase obtained after separation with an alkali liquid, performing a defluorination reaction, performing filtration, washing and separation on a defluorination slurry so as to obtain a solid phase and a liquid phase, wherein the obtained solid phase is aluminum oxide concentrate; performing a neutralization reaction on the liquid phase by using a diluted acid, and adjusting the pH value of the solution to be neutral; performing a solution defluorination reaction on the blended neutral solution with the liquid phase obtained after desalination denitrification; performing a sufficient defluorination reaction on the solution, and performing solid-liquid separation so as to obtain a solid phase, namely a fluorine salt; and performing evaporation crystallization on the liquid phase after solid-liquid separation, so as to obtain a crystallization product, namely a chlorine salt. Due to the desalination denitrification process and the defluorination process, products such as ammonium hydroxide, the chlorine salt, the fluorine salt and the high-purity aluminum oxide concentrate can be prepared, and efficient separation of aluminum oxide, salts and toxicand harmful components in the aluminum ash can be achieved.

A system and method for passive capture of ammonia in an enclosure containing material that gives off ammonia. The invention allows for the passage of gaseous NH₃ through microporous hydrophobic gas-permeable membranes and its capture in a circulated acidic solution with concomitant production of a concentrated non-volatile ammonium salt.

The invention relates to a potassium nitrate crystallization system and process through a double-decomposition method. The potassium nitrate crystallization system comprises a dissolving tank, a potassium nitrate vacuum crystallization device, a thickener, a first centrifuge, a mixing tank, a concentration device, a potassium chloride crystallization device and a second centrifuge. The potassium nitrate crystallization process comprises the following steps: adding circulating mother liquid, water and potassium chloride into the dissolving tank, sequentially feeding material liquid into the potassium nitrate vacuum crystallization device, the thickener and the first centrifuge, separating potassium nitrate crystals from the first centrifuge, drying and cooling, thereby obtaining the finished product potassium nitrate; adding potassium nitrate crystal mother liquid into the mixing tank, adding ammonium nitrate, uniformly mixing, and sequentially feeding the mixture into the concentration device, the ammonium chloride crystallization device and the second centrifuge; separating ammonium chloride crystals from the second centrifuge, drying and cooling, thereby obtaining the finished product ammonium chloride. A set of novel potassium nitrate crystallization system and process through the double-decomposition method are disclosed by the invention, the stability of potassium nitrate crystallization is improved, and the production quality and the yield are effectively ensured.

The invention relates to a method for recovering 6-APA and salt from a 6-APA mother liquor, belongs to the technical field of pharmaceuticals. The process comprises the following steps: using a nanofiltration membrane for concentrating the 6-APA mother liquor; recovering 6-APA from a nanofiltration concentrate; recovering ammonium chloride or sodium chloride from a 6-APA nanofiltration dialyzate; meanwhile, recovering condensation water in an evaporative crystallization process. Compared with the prior art, the invention has the advantages that 6-APA and sodium chloride or ammonium chloride are recovered from the 6-APA mother liquor, steam condensation water of feed liquid is obtained while evaporating the recovered salt, the condensation water can be recycled into the workshop, to achieve the resource utilization of 6-APA mother liquor.