Recycling using method of aluminum ash at last time

A technology for aluminum ash and ammonia removal, applied in chemical instruments and methods, preparation/separation of ammonium nitrate, ammonia, etc., can solve the problem of recycling ammonia and chloride in aluminum ash, large investment in equipment, and difficulty in refining Large and other problems, to avoid air dust pollution, improve utilization, and achieve the effect of harmlessness

Inactive Publication Date: 2018-06-01
湛卫华
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The aluminum ash recycling technology of the prior art has the following deficiencies: (1) all need to be provided with special refining equipment to extract pure aluminum and alumina, the equipment investment is too large, the process flow is long, the refining cost is high, the refining difficulty is large, and the energy Serious waste and secondary pollution; 2. The recycling of ammonia and chloride in aluminum ash is not considered; 3. There is no effective recycling of the last aluminum ash, which is likely to cause environmental pollution

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] The recycling method of the last aluminum ash of the present embodiment, its steps are:

[0024] S1, catalytic deamination: add water and catalyst to the last aluminum ash under the condition of stirring and stirring to form a paste, and the weight percentage of water in the paste formed by adding water to the last aluminum ash is 60%; The body is heated and catalytically decomposed to remove ammonia, and the escaped ammonia generated by catalytic decomposition and deamination enters the ammonia absorption tower; the catalyst is one of sodium organic acid, sodium amino acid, sodium carbonate, sodium nitrate, sodium hydroxide, sodium aluminate or Several kinds of mixtures, the amount of catalyst used is 50% of the dry weight of the last aluminum ash; the heating temperature of heating and catalytic decomposition is 130°C, and the time is 1h;

[0025] S2. Use spray water or dilute acid to collect the escaped ammonia gas in the ammonia absorption tower to obtain ammonia wa...

Embodiment 2

[0029] The recycling method of the last aluminum ash of the present embodiment, its steps are:

[0030] S1. Catalytic deamination: Add water and catalyst to the last aluminum ash under the condition of stirring and stirring to form a paste. The weight percentage of water in the paste formed by adding water to the last aluminum ash is 50%; The body is heated and catalytically decomposed to remove ammonia, and the escaped ammonia generated by catalytic decomposition and deamination enters the ammonia absorption tower; the catalyst is one of sodium organic acid, sodium amino acid, sodium carbonate, sodium nitrate, sodium hydroxide, sodium aluminate or Several kinds of mixtures, the amount of catalyst used is 10% of the dry weight of the last aluminum ash; the heating temperature for heating and catalytic decomposition is 120°C, and the time is 2h;

[0031] S2. Use spray water or dilute acid to collect the escaped ammonia gas in the ammonia absorption tower to obtain ammonia water...

Embodiment 3

[0035] The recycling method of the last aluminum ash of the present embodiment, its steps are:

[0036] S1. Catalytic deamination: add water and catalyst to the last aluminum ash under the condition of stirring and stirring to form a paste, and the weight percentage of water in the paste formed by adding water to the last aluminum ash is 80%; The body is heated and catalytically decomposed to remove ammonia, and the escaped ammonia generated by catalytic decomposition and deamination enters the ammonia absorption tower; the catalyst is one of sodium organic acid, sodium amino acid, sodium carbonate, sodium nitrate, sodium hydroxide, sodium aluminate or Several kinds of mixtures, the amount of catalyst used is 100% of the dry weight of the last aluminum ash; the heating temperature for heating and catalytic decomposition is 150°C, and the time is 45min;

[0037] S2. Use spray water or dilute acid to collect the escaped ammonia gas in the ammonia absorption tower to obtain ammon...

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PUM

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Abstract

The invention discloses a recycling using method of aluminum ash at the last time. The recycling using method has the steps that 1, water and a catalyst are added to the aluminum ash at the last timeunder stirring and turning over conditions, a pasty fluid is formed, heating and catalytic decomposition deamination are conducted on the pasty fluid, and escape ammonia generated by catalytic decomposition deamination enters an ammonia absorption tower; 2, in the ammonia absorption tower, spraying water or dilute acid are used to conduct collection to the escape ammonia, and ammonia water or ammonium salt serous fluid are obtained; ammonia water is in cyclic utilization, the generated ammonium salt serous fluid falls into a settling pond in the bottom of the ammonia absorption tower, the ammonium salt serous fluid is sent into a filter press through a pump to be conducted filter pressing dehydration; and the ammonium salt solid obtained after dehydration is recycled and used; 3, drying isconducted; the obtained materials after deamination in the step 1 are added to shoe cover materials, the obtained materials after deamination in the step 1 and the shoe cover materials enter into anelectrolytic cell together; calcinations is conducted by using the electrolytic cell temperature, and calcinations material mixture is formed; and 4, after the calcinations material mixture is crushed, the calcinations material mixture enters into the electrolytic cell to be used as raw materials.

Description

technical field [0001] The invention relates to the technical field of recycling of industrial aluminum ash, in particular to a method for recycling the last aluminum ash. Background technique [0002] Aluminum ash is the slag and floating skin produced in the process of aluminum liquid, aluminum ingot, and secondary aluminum smelting and refining aluminum. The last aluminum ash is a kind of scum produced in the casting production of the aluminum industry, which is in the form of loose ash. The last aluminum ash is a kind of industrial waste residue with large output and serious pollution. It mainly comes from the casting process of electrolytic aluminum plants, aluminum processing plants and the smelting and casting process of secondary aluminum plants. According to statistics, about 20-40 kg of aluminum ash is produced for each ton of raw aluminum processed. The amount produced is less when the aluminum liquid is directly melted and cast, and the amount is more when the al...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22B7/04C22B21/00C01C1/02C01C1/16C01C1/18C01C1/242
CPCC01C1/022C01C1/164C01C1/185C01C1/242C22B7/04C22B21/0069Y02P10/20
Inventor 湛卫华
Owner 湛卫华
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