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Composite manufacturing method for improving high-temperature oxidation resistance of valve rod of steam turbine

A technology of anti-high temperature oxidation and manufacturing method, applied in the direction of superimposed layer plating, ion implantation plating, coating, etc., can solve the problems of oxide skin shedding, accelerated high temperature oxidation of valve stem, valve jamming, etc., and achieve high performance Improves and improves antioxidant properties

Inactive Publication Date: 2021-07-16
东莞市华鑫激光科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] The valve stem material used on the main steam valve and steam regulating valve of the original steam turbine is 12%Cr martensitic stainless heat-resistant steel (such as 20Cr12NiMoV1), and the surface of the valve stem is subjected to nitriding (nitriding) treatment after quenching and tempering; The valve stem made of the above materials and processes, in the process of use, the oxide skin of the valve stem grows too fast, causing the valve to be stuck; this is mainly because 12% Cr martensitic stainless steel heat-resistant steel at high temperature (538 ° C or 566 ° C) Under the long-term action of water vapor, corrosion and oxidation will occur, and the nitriding process will accelerate the high-temperature oxidation of such valve stems; in the later period, some people tried to use GH901 alloy material, solid solution + aging, and then surface nitriding treatment, the poppet valve The anti-oxidation performance of the stem at high temperature has not been solved, but it has not yet solved the problem of excessive growth and shedding of oxide skin on such valve stems under long-term high-temperature service, resulting in the jamming problem of the regulating valve, which restricts the safe operation of the steam turbine unit

Method used

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  • Composite manufacturing method for improving high-temperature oxidation resistance of valve rod of steam turbine
  • Composite manufacturing method for improving high-temperature oxidation resistance of valve rod of steam turbine
  • Composite manufacturing method for improving high-temperature oxidation resistance of valve rod of steam turbine

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Effect test

Embodiment 1

[0036] (1) A plasma-based alloy powder is used to form a cobalt-based alloy powder, and a 1.0 mm thick cobalt-based pile of welding layer, a plasma-reducing process is formed on the surface of 12% CR martensite stainless heat-resistant steel valve stem. Technical parameters are current 140a, pulse welding time 700ms & residence time 300ms, welding speed 200 mm / min, overlink rate of 50%, feed powder 8g / mim; cobalt-based alloy is based on mass split, composed, carbon 0.40 %, 25.5% of chromium, 1.0%, manganese, 1.0%, nickel 10.0%, silicon 0.36%, tungsten 8.5%, margin is cobalt;

[0037] (2) 12% CR martensite stainless heat-resistant steel valve stem after step (1), 560 ° C, high temperature, pressure tempering treatment, heat insulation for 6 h, eliminates part of the heterogeneous metal fusion internal stress, the original The thickness is 1.6mm, and the remaining effective thickness is 1.0mm after approximately 0.6 mm, ensuring the machining to the valve stem final size + 0.08m...

Embodiment 2

[0041] (1) The plasma-binder is used, with a cobalt-based alloy powder, a 0.8 mm thick cobalt-based pile of welding layer formed in the GH901 alloy material valve stem surface, the technical parameter of the plasma surfacing process is current 130a, pulsed welding Time 700ms & stay time 300ms, welding speed 200 mm / min, overlink rate of 50%, powder distribution 7g / mim; cobalt-based alloy by mass fraction, composed of the following components, carbon 0.40%, chromium 25.5%, iron 1.0 %, Manganese 0.5%, molybdenum 1.0%, nickel, 0.36% silicon, 8.5% tungsten, margin is cobalt;

[0042](2) After the step (1), the GH901 alloy material valve stem is taken at 660 ° C for high temperature depletion, heat-insulation 6 h, eliminates part of the heterogeneous metal fusion internal stress, the original thickness of 1.4mm after the solder welding, the motor After the processing is about 0.6 mm, the remaining effective thickness is 0.8mm to ensure turning processing to the valve stem final size...

Embodiment 3

[0046] (1) A plasma-stained fabrication is equipped with a cobalt-based alloy powder, and a 1.2 mm thick cobalt-based stacuk layer, a plasma surfracting process is formed on the surface of 12% Cr martensite stainless heat-resistant steel valve stem. The technical parameters are current 145a, pulse welding time 700ms & residence time 200ms, welding speed 200 mm / min, overlink rate of 50%, powder distribution amount 9g / mim; cobalt-based alloy is based on mass fraction, composed of the following components, carbon 0.5%, chromium 24%, iron 1.3%, manganese, molybdenum 1.2%, nickel 9.5%, silicon 0.4%, tungsten, tungsten, tungsten, tungsten 7%, margin is cobalt;

[0047] (2) 12% CR martensite stainless heat-resistant steel material after step (1), 520 ° C, high temperature, rectification, heat-insulation 8 h, eliminate partial heterogeneous metal fusion internal stress, depiculation The original thickness is about 1.8mm, and the remaining effective thickness is 1.2mm after approximate...

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Abstract

The invention relates to a composite manufacturing method for improving the high-temperature oxidation resistance of a valve rod of a steam turbine. The composite manufacturing method comprises the following steps of: step one, forming an atomic metallurgical-bonded cobalt-based surfacing layer with the thickness of 0.5-1.2 mm on the surface of a valve rod by adopting plasma surfacing equipment and cobalt-based alloy powder; step two, conducting stress relief tempering on the valve rod, and eliminating part of internal stress of dissimilar metal fusion; step three, conducting turning till the grinding allowance of the final size plus (0.05-0.10) mm is obtained; step four, conducting laser shock peening treatment on the surface of a cobalt-based alloy surfacing layer; step five, conducting grinding and polishing to the assembly size; and step six, forming a (2-12) micron high-temperature oxidation coating (Cr-Al) resistant to 1100 DEG C through physical vapor deposition. According to the composite manufacturing method, the problem that the valve rod of the steam turbine is often jammed is solved, and the safety and reliability of a steam turbine set are improved.

Description

Technical field [0001] The present invention relates to the field of valve stem processing, and more particularly to a composite manufacturing method for lifting high temperature oxidation properties of steam turbine valve bar. Background technique [0002] The valve stem material used on the original steam turbine main steam valve and steam regulating valve is 12% CR martensite stainless heat-resistant steel (e.g., 20Cr12Nimov1), and the surface of the valve stem is nitrided (nitrogen nitrogen) treatment after the conditioning treatment; The above-mentioned material and process manufactured, the valve stem growth is too fast during use, resulting in a valve card; this is mainly 12% CR martensite stainless heat resistant steel at high temperature (538 ° C or 566 ° C) Under the long action of water vapor, corrosion and oxidation occurs, and the nitridation process can accelerate the high temperature oxidation of such stems; the late Some people try to use GH901 alloy materials, so...

Claims

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Application Information

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IPC IPC(8): C23C28/02C23C24/10C22C19/07C22F1/10C22F3/00C23C14/16
CPCC23C28/021C23C24/106C22C19/07C22F1/10C22F3/00C23C14/16
Inventor 罗雄光
Owner 东莞市华鑫激光科技有限公司