Anti-mite antibacterial polyester staple fiber and preparation method thereof

A polyester staple fiber, anti-mite technology, applied in the direction of botanical equipment and methods, fiber chemical characteristics, acaricide, etc., can solve the problems of poor temperature resistance, endocrine disorder, skin irritation, etc., and achieve high heat resistance effect

Active Publication Date: 2014-04-16
SHANGHAI DEFULUN CHEM FIBER
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] Anti-mite and antibacterial fiber products are mostly used in products that are in direct contact with the skin surface, so the safety and effectiveness of the finishing agent used and the compatibility with the fiber characteristics should be fully considered. Scientific research shows that acids, esters, alcohols, and phenols are used as The organic anti-mite and antibacterial agent as the main raw material has obvious short-term bactericidal and bacteriostatic effects, but its temperature resistance is poor, generally within 200°C, and it will melt out and precipitate after long-term use, which may irritate the skin and endanger health, such as organochlorines It will produce dioxin, a persistent pollutant poison, which will damage the liver and immune system. Pyrethroid anti-mite agents will also produce dioxin, and their anti-mite effect is not satisfactory. Organophosphorus anti-mite agents are an environmental hormone. It can cause many problems such as endocrine disorders and hormone regulation disorders.

Method used

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  • Anti-mite antibacterial polyester staple fiber and preparation method thereof
  • Anti-mite antibacterial polyester staple fiber and preparation method thereof
  • Anti-mite antibacterial polyester staple fiber and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0051] 10kg of Taiji stone, 25kg of boric acid, 40kg of clay, and 15kg of silicic acid were mixed and ground into powders of 1-100 μm, which were pressed into tablets using a powder tableting machine and a mold. The heating rate is increased to 1500°C, calcined for 2~4h, and the anti-mite ceramic powder A1 of 1-60μm is formed after high temperature compounding.

[0052] Using silver nitrate 2kg, sodium chloride 0.63kg, metatitanic acid 7.9kg as raw materials, Ag + and Cl - AgCl is formed by direct reaction and precipitation, and AgCl is used as the seed crystal, and the pH is adjusted to 9-10, so that the metatitanic acid precipitates Ti(OH) on the surface of the seed crystal. 4 , after suction filtration, washing and drying, in a box-type resistance furnace with a heating rate of 10 °C / min to 800 °C, and calcined for 2-3 h to obtain silver-loaded nano-titania composite antibacterial powder A1.

[0053] The preparation method of the anti-mite and antibacterial polyester stap...

Embodiment 2

[0061] 6kg of Taiji stone, 12kg of boric acid, 30kg of clay, and 8kg of silicic acid were mixed and ground into powders of 1-100 μm, which were pressed into tablets using a powder tableting machine and a mold. The heating rate is increased to 1500°C, calcined for 2~4 hours, and the anti-mite ceramic powder A2 of 1-60 μm is formed after high temperature compounding.

[0062] Using silver nitrate 2kg, sodium chloride 0.63kg, metatitanic acid 8.7kg as raw materials, Ag + and Cl - AgCl is formed by direct reaction and precipitation, and AgCl is used as the seed crystal, and the pH is adjusted to 9-10, so that the metatitanic acid precipitates Ti(OH) on the surface of the seed crystal. 4 , after suction filtration, washing and drying, in a box-type resistance furnace at a heating rate of 10 °C / min, the temperature was raised to 800 °C and calcined for 2-3 h to obtain silver-loaded nano-titania composite antibacterial powder A2.

[0063] The preparation method of the anti-mite and...

Embodiment 3

[0071] Taiji stone 4kg, boric acid 8kg, clay 18kg, silicic acid 6kg were mixed and ground into powders of 1-100 μm, which were pressed into tablets using a powder tableting machine and a mold. The heating rate is increased to 1500°C, calcined for 2 to 4 hours, and the anti-mite ceramic powder B1 of 1-60 μm is formed after high temperature compounding.

[0072] Using silver nitrate 2kg, sodium chloride 0.63kg, metatitanic acid 8.42kg as raw materials, Ag + and Cl - AgCl is formed by direct reaction and precipitation, and AgCl is used as the seed crystal, and the pH is adjusted to 9-10, so that the metatitanic acid precipitates Ti(OH) on the surface of the seed crystal. 4 , after suction filtration, washing and drying, in a box-type resistance furnace with a heating rate of 10 °C / min to 800 °C, and calcined for 2-3 h to obtain silver-loaded nano-titania composite antibacterial powder B1.

[0073] Blend 25kg of micron-scale heat-storage anti-mite ceramic powder B1 and 75kg of P...

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Abstract

The invention relates to insoluble inorganic anti-mite antibacterial polyester staple fiber which is prepared from micron-scale heat accumulation anti-mite ceramic powder and silver-loaded nano titanium dioxide composite antibacterial powder through an esterification polymerization spinning mode or prepared by making the powder into masterbatch and mixing with polyether slices and spinning, wherein the micron-scale heat accumulation anti-mite ceramic powder is prepared from 2-6 parts of Tai Chi stone, 5-12 parts of boric acid, 8-30 parts of clayed soil and 3-8 parts of silicic acid by mass by grinding, tabletting, calcining and high-temperature compounding; the silver-loaded nano titanium dioxide composite antibacterial powder is prepared from 1-1.5 parts of silver nitrate and sodium chloride and 3-5 parts of metatitanic acid by mass by precipitation, suction filtration, washing, drying and calcining; the anti-mite antibacterial polyester staple fiber obtained by spinning has a relatively strong antibacterial effect on staphylococcus aureus and escherichia coli, wherein the antibacterial rate is greater than or equal to 95%, and the mite proliferation inhibition rate is greater than 92%.

Description

technical field [0001] The invention relates to an anti-mite and antibacterial polyester staple fiber and a preparation method thereof, in particular to a non-dissolving, inorganic anti-mite and antibacterial polyester staple fiber and a preparation method thereof. Background technique [0002] Mites are a kind of "miniature animals" that are not easy to see with the naked eye. There are many kinds of mites. At present, there are more than 40 kinds of mites living in the living room. The suitable living conditions for mites are the temperature of 17~30℃ and the relative humidity of 75%~80%. Mites are found in every corner of our lives. They breed on carpets, sofas, plush toys, bedding, cushions, mattresses and pillow cores, and feed on mold, human sweat, secretions, and shed skin flakes. Extremely fast, the mite can live for about four months, during which time it can produce feces 200 times its body weight and lay as many as 300 eggs. Mites themselves are not allergens, b...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D01F6/92D01F1/10C08G63/183C04B33/13A01N59/16A01P1/00A01P7/02C08J3/22
Inventor 孔彩珍冯忠耀刘萍杨卫忠陈辉华陆正辉邱杰峰闫吉付朱亚宏沈飞
Owner SHANGHAI DEFULUN CHEM FIBER
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