Roller for continuous induction type rapid quenching furnace and manufacturing method of roller

A manufacturing method, inductive technology, applied to other manufacturing equipment/tools, turbines, engine components, etc., can solve the problem of extending the working cycle, not involving the chemical composition of molybdenum rollers, physical properties and preparation methods of size specifications, lack of molybdenum and Molybdenum alloy roller physical properties and other issues

Active Publication Date: 2021-05-14
GRIMAT ENG INST CO LTD
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  • Claims
  • Application Information

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Problems solved by technology

However, the above patents only mention the application of molybdenum rollers in the preparation of rapid quenching alloys, etc., and do not involve the chemical composition, size specifications, physical properties and preparation methods of molybdenum rollers
Youyan Rare Earth New Materials Co., Ltd. invented a thermal fatigue-resistant chilled roll material and its preparation method (ZL 201410432981.7), which mentioned that when the rare earth permanent magnet material is prepared by the rapid quenching method, the cooling roll always has the problem of thermal fatigue and fatigue The short life cannot meet the industrializat

Method used

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  • Roller for continuous induction type rapid quenching furnace and manufacturing method of roller
  • Roller for continuous induction type rapid quenching furnace and manufacturing method of roller
  • Roller for continuous induction type rapid quenching furnace and manufacturing method of roller

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preparation example Construction

[0042] (1) Preparation of molybdenum or molybdenum alloy powder: the present invention adopts 2.5-5.0 μm medium particle specification high-purity molybdenum powder or 0.5-5.0 μm medium-fine particle specification REO rare earth oxide doped molybdenum alloy powder as raw material, wherein by Molybdenum powder obtained by hydrometallurgical high purification has a Mo content of not less than 99.9% by weight, low C / O (≤50 / 500ppm) and K / W (≤20 / 50ppm) impurity content, or liquid-liquid, solid-liquid REO is uniformly doped by the method, the REO content is 0.01% by weight to 5.0% by weight, and the REO is selected from Y 2 o 3 、Sc 2 o 3 , La 2 o 3 、Ce 2 o 3 、Nd 2 o 3 、Sm 2 o 3 、Gd 2 o 3 and ZrO 2 Among them, molybdenum alloy powder uniformly doped with REO is used as raw material, which can provide better protection for the toughening and high temperature resistance of molybdenum rollers.

[0043] (2) Compressed ring billet: cold isostatic pressing is used for pressin...

Embodiment 1

[0050] To achieve Nd via liquid-liquid method 2 o 3 Uniformly doped 1.2μm fine-grain molybdenum alloy powder is used as raw material, and its Nd 2 o 3 The content is 0.5% by weight; the Nd 2 o 3 Evenly doped molybdenum alloy powder is evenly loaded into the soft rubber sleeve with high-quality carbon steel as the rigid mandrel. When loading the material, it must be beaten evenly with a pestle and tightly sealed with iron wires. Cold isostatic pressing under 350MPa pressure for 5 minutes to obtain the shape More regular Nd 2 o 3 Doped molybdenum alloy annular compact; place the single REO-doped molybdenum alloy annular compact in a medium-frequency induction heating resistance furnace, supplemented by high-temperature-resistant high-purity ceramic particles with high sphericity as the sintering pad to minimize the ring Friction between the billet and the contact surface, sintering at 1800°C for 4 hours in a high-purity hydrogen atmosphere with a dew point of -50°C, to obt...

Embodiment 2

[0052] Using the 4.0μm medium particle size molybdenum powder highly purified by hydrometallurgy as raw material, the Mo content is 99.99% by weight, the impurity C / O is 50ppm / 500ppm, and the K / W is 20ppm / 50ppm respectively; the high-purity molybdenum powder Evenly put it into the soft rubber sleeve with ordinary carbon steel as the rigid mandrel. When loading, it must be pounded evenly and tightly sealed with iron wires. Cold isostatic pressing under 250MPa pressure for 20 minutes to obtain a molybdenum ring with a relatively regular shape. The molybdenum annular compact is placed in a high-temperature tungsten wire mesh resistance heating furnace, supplemented by high-temperature-resistant high-purity ceramic particles with a high degree of sphericity as a sintering pad to minimize the friction between the ring blank and the contact surface. Sintering at a high temperature of 1900°C for 8 hours in a high-purity hydrogen atmosphere with a dew point of -60°C to obtain a pure mo...

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Abstract

The invention relates to a roller for a continuous induction type rapid quenching furnace and a manufacturing method of the roller, and belongs to the field of refractory metal powder metallurgy and deformation machining. The roller is made of pure molybdenum or REO doped molybdenum alloy materials, the outer diameter is 400-800 mm, the wall thickness is 15-60 mm, the relative density is not lower than 99.5%, and the tensile strength is not lower than 500 MPa. The manufacturing method comprises the following steps: by taking molybdenum and molybdenum alloy powder which are highly purified by a wet method or are uniformly doped with rare earth oxide by a liquid-liquid or solid-liquid method as raw materials, performing cold isostatic pressing to obtain a ring blank, performing hydrogen high-temperature sintering, performing rough turning, performing ring forging or closed die forging, performing hydrogen annealing treatment, and finally performing precision machining. The roller is uniform in component, high in density, good in strength and toughness and excellent in thermal fatigue resistance, serves as an important component of a large continuous induction type rapid quenching furnace as core equipment for rare earth bonded magnetic powder production, and can be extensively applied to development and production of iron-based soft magnetic amorphous alloy, thermoelectric materials and the like.

Description

technical field [0001] The invention belongs to the field of refractory metal powder metallurgy and deformation processing, and in particular relates to a roller for a continuous induction type quick quenching furnace and a manufacturing method thereof. Background technique [0002] In recent years, mechanical and electronic products have shown the development trend of miniaturization, thinning, light weight, high frequency, low loss, and low noise, which has led to a rapid increase in the amount of high-performance bonded magnets. The core equipment for the production of key raw material magnetic powder is a large continuous induction quenching furnace, in which the chilled roller of the critical part determines the product performance and affects the continuous production capacity of the equipment. Generally speaking, thermal conductivity, that is, the product of thermal diffusivity, density and specific heat capacity (κρCp), is often used to measure the quality of the chi...

Claims

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Application Information

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IPC IPC(8): B22D11/06B22F5/00B22F3/04B22F3/10B22F3/24C22C27/04C22C32/00
CPCB22D11/0651C22C27/04B22F5/00B22F3/04B22F3/1007B22F3/24C22C32/001B22F2003/247B22F2003/248
Inventor 周增林李艳何学良惠志林陈文帅陆艳杰
Owner GRIMAT ENG INST CO LTD
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