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Carbon-coated nickel oxide catalyst and preparation method and application thereof

A carbon-coated nickel and catalyst technology, applied in the field of carbon-coated nickel oxide catalyst and its preparation, can solve the problems of low activity, limiting the large-scale application of noble metal catalysts, high price, etc., and achieve improved catalytic activity and good industrial application Prospects, effects of improving catalytic performance

Active Publication Date: 2021-12-07
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Noble metal catalysts (such as Rh and Ru) have high low-temperature catalytic activity for N2O catalytic decomposition (250℃~350℃ range, can efficiently decompose N2O) , but the high price limits the large-scale application of noble metal catalysts
The price of molecular sieve catalysts and transition metal oxide catalysts is significantly lower than that of noble metals, but the activity of these two types of catalysts for the catalytic decomposition of N2O is relatively low, and the temperature range for efficient decomposition is 450°C to 550°C. ℃

Method used

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  • Carbon-coated nickel oxide catalyst and preparation method and application thereof
  • Carbon-coated nickel oxide catalyst and preparation method and application thereof
  • Carbon-coated nickel oxide catalyst and preparation method and application thereof

Examples

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preparation example Construction

[0050] figure 1 It is a flow chart of the preparation process of a carbon-coated nickel oxide catalyst according to an embodiment of the present invention. Such as figure 1 As shown, the present invention provides a method for preparing a carbon-coated nickel oxide catalyst, comprising the following steps: providing a carbon-coated nickel nanocomposite as a raw powder, adding a binder to the raw powder and mixing to obtain a wet material Dough; the wet dough is dried and subjected to the first roasting treatment under an inert atmosphere; the second metal salt solution is prepared, and the product after the first roasting treatment is mixed with the second metal salt solution and stirred to obtain A solid-liquid mixture; the solid-liquid mixture is dried and subjected to molding treatment; and the product after the molding treatment is subjected to a second roasting treatment in air to obtain a carbon-coated nickel oxide catalyst; wherein the second metal salt solution selec...

Embodiment 1

[0095] This embodiment is used to illustrate the preparation method of catalyst of the present invention

[0096] (1) Weigh 10 g of nickel carbonate and 10 g of citric acid into a beaker containing 100 mL of deionized water, stir at 70° C. to obtain a homogeneous solution, and continue heating and evaporating to dryness to obtain a solid precursor.

[0097] (2) Place the solid precursor obtained in step (1) in a porcelain boat, then place the porcelain boat in the constant temperature zone of the tube furnace, feed in nitrogen gas with a flow rate of 100mL / min, and heat at a rate of 4°C / min. The temperature was raised to 600° C., and the heating was stopped after keeping the temperature for 2 hours, and cooled to room temperature under a nitrogen atmosphere to obtain a carbon-coated nickel nanocomposite material. According to elemental analysis, the mass percentages of elements contained in the carbon-coated nickel nanocomposite material are: carbon 26.14%, hydrogen 0.42%, oxy...

Embodiment 2

[0105] (1) Weigh 10g of nickel acetate and 10g of citric acid into a beaker containing 100mL of deionized water, stir at 70°C to obtain a homogeneous solution, continue heating and evaporate to dryness, and obtain a solid precursor.

[0106] (2) Place the solid precursor obtained in step (1) in a porcelain boat, then place the porcelain boat in the constant temperature zone of the tube furnace, feed nitrogen gas with a flow rate of 100mL / min, and set the temperature at a rate of 2°C / min. Raise the temperature to 650° C., stop the heating after 2 hours of constant temperature, and cool to room temperature under a nitrogen atmosphere to obtain a carbon-coated nickel nanocomposite material. According to elemental analysis, the mass percentages of elements contained in the carbon-coated nickel nanocomposite are: carbon 24.29%, hydrogen 0.47%, oxygen 0.96%, nickel 74.28%. From Figure 4 It can be seen that the nickel in this material is present in a reduced state. Figure 5 It is...

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Abstract

The invention provides a carbon-coated nickel oxide catalyst and a preparation method and application thereof, and the preparation method comprises the following steps: providing a carbon-coated nickel nano composite material as raw powder, adding a binder into the raw powder, and mixing to obtain a wet material block; drying the wet material block, and then carrying out first roasting treatment in an inert atmosphere; preparing a second metal salt solution, uniformly mixing a product after the first roasting treatment with the second metal salt solution, and stirring to obtain a solid-liquid mixture; the solid-liquid mixture is dried and then subjected to molding treatment; carrying out second roasting treatment on the molded product in the air to obtain the carbon-coated nickel oxide catalyst; the second metal salt solution is selected from an alkali metal salt solution and / or an alkaline earth metal salt solution. The nano composite material is used as raw powder and a second metal oxide is used as an auxiliary agent to prepare the catalyst, and the catalyst is processed through a specific process, so that the specific surface, the pore volume and the pore diameter of the catalyst can be adjusted, and the catalyst has relatively high catalytic activity and mechanical strength and has a relatively excellent effect on catalytic decomposition of nitrous oxide.

Description

technical field [0001] The invention relates to the field of catalysts, in particular to a carbon-coated nickel oxide catalyst, a preparation method and application thereof. Background technique [0002] Transition metal oxides have excellent catalytic properties and photoelectromagnetic properties, and are research hotspots in the field of inorganic materials. Carbon materials have good electrical conductivity, good chemical / electrochemical stability, and high structural strength. Coating the nanoparticles of active metals or metal oxides with carbon materials can effectively improve the conductivity and stability of the nanomaterials, and have a limited effect on the nanoparticles so that they are not easy to agglomerate. In recent years, carbon-coated metal nanomaterials have not only been widely used in the fields of electrocatalysis, supercapacitor materials, lithium-ion battery anode materials, and bioengineering, but also show good application prospects in the field ...

Claims

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Application Information

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IPC IPC(8): B01J23/58B01J35/10B01J37/08B01D53/86B01D53/56
CPCB01J23/58B01J23/002B01J37/08B01D53/8628B01D2257/402B01J35/40B01J35/633B01J35/647B01J35/615Y02C20/10
Inventor 于鹏徐国标荣峻峰谢婧新宗明生吴耿煌林伟国纪洪波
Owner CHINA PETROLEUM & CHEM CORP
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