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Mildew-proof microcapsule for bamboo wood and preparation method of mildew-proof microcapsule

A microcapsule and anti-mildew technology, which is applied in the direction of microcapsule preparation, microsphere preparation, wood treatment, etc., can solve the problems that organic fungicides cannot be uniformly dispersed, cannot protect bamboo and wood for long-term protection, and is easy to hydrolyze and photolyze. Narrow distribution index, industrialized production and application, and good thermal stability

Pending Publication Date: 2021-11-30
国家林业和草原局竹子研究开发中心
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, organic fungicides cannot be uniformly dispersed in water to form a micron or nano-scale protective agent solution; they are easy to be hydrolyzed and photolyzed during storage and use, and are easy to lose, so they cannot provide long-term protection for bamboo wood.

Method used

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  • Mildew-proof microcapsule for bamboo wood and preparation method of mildew-proof microcapsule
  • Mildew-proof microcapsule for bamboo wood and preparation method of mildew-proof microcapsule
  • Mildew-proof microcapsule for bamboo wood and preparation method of mildew-proof microcapsule

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] Embodiment 1: a kind of mildew-proof microcapsule for bamboo, comprising by mass parts:

[0031] Core material 1g, wall material 1g, emulsifier 0.8g, dispersant 0.5g, acid catalyst 0.4g; Described emulsifier is styrene-maleic anhydride emulsion, and described dispersant is polyvinyl alcohol, and described acid catalyst is acetic acid;

[0032] The core material includes the following components in parts by weight: 3 g of a triazole fungicide, 0.9 g of an organic solvent; the triazole fungicide is tebuconazole, and the organic solvent is toluene;

[0033] The wall material is amino resin, and the amino resin is urea-formaldehyde resin.

[0034] Carry out the preparation of mildew-proof microcapsules according to above-mentioned raw material, its step is as follows:

[0035] S1, mixing triazole fungicides and organic solvents at a temperature of 20-40°C to obtain core materials;

[0036] S2. After mixing the core material and the emulsifier in the amino resin, add a di...

Embodiment 2

[0038] Embodiment 2: a kind of mildew-proof microcapsule for bamboo, comprising by mass parts:

[0039] Core material 1g, wall material 2g, emulsifier 1.3g, dispersant 0.8g, acid catalyst 0.8g; Described emulsifier is sodium lauryl sulfate, and described dispersant is polyethylene glycol, and described acid catalyst is citric acid;

[0040] The core material includes the following components in parts by weight: 6 g of triazole fungicide, 1.2 g of organic solvent; the triazole fungicide is propiconazole, and the organic solvent is ethanol;

[0041] The wall material is amino resin, and the amino resin is urea-formaldehyde resin.

[0042] Carry out the preparation of mildew-proof microcapsules according to above-mentioned raw material, its step is as follows:

[0043] S1. Mix and stir a triazole fungicide and an organic solvent at a temperature of 20-40° C. to obtain a core material;

[0044] S2. After mixing the core material and the emulsifier in the amino resin, add a disp...

Embodiment 3

[0046] Embodiment 3: a kind of mildew-proof microcapsule for bamboo, comprising by mass parts:

[0047] Core material 1g, wall material 2.5g, emulsifier 0.8g, dispersant 1g, acid catalyst 0.5g; Described emulsifier is the combination of sodium lauryl sulfate and polyoxyethylene octylphenol ether-10, both mass The ratio is 1:1, the dispersant is sodium polyacrylate, and the acidic catalyst is potassium hydrogen phthalate solution;

[0048] The core material includes the following components in parts by weight: 5 g of a triazole fungicide, 1 g of an organic solvent; the triazole fungicide is diniconazole, and the organic solvent is acetone;

[0049] The wall material is amino resin, and the amino resin is urea-formaldehyde resin.

[0050]Carry out the preparation of mildew-proof microcapsules according to above-mentioned raw material, its step is as follows:

[0051] S1. Mix and stir a triazole fungicide and an organic solvent at a temperature of 20-40° C. to obtain a core mat...

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Abstract

The invention discloses a mildew-proof microcapsule for bamboo wood and a preparation method of the mildew-proof microcapsule. The mildew-proof microcapsule comprises the following components in parts by mass: 1 part of a core material, 0.5-3 parts of a wall material, 0.8-1.5 parts of an emulsifier, 0.2-1.5 parts of a dispersing agent and 0.2-1.5 parts of an acid catalyst, wherein the core material comprises, in parts by weight, 3 to 6 parts of triazole bactericide and 0.8 to 1.5 parts of organic solvent; and the wall material is amino resin. The preparation method comprises the following steps: mixing and stirring the triazole bactericide and the organic solvent to obtain the core material; and mixing the core material and the emulsifier in the amino resin, adding the dispersing agent, carrying out heating for emulsifying to obtain a water-in-oil emulsion, adding the acidic catalyst into the water-in-oil emulsion, and carrying out an in-situ copolymerization reaction to form a microcapsule wall coating system, thereby obtaining the mildew-proof microcapsule. The mildew-proof microcapsule has the advantages of small particle size, excellent anti-mildew effect, good thermal stability and capability of slowing down the leakage rate of the core material.

Description

technical field [0001] The invention relates to a mildew-proof microcapsule for bamboo and a preparation method thereof, belonging to the field of bamboo and wood processing. Background technique [0002] Bamboo is an important part of forest resources, known as the "second forest". Bamboo products such as bamboo flooring, bamboo furniture, and recombined bamboo have been widely used in decoration, furniture, and building structural materials. By 2020, the annual output value of the bamboo industry has reached about 300 billion yuan. As these bamboo materials are gradually applied to outdoor fields such as structural buildings and wetland garden landscape facilities, when they are exposed to the natural environment, they are easily corroded by fungi, which accelerates their mildew and decay, greatly reducing their use value, thus gradually making them useless. The material loses its original excellent performance. At present, the long-acting anti-mildew problem of bamboo p...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J13/14B01J13/02B27K3/50B27K9/00
CPCB01J13/14B01J13/02B27K3/50B27K9/002B27K2240/20
Inventor 鲍敏振李能吴再兴包永洁何盛李景鹏陈玉和
Owner 国家林业和草原局竹子研究开发中心
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