Solar cell silicon wafer cleaning agent and solar cell silicon wafer cleaning method

A cleaning agent technology for solar cells and silicon wafers, which is applied in the direction of chemical instruments and methods, detergent compositions, detergent compounding agents, etc., and can solve the problem of large thinning of silicon wafers, harsh cleaning liquid use conditions, and non-compliance with environmental protection requirements And other issues

Active Publication Date: 2021-06-11
嘉兴市小辰光伏科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although rough polishing can remove the surface damage layer and remove surface pollutants to a certain extent, the rough polishing process consumes a lot of alkali, resulting in a large amount of silicon wafer thinning and a high fragmentation rate
In addition, after rough polishing and cleaning, the suede surface obtained by making texture is larger, the uniformity is poor, the nucleation is low, and the reflectivity of the obtained silicon wafer is high, which leads to low conversion efficiency of the battery
[0006] Of course, in addition to the above-mentioned coarse throwing process, there is also a method of cleaning with chemical reagents. For example, the patent document of Publication No. CN108559639A discloses "a cleaning solution for the surface treatment of black silicon cells, which consists of fluorine compounds, alcohol additives, It is prepared by mixing complexing agent, dispersant, surfactant and deionized water. The mass percentage of each raw material is: fluorine compound 8%-25%, alcohol auxiliary agent 5%-30%, complexing agent 2%- 6%, dispersant 4%-15%, surfactant 5%-10%, deionized water 14%-76%"; the cleaning solution uses fluorine compounds, which are harmful to the environment and do not meet the current environmental protection requirements ; At the same time, the use of the cleaning solution is relatively harsh, and the surface of the black silicon cell can be effectively cleaned only under ultrasonic conditions.

Method used

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  • Solar cell silicon wafer cleaning agent and solar cell silicon wafer cleaning method
  • Solar cell silicon wafer cleaning agent and solar cell silicon wafer cleaning method
  • Solar cell silicon wafer cleaning agent and solar cell silicon wafer cleaning method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0039] 1. Prepare solar cell cleaning solution:

[0040] Take a 5L PP measuring cup, add 4.5L deionized water, then add 2g fatty alcohol polyoxyethylene ether, 3g sodium pyrophosphate, 5g sodium acetate, 0.5g protease, 1.5g lipase, 0.8g cellulase, 2.5g ethyl alcohol Diaminetetraacetic acid and 5g of diethyltriaminepentaacetic acid were stirred evenly to prepare a cleaning agent; 250L of deionized water was added to the pre-cleaning tank, 2.5kg of sodium hydroxide was added to dissolve, and the temperature was raised to 45°C. Take 2.5L of the cleaning agent prepared above and add it to the cleaning tank to obtain the cleaning solution.

[0041] 2. Surface cleaning of silicon wafers for solar cells

[0042] Add 400pcs (pieces) of silicon wafers into the cleaning solution for cleaning for 5 minutes, then put them into the deionized water tank for rinsing, and replenish the cleaning solution. After each cleaning batch, add 30ml of cleaning agent, and the cycle of rehydration is c...

Embodiment 2

[0046] 1. Prepare solar cell cleaning solution:

[0047] Take a 5LPP measuring cup, add 4.5L deionized water, then add 1.0g fatty alcohol polyoxyethylene ether, 1.5g polyoxypropylene polyoxyethylene block copolymer, 10g sodium acetate, 1.0g lipase, 0.8g cellulase, 1.2g of amylase and 20g of diethyltriaminepentaacetic acid were mixed evenly to make a cleaning agent; 250L of deionized water was added to the pre-cleaning tank, 2.5kg of sodium hydroxide was added to dissolve, and the temperature was raised to 50°C. Add 2.5L of the cleaning agent prepared above into the cleaning tank to obtain the cleaning solution.

[0048] 2. Surface cleaning of silicon wafers for solar cells

[0049] Add 400pcs of silicon wafers into the cleaning solution for cleaning for 5 minutes, then put them in deionized water for rinsing, and then replenish the cleaning solution, add 30ml of cleaning agent after each cleaning batch, and complete each batch by circulating the rehydration. Silicon wafer cl...

Embodiment 3

[0053] 1. Prepare solar cell cleaning solution:

[0054] Take a 5L PP measuring cup, add 4.5L deionized water, then add 1.4g fatty alcohol polyoxyethylene ether, 30g sodium pyrophosphate, 50g sodium acetate, 0.3g protease, 0.5g lipase, 0.3g cellulase, 15g ethyl alcohol Diaminetetraacetic acid and 15g of diethyltriaminepentaacetic acid were stirred evenly to prepare a cleaning agent; 250L of deionized water was added to the pre-cleaning tank, 2.5kg of sodium hydroxide was added to dissolve, and the temperature was raised to 45°C. Take 2.5L of the cleaning agent prepared above and add it to the cleaning tank to obtain the cleaning solution.

[0055] 2. Surface cleaning of silicon wafers for solar cells

[0056] Add 400pcs (pieces) of silicon wafers into the cleaning solution for cleaning for 5 minutes, then put them into the deionized water tank for rinsing, and replenish the cleaning solution. After each cleaning batch, add 30ml of cleaning agent, and the cycle of rehydration ...

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PUM

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Abstract

The invention discloses a solar cell silicon wafer cleaning agent and a solar cell silicon wafer cleaning method, wherein the solar cell silicon wafer cleaning agent comprises the components in percentage by weight: 0.02-1.0% of a surfactant, 0.1-0.8% of a chelating agent, 0.02-1.0% of compound enzyme, 0.03-2.0% of salt and the balance being water. The solar cell silicon wafer cleaning agent has the characteristics of no volatilization, no pungent smell, strong cleaning effect, no fluorine and environmental protection, and can effectively remove inorganic particles and organic stains adsorbed on the surface of a silicon wafer; meanwhile, the solar cell silicon wafer cleaning method can enable the cleaned silicon wafer to obtain a high-quality textured surface with good uniformity, high nucleation density and low reflectivity in the subsequent texturing process.

Description

technical field [0001] The invention relates to solar cell silicon wafers, in particular to a solar cell silicon wafer cleaning agent and a solar battery silicon wafer cleaning method. Background technique [0002] With the depletion of conventional energy and the increasingly prominent environmental problems, the new energy with the characteristics of environmental protection and renewable has been paid more and more attention by the governments of various countries, and the development and utilization of new energy has become the focus of global attention. Solar energy is favored by people because of its non-polluting, renewable, non-regional and other advantages. The solar photovoltaic industry has also developed rapidly. [0003] In the solar cell manufacturing process, silicon wafers are important components in solar photovoltaic power generation equipment. Silicon wafers are the core components of solar cells, and their performance parameters directly affect the power...

Claims

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Application Information

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IPC IPC(8): C11D1/72C11D1/825C11D1/83C11D3/06C11D3/20C11D3/386C11D3/33C11D3/04C11D3/60H01L21/02H01L31/18
CPCC11D1/72C11D1/8255C11D1/8305C11D3/06C11D3/2079C11D3/38627C11D3/38645C11D3/33C11D3/38618C11D3/044C11D3/201H01L31/18H01L21/02052C11D1/722C11D1/28Y02P70/50
Inventor 吴家阳周浩王涛彭丽韩军常帅峰
Owner 嘉兴市小辰光伏科技有限公司
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