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A wood modifier composition, and a method for improving physical and mechanical properties of wood

A technology of wood physical mechanics and modifier, applied in the field of wood modifier composition and wood physical and mechanical properties improvement, can solve the problem of low reactivity, difficulty in giving full play to polymer modification, poor bonding between polymer and cell wall interface And other issues

Active Publication Date: 2022-07-08
INST OF WOOD INDUDTRY CHINESE ACAD OF FORESTRY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, wood is a polymer complex composed of lignin, cellulose, and hemicellulose. These substances have low reactivity, and most of the chemicals entering wood are difficult to directly react with the above three elements.
In addition, wood is a polar material, and most of the polymers formed in the chemical modification of wood have non-polar characteristics. For example, Chinese patent CN103568088A discloses a kind of bulk polymerization of methyl methacrylate in wood to prepare glass In the method of chemicalizing wood, the interface between the polymer and the cell wall is poorly combined, and it is difficult to fully exert the modification effect of the polymer on wood.
[0004] By acetylating the hydroxyl groups in the wood, the hydrophobicity of the wood can be improved, and the interface affinity between the hydrophobic polymer and the cell wall can be improved. For example, Chinese patent CN101954662A discloses a method of grafting cell walls with organic monomer swelling The method of modifying wood combined with polymerization to fill the cell cavity can improve the mechanical properties of wood, but the acylation treatment in this technology is mainly to improve the hydrophobicity of wood, so there is still a poor interface between the polymer and the cell wall in this patent. The modification effect of the polymer on the mechanical properties of wood cannot be fully utilized, and at the same time, organic toxic solvents such as acetone or tetrahydrofuran need to be used in the acylation modification, which is unfavorable for green industrial applications

Method used

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  • A wood modifier composition, and a method for improving physical and mechanical properties of wood
  • A wood modifier composition, and a method for improving physical and mechanical properties of wood
  • A wood modifier composition, and a method for improving physical and mechanical properties of wood

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0093] Prepare a mixed aqueous solution of 32% concentration of hydroxyethyl methacrylate and 8% concentration of N-hydroxyacrylamide, and add 2% hydrogen peroxide / calcium chloride based on the mass of the monomer as a catalyst as a hydrophilic active system;

[0094] The 10-year-old fast-growing poplar samples (electron microscope photos such as figure 1 (shown) immersed in the hydrophilic active system, after vacuum immersion at -1MPa for 30min, pressure immersion at 1MPa for 2h. After the impregnation is completed, the solution on the surface of the sample is wiped dry and aged at room temperature for one day; the first impregnated wood is obtained;

[0095] The first impregnated wood was directly put into an oven, heated at 80° C. for 6 h to carry out the first heat treatment, and then heated to a constant weight at 103° C. to obtain the first treated wood (electron microscope photos such as: figure 2 shown);

[0096] A reactive system was obtained by adding 0.8% azobis...

Embodiment 2

[0100] Prepare an aqueous solution of 20% concentration of N-hydroxyacrylamide, and add 2% hydrogen peroxide / calcium chloride based on the mass of the monomer as a catalyst as a hydrophilic active system;

[0101] The 10-year-old fast-growing poplar samples (electron microscope photos such as figure 1 shown) immersed in the hydrophilic active system, after vacuum immersion at -1MPa for 30min, pressure immersion at 1MPa for 2h. After the impregnation is completed, the solution on the surface of the sample is wiped dry and aged at room temperature for one day; the first impregnated wood is obtained;

[0102] The first impregnated wood was directly put into an oven, heated at 80° C. for 6 h for the first activation, and then heated to a constant weight at 103° C. to obtain the first treated wood (electron microscope photo and figure 2 resemblance);

[0103] A reactive system was obtained by adding 0.8% azobisisobutyl cyanide based on the mass of the monomer into the methyl met...

Embodiment 3

[0107] An aqueous solution of N-isopropylacrylamide with a concentration of 20% is prepared, and 2% hydrogen peroxide / calcium chloride based on the mass of the monomer is added as a catalyst as a hydrophilic active system;

[0108] The 10-year-old fast-growing poplar samples (electron microscope photos such as figure 1 ) was immersed in the hydrophilic active system, after vacuum immersion at -1MPa for 30min, and pressure immersion at 1MPa for 2h. After the impregnation is completed, the solution on the surface of the sample is wiped dry, and aged at room temperature for one day; the first impregnated wood is obtained;

[0109] The first impregnated wood was directly put into an oven, heated at 80° C. for 6 h for the first activation, and then heated to a constant weight at 103° C. to obtain the first treated wood (electron microscope photo and figure 2 resemblance);

[0110]A reactive system was obtained by adding 0.8% azobisisobutyl cyanide based on the mass of the monome...

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Abstract

The invention belongs to the technical field of wood performance improvement, and in particular relates to a wood modifier composition and a method for improving the physical and mechanical properties of wood. The wood modifier composition provided by the present invention includes a hydrophilic active system and a reaction active system separately packaged; the hydrophilic active system includes a hydrophilic epoxy monomer and a polar solvent, or a hydrophilic alkenyl monomer body, catalyst and polar solvent; the reactive system includes reactive epoxy monomer and curing agent, or reactive ethylenic monomer and initiator. The dimensional stability and mechanical properties of the modified wood prepared by the wood modifier composition provided by the invention are significantly improved.

Description

technical field [0001] The invention belongs to the technical field of wood performance improvement, and in particular relates to a wood modifier composition and a method for improving the physical and mechanical properties of wood. Background technique [0002] Wood is a renewable, low-carbon material. It has been widely used in construction and furniture manufacturing. my country's plantation forests are rich in wood resources, but plantation woods have the defects of poor mechanical properties caused by loose structure, high porosity and low density, which restrict their application to a certain extent. Chemical modification of wood is considered as an important method to solve these problems. [0003] Chemical modification changes the physical and mechanical properties of wood by impregnating the wood with chemical agents and polymerizing the agents in the wood. However, wood is a polymer complex composed of lignin, cellulose and hemicellulose. These substances have l...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B27K3/02B27K3/08B27K5/00B27K3/50B27K3/34B27K3/36C08F289/00C08F220/20C08F220/58C08F212/08C08F220/14C08F220/54C08F222/14
CPCB27K3/025B27K3/08B27K5/0085B27K3/50B27K3/343B27K3/36C08F289/00C08F220/20C08F220/58C08F212/08C08F220/14C08F220/54C08F222/102
Inventor 李改云郭登康傅峰储富祥杨昇
Owner INST OF WOOD INDUDTRY CHINESE ACAD OF FORESTRY