Low-hydrogen easy-to-weld alkaline flux-cored wire prepared from steel slag and used for structural steel

A technology of flux-cored welding wire and structural steel, which is applied in the direction of welding medium, welding equipment, welding/cutting medium/material, etc., can solve the problems of poor crack resistance of weld seam, reduce alkalinity, and fail to reach, and achieve weld formability Good, the effect of increasing the burning intensity and reducing the formation tendency

Active Publication Date: 2021-01-22
ZHENGZHOU UNIV
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  • Abstract
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  • Claims
  • Application Information

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Problems solved by technology

When welding structural steel, the main problems are: ①The molten droplet transitions in coarse particles, and the splash is large during the welding process; ②The fluidity of the slag is too large, and it is difficult to realize all-position welding; Make the weld narrow and poorly formed; ④ Difficult to remove slag; ⑤ In order to ensure the welding quality, the amount of marble added is usually reduced, but the alkalinity of the slag is reduced, and the crack resistance of the weld is poor; ⑥ In order to avoid hydrogen embrittlement, usually Fluorite (the main component is calcium fluoride) is added to remove hydrogen, but the arc atmosphere is deteriorated, and the welding arc is unstable; Poor mechanical properties
But there are the following deficiencies: ① Fluorite and sodium fluorosilicate are added to the flux core, which deteriorates the welding arc. Although the welding arc is stable as recorded in the manual, there is neither theoretical support nor data verification, and the flux cored wire belongs to Non-self-shielded welding wire, CO2 is required for welding 2 Gas protection, in addition to increasing the cost of use, is also easy to mix nitrogen in the air when the protective atmosphere is not good (on the one hand, nitrogen pores are generated, on the other hand, nitrogen enters the deposited metal, reducing its crack resistance), welding processability The degree of improvement is low; ②Al existing in steel slag 2 o 3 When welding with MnO, MnO·A1 will be generated 2 o 3 Spinel-type compounds, they are built on the iron oxide lattice on the surface of the weld metal, which will cause the slag and the weld metal to stick together firmly, making it more difficult to remove the slag; Added in the form of an intermediate alloy, resulting in poor uniformity of the chemical composition of the deposited metal,

Method used

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  • Low-hydrogen easy-to-weld alkaline flux-cored wire prepared from steel slag and used for structural steel

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] Low-hydrogen easy-to-weld basic flux cored wire for structural steel prepared from steel slag, including flux core powder and sheath, the chemical composition and dosage of flux core powder are calculated by mass percentage: 28% steel slag, 9.0% Mo40V40Al20 powder, FeMn60Si34C0.02 Powder 8.2%, FeTi80-A powder 5.0%, CaF coated with Ni 2 Powder 9.6%, Nano TiO 2 6.0%, 200 mesh nitrocellulose powder 3.8%, feldspar 3.0%, the balance is FHT100·25 reduced iron powder, CaF 2 The particle size of the powder without Ni plating is 5μm-10μm, the thickness of the Ni plating layer is 30nm-50nm, and the outer skin is made of low-carbon cold-rolled steel strip.

[0038] The chemical composition of steel slag is calculated by mass percentage: SiO 2 1.5%-3.0%, Al 2 o 3 32%-36%, MgO8%-12%, CaO49%-52%, FeO0.3%-0.5%, MnO0.5%-1.5%, S+P≤0.03%; Mo40V40Al20 powder, FeMn60Si34C0.02 powder, FeTi80 -The 100-mesh passing rate of A powder is 100%.

[0039] The thickness of the steel strip is 0...

Embodiment 2

[0050] Low-hydrogen easy-to-weld basic flux cored wire for structural steel prepared from steel slag, including flux core powder and sheath, the chemical composition and dosage of flux core powder are calculated by mass percentage: 22% steel slag, 7.5% Mo40V40Al20 powder, FeMn60Si34C0.02 Powder 5.6%, FeTi80-A powder 4.1%, CaF coated with Ni 2 Powder 7.8%, Nano TiO 2 4.2%, 200 mesh nitrocellulose powder 3.1%, feldspar 2.1%, the balance is FHT100·25 reduced iron powder, CaF 2 The particle size of the powder without Ni plating is 5μm-10μm, the thickness of the Ni plating layer is 30nm-50nm, and the outer skin is made of low-carbon cold-rolled steel strip.

[0051] The chemical composition of steel slag is calculated by mass percentage: SiO 2 1.5%-3.0%, Al 2 o 3 32%-36%, MgO8%-12%, CaO49%-52%, FeO0.3%-0.5%, MnO0.5%-1.5%, S+P≤0.03%.

[0052] The 100-mesh passing rate of Mo40V40Al20 powder, FeMn60Si34C0.02 powder and FeTi80-A powder is 100%.

[0053] The thickness of the steel...

Embodiment 3

[0058] Low-hydrogen easy-to-weld basic flux cored wire for structural steel prepared from steel slag, including flux core powder and sheath, the chemical composition and dosage of flux core powder are calculated by mass percentage: 25% steel slag, 8.3% Mo40V40Al20 powder, FeMn60Si34C0.02 Powder 7.0%, FeTi80-A powder 4.7%, CaF coated with Ni 2 Powder 8.6%, Nano TiO 2 5.0%, 200 mesh nitrocellulose powder 3.4%, feldspar 2.6%, the balance is FHT100·25 reduced iron powder, CaF 2The particle size of the powder without Ni plating is 5μm-10μm, the thickness of the Ni plating layer is 30nm-50nm, and the outer skin is made of low-carbon cold-rolled steel strip.

[0059] The chemical composition of steel slag is calculated by mass percentage: SiO 2 1.5%-3.0%, Al 2 o 3 32%-36%, MgO8%-12%, CaO49%-52%, FeO0.3%-0.5%, MnO0.5%-1.5%, S+P≤0.03%.

[0060] The 100-mesh passing rate of Mo40V40Al20 powder, FeMn60Si34C0.02 powder and FeTi80-A powder is 100%.

[0061] The thickness of the steel ...

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Abstract

The invention belongs to the technical field of welding materials, and particularly relates to a low-hydrogen easy-to-weld alkaline flux-cored wire prepared from steel slag and used for structural steel. The flux-cored wire is formed in a manner that a low-carbon cold-rolled steel strip is wrapped with flux core powder, and the flux core powder comprises 22%-28% of steel slag, 7.5%-9.0% of Mo40V40Al20 powder, 5.6%-8.2% of FeMn60Si34C 0.02 powder, 4.1%-5.0% of FeTi80-A powder, 7.8%-9.6% of CaF2 powder plated with Ni on the surface, 4.2%-6.0% of nano TiO2, 3.1%-3.8% of 200-mesh nitrocellulose powder, 2.1%-3.0% of feldspar and the balance FHT100.25 iron powder reduced. During welding, the flux-cored wire is stable in electric arc, small in splashing, good in post-welding forming, easy to deslag, suitable for all-position welding, low in residual hydrogen content in deposited metal, uniform in chemical component and high in mechanical property, and is an innovation in the aspect of alkaline flux-cored wires.

Description

technical field [0001] The invention belongs to the technical field of welding materials, and in particular relates to a low-hydrogen easy-welding basic flux-cored welding wire for structural steel prepared by using steel slag. Background technique [0002] Basic welding materials have the advantages of low hydrogen, high toughness, high crack resistance and excellent mechanical properties. Basic welding wire is generally the first choice for welding important structural parts. The core powder of the existing basic flux-cored welding wire for structural steel welding is composed of mineral powder and alloy powder. Due to the problems in the components, the mineral powder should be added with alkaline substances such as marble and magnesium oxide. When welding structural steel, the main problems are: ①The molten droplet transitions in coarse particles, and the splash is large during the welding process; ②The fluidity of the slag is too large, and it is difficult to realize al...

Claims

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Application Information

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IPC IPC(8): B23K35/30B23K35/40
CPCB23K35/3053B23K35/40
Inventor 陈永刘胜新李立碑孟迪潘继民付雅迪王靖博吴书菲马贺祥
Owner ZHENGZHOU UNIV
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